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Large-scale smelting activities release large amounts of potentially toxic elements (PTEs) in fine particles. These particles floating in the air eventually settle on leaves, roads, and even indoors. In smelting areas, indoor environments are generally considered relatively safe. However, these areas are not taken seriously and need to be assessed. This paper systematically studied pollution characteristics, main sources and health risks of ten potentially toxic elements, PTEs (Mn, Ni, Cu, Zn, Hg, Cd, As, Cr, Pb, and Tl), of dust samples from different indoor environments in smelting areas using various methods. Therefore, this study analyzed dust samples from 35 indoor environments. The enrichment factors showed that the indoor dust samples were extremely enriched by Cd and Cu and significantly enriched by Hg, Pb, As, and Zn. The result of the spatial distribution showed that the high-value PTEs were mainly distributed near the Cu smeltery. Three sources were quantitatively assigned for these PTEs, and they were industrial smelting and traffic activities (44.40%), coal-fired activities (18.11%), and natural existence (37.49%). Based on the calculation of health risk, the value of THI for children was 7.57, indicating a significant non-carcinogenic risk. For carcinogenic risk, the values of TCR for children and adults were 2.91×10−2 and 2.97×10−3, respectively, which were much higher than the acceptable risk value 1×10−4. Combining health risk assessment with source discrimination, we found that the industrial discharges and traffic activities were the most main source of non-cancer and cancer risks. Therefore, smelting activities should be more strictly monitored, and traffic emission management should be strengthened.

The widespread adoption of Bt crops expressing insecticidal proteins derived from Bacillus thuringiensis has created a need to assess the potential effects of these toxins on non-target organisms, especially species such as Arma custos, a generalist predator that provides important biological control services in many field crops in Asia. Direct dietary exposure of A. custos to Cry1Ah and Vip3Aa proteins produced no adverse effects on life history traits, despite continuous exposure throughout development and early adult life to concentrations significantly higher than the Bt protein concentration likely encountered by A.custos in the field, even when feeding directly on Bt plants. Enzyme-linked immunosorbent assay confirmed the presence of Bt proteins in A. custos midguts, but quantitative real-time PCR analysis of 12 genes associated with detoxification, antioxidative responses, immune responses, and metabolism revealed no significant changes in expression in adult bugs. Indirect exposure to these toxins via consumption of intoxicated prey, larvae of Helicoverpa armigera (Hübner), likewise produced no negative impacts on survival, development, adult weight, or female fecundity in either the F0 (exposed) or F1 (unexposed) generation, but female fresh weight was reduced in the F0 generation by the Cry1Ah (50 μg/g) treatment. Finally, a competitive binding assay with labelled protein and a ligand blotting assay both demonstrated that the Cry1Ah protein could not bind to receptors on the midgut brush border membrane vesicles (BBMVs) of A. custos adults. Therefore, we conclude that Cry1Ah and Vip3Aa proteins are unlikely to have significant negative effects on A. custos populations if employed as plant-incorporated protectants in field crops.

Short-chain chlorinated paraffins (SCCPs) are a series of new persistent organic pollutants, posing a risk of significant adverse effects to biota. Increasing attention has been paid to SCCP pollution in China as large amounts of chlorinated paraffin (CP) products containing SCCPs have been produced and used there. However, knowledge of the bioaccumulation of SCCPs in marine organisms from the Pearl River Estuary (PRE), Southern China, is still scarce. In this study, SCCP concentrations were measured in seawater, sediments, and marine organisms from the PRE. SCCP concentrations ranged from 180 to 460 ng/L in seawater, from 180 to 620 ng/g dry weight (dw) in sediments, and from 870 to 36,000 ng/g lipid weight (lw) in marine biota samples. C10–11 SCCPs were the predominant homologues in all the samples, with an average abundance of 68% in seawater, 57% in sediments, and 56–77% in marine organisms. However, chlorine patterns of SCCPs in seawater, sediments, and marine organisms were different. Cl8–10 SCCPs dominated in sediments, whereas Cl5–7 SCCPs were the predominant SCCP homologues in water and most organism species. The logarithm bioaccumulation factors (BAFs) of SCCPs ranged from 1.6 to 3.0, and increased significantly with the increase of Kow values for most marine biota species, indicating that Kow was the major factor controlling the bioaccumulation of SCCPs and that SCCPs with higher lipophilicity were more prone to being bioaccumulated from water. Opposite to that observed for log BAFs, biota-sediment accumulation factors of specific SCCPs (range: 0.01–30) decreased significantly with the increase of Kow values. The biomagnification factor of total SCCPs for oyster–mangrove crab was 2.40, implying the potential biomagnification of SCCPs for benthos in the PRE.

The single and combined effects of phyto and electro remediation to decontaminate metal contaminated soil were evaluated in this study. Leaching risks of metals from top soil to groundwater after chelator application were compared under different conditions. Soil from Guiyu (China), a notorious e-waste recycling centre, was remediated by different methods including chelator addition, electric field application and their combination. Ethylene diamine tetraacetic acid (EDTA) was applied as chelator. In electrokinetic and combined remediation experiments, stainless steel sheets were adhered to stems to charge the plant negatively. Chelator can significantly enhance the plant's ability to absorb metals and impel the metals moving from top to deep soil layers. Individual effects of electric field with varied voltages on phytoremediation efficiency were different. The ability of plants to accumulate metals increased with the increase of voltages. The biomass production of plants was enhanced at low (2 V) and moderate (4 V) voltages and decreased at high (10 V). Metal leaching in electrokinetic remediation processes was less significant than in EDTA treatment and the control. Phytoremediation efficiency improved by combining chelator and electric field was up to twice as much as by individual chelator. These results indicated that phytoremediation assisted by electric field is a potential technology to decontaminate large scale fields.

Soil-bound heavy metals are of great concern for human health due to the potential exposure via food chain transfer. In the present study, the occurrence, the bioavailability and the soil-to-crop transfer of heavy metals in farmland soils were investigated based on data from two agricultural areas, i.e. Sihui and Shunde in South China. Six heavy metals (As, Cu, Hg, Mn, Ni and Pb) were quantified in the farmland soils. The mean single pollution level indices (PI) were all lower than 1 except for Hg in soils from Shunde (PI = 1.51 ± 0.46), suggesting the farmland soils were within clean and slightly polluted by heavy metals. As, Cu, Ni and Pb were found to be mostly present in the non-bioavailable form. The majority of Hg was considered potentially bioavailable, and Mn was found to be largely bioavailable. Soil pH was an important factor influencing bioavailability of soil-bound heavy metals. The concentrations of heavy metals in vegetables from Sihui and Shunde were within the food hygiene standards, while the rice grain from Sihui was polluted by Pb (PI = 10.3 ± 23.4). Total soil concentrations of heavy metals were not correlated to their corresponding crop concentrations, instead, significant correlations were observed for bioavailable concentrations in soil. The results supported the notion that the bioavailability of the investigated heavy metals in the soil was largely responsible for their crop uptake. The soil-to-crop transfer factors based on bioavailable concentrations suggested that Cu, As and Hg in soils of the study area had greater tendency to be accumulated in the vegetables than other heavy metals, calling for further human health assessment by consuming the contaminated crops.

Direct and alternating current electric fields with various voltages were used to improve the decontamination efficiency of chelator assisted phytoremediation for multi-metal polluted soil. The alleviation effect of electric field on leaching risk caused by chelator application during phytoremediation process was also evaluated. Biomass yield, pollutant uptake and metal leaching retardation under alternating current (AC) and direct current (DC) electric fields were compared. The biomass yield of Eucalyptus globulus under AC fields with various voltages (2, 4 and 10 V) were 3.91, 4.16 and 3.67 kg, respectively, significantly higher than the chelator treatment without electric field (2.71 kg). Besides growth stimulation, AC fields increased the metal concentrations of plant tissues especially in aerial parts manifested by the raised translocation factor of different metals. Direct current electric fields with low and moderate voltages increased the biomass production of the species to 3.45 and 3.12 kg, respectively, while high voltage on the contrary suppressed the growth of the plants (2.66 kg). Under DC fields, metal concentrations elevated obviously with increasing voltages and the metal translocation factors were similar under all voltages. Metal extraction per plant achieved the maximum value under moderate voltage due to the greatest biomass production. DC field with high voltage (10 V) decreased the volume of leachate from the chelator treatment without electric field from 1224 to 56 mL, while the leachate gathered from AC field treatments raised from 512 to 670 mL. DC field can retard the downward movement of metals caused by chelator application more effectively relative to AC field due to the constant water flow and electroosmosis direction. Alternating current field had more promotive effect on chelator assisted phytoremediation efficiency than DC field illustrated by more metal accumulation in the species. However, with the consideration of leaching risk, DC field with moderate voltage was the optimal supplementary technique for phytoremediation.

The phytoremediation efficiency of various metals by Ficus microcarpa was evaluated through a real scale experiment in the present study. The root biomass production of the species varied significantly from 3.68 to 5.43 g because of the spatial heterogeneity of different metals. It would take 4–93 years to purify the excess Cd of the experimental site. Mercury was the most inflexible element which can barely be phytoremediated by F. microcarpa. After the species transplanted from the polluted soil to the clean site, Cd and Cu were transferred to the rhizosphere soil to different extent while the bulk soil was barely influenced. Relative to Cd and Cu, significantly fewer amounts of Pb and Hg were released. The highest concentrations of Cd, Cu, Hg and Pb in the clean soil were far below their corresponding safe thresholds for agricultural land after 3 months of the polluted plants were cultivated and metal concentrations of plant leaves were negligible, both indicated the low ecological risk of transplantation. Results from this study suggested a feasible disposal method for metal rich plants after phytoremediation.

Multiple techniques for soil decontamination were combined to enhance the phytoremediation efficiency of Eucalyptus globulese and alleviate the corresponding environmental risks. The approach constituted of chelating agent using, electrokinetic remediation, plant hormone foliar application and phytoremediation was designed to remediate multi-metal contaminated soils from a notorious e-waste recycling town. The decontamination ability of E. globulese increased from 1.35, 58.47 and 119.18 mg per plant for Cd, Pb and Cu in planting controls to 7.57, 198.68 and 174.34 mg per plant in individual EDTA treatments, respectively, but simultaneously, 0.9–11.5 times more metals leached from chelator treatments relative to controls. Low (2 V) and moderate (4 V) voltage electric fields provoked the growth of the species while high voltage (10 V) had an opposite effect and metal concentrations of the plants elevated with the increment of voltage. Volumes of the leachate decreased from 1224 to 134 mL with voltage increasing from 0 to 10 V due to electroosmosis and electrolysis. Comparing with individual phytoremediation, foliar cytokinin treatments produced 56% more biomass and intercepted 2.5 times more leachate attributed to the enhanced transpiration rate. The synergistic combination of the individuals resulted in the most biomass production and metal accumulation of the species under the stress condition relative to other methods. Time required for the multi-technique approach to decontaminate Cd, Pb and Cu from soil was 2.1–10.4 times less than individual chelator addition, electric field application or plant hormone utilization. It's especially important that nearly no leachate (60 mL in total) was collected from the multi-technique system. This approach is a suitable method to remediate metal polluted site considering its decontamination efficiency and associated environmental negligible risk.

Soil samples containing excess Cd (0.82 mg kg−1), Pb (92.7 mg kg−1) and Cu (72.7 mg kg−1) relative to their corresponding safe thresholds (0.3, 80 and 50 mg kg−1, respectively) from a notorious e-waste disposing and recycling place in southern China were phytoremediated with EDTA addition to evaluate the promotion effects of cytokinin on the remediation efficiency of Eucalyptus globulus. Biomass production of the plant, evapotranspiration amount of the soil, metals accumulation in plant organs and the volume of leachate under various treatments were compared. Relative to the planting control, EDTA application shortened the time required for Cd, Pb and Cu decontamination by 1.7–5.5 times but led to significantly more leachate (996 vs 1256 mL), indicating the negative influence of the chelate treatment on the species and the surrounding environment. The foliar application of cytokinin can expand the advantage and alleviate the adverse impact of individual EDTA application simultaneously as manifested by the increased biomass yield, less time consumption for purification and decreased leachate volume. Cytokinin accelerated the transpiration rate of the plant proved by the least volume of leachate in individual cytokinin treatment. The major factors for effective phytoremediation were the resistance of species to high concentrations of contaminants and less environmental risks generation during the remediation processes. Therefore, synergistic use of such components provides more efficient decontamination of metals and more security for the environment.

A total of 321 surface soil samples were collected from Huilai County, Guangdong Province, Southern China. Concentrations of 12 metals (Cr, Hg, As, Pb, Ni, Cd, Cu, Zn, Sb, Sn, Ti, and V) were measured. The mean concentrations of As, Pb, Cd, Zn, Sn, and Ti were higher than their corresponding soil background values, especially for As, Cd, and Sn, which were 1.36, 2.50, and 2.77 times of the background values, respectively. And the results of enrichment factor and pollution load index suggested that soil metals in the study area were moderately contaminated, but pollution of As, Cd, and Sn was relatively serious. According to one-way analysis of variance, there were significant differences in concentrations of Hg, As, Pb, Cd, Zn, and Sn between different land use types, indicating that they were associated with the anthropogenic inputs. The potential sources of metals were quantitatively apportioned by positive matrix factorization, and combined with correlation analysis and geostatistical. The results showed that Cr, Ni, Ti, and V mainly originated from natural sources. Lead, Zn, and partially, Cd mainly came from traffic emissions. Arsenic, Cu, and partially, Sb were ascribed to agricultural practices. Mercury, Sn, partially, Cd, and Sb were derived from industrial activities. Their corresponding contributions were 36.88%, 22.14%, 20.87%, and 20.11%, respectively.

In this work, we developed a novel magnetic bimetallic Al/Fe (oxyhydr)oxide adsorbent through a facile and cost-effective method and explored its potential to adsorb fluoride in water. Its synthesis involved corrosion of natural magnetite in aluminium chloride solution, followed by titration with NaOH solution for in-situ synthesis of Al/Fe (oxyhydr)oxide-coated magnetite (Mag@Al2Fe). Characterization data indicated a uniform coating of Al/Fe (oxyhydr)oxide on magnetite, and the resulting composite possessed large specific surface area (∼90 m2/g) and good magnetic property. In batch adsorption experiments, the isotherm and kinetic data fitted well to the Langmuir model and pseudo-second-order model, respectively. The maximum adsorption capacity of Mag@Al2Fe is 26.5 mg/g, which was much higher than natural magnetite (0.44 mg/g). Moreover, this material retained high adsorption capacity toward fluoride within a wide pH range (3.0–8.0) and offered facile magnetic separation from water. Influence of competing ions was also evaluated which showed that the presence of Cl− and NO3− posed negligible interference, while HCO3− and SO42− had negative effects on fluoride adsorption. Thermodynamic investigations revealed that fluoride adsorption was exothermic and spontaneous. The observed increase in solution pH and formation of Al–F and Fe–F bonds (as indicated by XPS analysis) after fluoride adsorption suggested the major adsorption mechanism of ligand exchange. Besides, the adsorption/desorption cycle studies demonstrated the well-retained performance of Mag@Al2Fe for repeated application after regeneration by 0.5 mol/L NaOH solution. Facile synthesis, high defluoridation, lower cost, and quick separation of Mag@Al2Fe indicates its promising potential for drinking water defluoridation.

Concentrations of gaseous elemental mercury (GEM) were continuously monitored from May 2011 to May 2012 at the Wuzhishan State Atmosphere Background Monitoring Station (109°29′30.2″ E, 18°50′11.0″ N) located in Hainan Island. This station is an ideal site for monitoring long-range transport of atmospheric pollutants from mainland China and Southeast Asia to South China Sea. Annual average GEM concentration was 1.58 ± 0.71 ng m−3 during the monitoring period, which was close to background values in the Northern Hemisphere. GEM concentrations showed a clear seasonal variation with relatively higher levels in autumn (1.86 ± 0.55 ng m−3) and winter (1.80 ± 0.62 ng m−3) and lower levels in spring (1.16 ± 0.45 ng m−3) and summer (1.43 ± 0.46 ng m−3). Long-range atmospheric transport dominated by monsoons was a dominant factor influencing the seasonal variations of GEM. The GEM diel trends were related to the wind speed and long-range atmospheric mercury transport. We observed 30 pollution episodes throughout the monitoring period. The analysis of wind direction and backward trajectory suggested that elevated GEM concentrations at the monitoring site were primarily related to the outflows of atmospheric Hg from mainland China and the Indochina peninsula. The △GEM/△CO values also suggested that GEM was significantly affected by the long-range transport from the anthropogenic sources and biomass burning in Asia and Indochina peninsula.

Municipal wastewater treatment plants (MWTPs) serve an essential role in reducing mercury (Hg) pollution. However, few studies quantified the transport and transformation of Hg through MWTPs, particularly plants based on the anaerobic-anoxic-aerobic (A2/O) process. Here, we present a mass balance for total mercury (THg) and total methylmercury (TMeHg) at the plant, and investigate the influence of pH, temperature, and dissolved oxygen on the occurrence and fate of methylmercury (MeHg) in the system. The concentrations of the THg and TMeHg in the raw sewage were 40.3 ± 26.6 ng/L (4.3 ± 2.7 g/day) and 1.9 ± 0.6 ng/L (193 ± 58 mg/day), respectively. Their concentrations in the plant's effluent water were 7.4 ± 1.5 ng/L (0.74 ± 0.2 g/day) and 0.04 ± 0.01 ng/L (3.9 ± 1.0 mg/day), corresponding to decreases of ~82% for THg and ~98% for TMeHg. Within the plant, only ~10% of the THg was removed with primary sedimentation, as Hg in the raw sewage was predominately in dissolved form. In contrast, a significant portion of TMeHg (~43%) was associated with incoming particulate matter. Much of the remaining Hg was removed in subsequent A2/O process and secondary clarifiers, with a ~78% of the THg entering the plant transferring to the dewatered sludge (concentration 1.05 ± 0.28 μg/g; 3.2 ± 0.8 g/day). These same steps decreased TMeHg in the water by ~95%, with 90% TMeHg degradation. In addition, the most important factor that impacted the variation of TMeHg concentrations was pH, then was temperature. Dissolved oxygen showed no relationship with TMeHg and DMeHg. Overall, this study demonstrates that A2/O MWTPs effectively remove MeHg from wastewater, however, sludge remains an important potential source of Hg to the environment.

An extensive survey was conducted in the study to determine the spatial distribution and possible sources of As and heavy metals in the agricultural soils in the Shunde, a representative area in the Pearl River Delta, China. A total of 238 topsoil samples were collected (0–20 cm) from the study area. The levels of Cd, Co and Ni were then analyzed by inductively coupled plasma mass spectrometry, while the content of Cr was determined by inductively coupled plasma optical emission spectrometry, and As and Hg concentrations were analyzed by atomic fluorescence spectrophotometry. The results showed that the mean concentrations of As, Cd, Co, Cr, Hg and Ni are 16.08, 0.60, 16.76, 78.87, 0.38 and 33.45 mg/kg, respectively. The concentrations of Cd and Hg were far higher than their background values of Pearl River Delta topsoil, and in the study area, 2.10%, 90.86%, 43.27% and 18.07% samples for As, Cd, Hg and Ni were higher than the guideline values of the Chinese Environmental Quality Standard for Soils, especially for Cd and Hg, which are 2.00 and 1.27 times the guide values, respectively. Multivariate and geostatistical analyses suggested that soil Cr, Ni, and Zn had a lithogenic origin. Whereas, soil contamination of Cd and As was mainly related to industrial and agronomic practices, and the main sources of Hg were coal burning exhausts, industrial fumes, domestic waste, and vehicle exhausts. The origin identification of As and heavy metals in agricultural soils is a basis for undertaking appropriate action to reduce their inputs.

A total of 118 of agricultural soil and 43 of vegetable samples were collected from Dongguan City, Guangdong, China. The spatial distribution, sources, accumulation characteristics and potential risk of heavy metals in the agricultural soils and vegetables were depicted in details by three different approaches, including total contents of eight metal elements in soils and vegetables, GIS maps and multivariate analysis of heavy metals in soils in the study. The results show that there are higher accumulation of heavy metals such as Cu, Zn, Ni, Pb, Cd and Hg in agricultural soils, and the contents of Pb (65.38 mg kg−2) and Hg (0.24 mg kg−2) are 1.82 and 2.82 times of the background contents of the corresponding heavy metals in soils of Guangdong Province, respectively. There are about 3.4% of Cu, 5.9% of Ni, 1.7% of Cd and 28% of Hg in all collected soil samples from all investigated sites which have overran the contents for heavy metals of the China Environmental Quality Standard for Soils (GB15618-1995, Grade II). The pollution characteristics of multi-metals in soils are mainly reflected by Hg. There are different sources to eight metal elements in soils, Cu, Zn, Ni, Cr and As are predominantly derived from parent materials, and Pb, Hg and Cd are affected by anthropogenic activities. The spatial distribution shows that the Cu, Zn, Ni, Cr, Pb, As and Hg contents of agricultural soils are high in the west and low in the east, and Cd contents are high in the northwest, southeast and low in the southwest in Dongguan. The ratios of vegetable samples which Ni, Pb and As concentrations higher than the Maximum Levels of Contaminants in Foods (GB2762-2005) are 4.7%, 16.3% and 48.8%, respectively. The order of bio-concentration factors (BCF) of heavy metals in vegetables is Cd > Zn > Cu > As > Ni > Hg > Cr > Pb. It is necessary to focus on potential risk of heavy metals for food safety and human’s health from agricultural soils and vegetables in Dongguan City, Guangdong Province.

Heavy metal contamination due to mining activity is a global major concern because of its potential health risks to local inhabitants. In the present study, we investigated the levels of Cd, Cu, Pb and As in soil, crop, well water and fish samples collected from the vicinity of the Tonglushan mine in Hubei, China, and evaluated potential health risks among local residents. Results indicate that soils near the mine were heavily contaminated with Cd (2.59 mg kg −1 ), Cu (386 mg kg −1 ), Pb (120 mg kg −1 ) and As (35.4 mg kg −1 ), and exceeded the soil quality standard values of Cd and Cu contamination. The concentrations of Cd, Cu, Pb and As in crop samples grown in mine-affected soils were significantly higher than those of the reference soils. The concentrations of Cd and As in most vegetables grown in mine-affected soils exceeded the maximum allowable level (MAL). The Cd, Pb and As concentration in rice grain collected from mine-affected soils were 2.95, 1.85 and 2.07-fold higher than the MAL, respectively. The concentrations of Cd and As in fish muscle from the mine-affected area were above national MAL in 61% and 34% of analyzed samples, respectively. All measured heavy metals except Pb were significantly greater in well water in the mine-affected area than those in the reference areas. The average estimated daily intakes of Cd and As were beyond the provisional tolerable daily intake, respectively. The intake of rice was identified as a major contributor (⩾72%) to the estimated daily intake among the residents.