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Following circular economy principles, the reuse or recycling of saturated adsorbents (SAs or adsorbate-laden adsorbents) into a low-cost engineered product is a valuable alternative to eliminate secondary pollution after adsorption. This review evaluates the application of SAs for the generation of products that can serve as (i) antimicrobial agents or disinfectants, (ii) materials for civil construction, (iii) catalysts, (iv) fertilizers, and (v) secondary adsorbents. The importance of SAs configuration in terms of functional groups, surface area and pore morphology played a crucial role in their reutilization. The SAs-laden silver ions (Ag

Per- and polyfluoroalkyl substances (PFAS) are potential human carcinogens that have been ubiquitously detected in drinking water sources. Ion exchange (IX) resins offer promising potential for the treatment of water sources impacted by high natural organic matter (NOM) and PFAS concentrations. Several kinetic models such as the pseudo-first-order (PFO), pseudo-second-order (PSO) and intraparticle diffusion (ID) have been investigated to examine the PFAS uptake kinetics on IX resins. However, the kinetic parameters are strongly impacted by the sorption test conditions, especially the sorbate-to-sorbent ratio, which were highly variable in past studies, resulting in several discrepancies when comparing published data. This study examined the use of the homogenous surface diffusion model (HSDM) coupled with the equivalent background concentration (EBC) model as an approach to describe competitive uptakes of regulated long- and short-chain PFAS, NOM, and inorganic ions (such as sulphate and nitrate) with IX resins. Kinetic studies confirmed surface diffusion as the rate-limiting step in NOM-rich waters (Biot number >30), while the multicomponent equilibrium model demonstrated that the initial NOM concentration of approximately 0.35–0.95 μmol L−1 (C0 = 5 mg C per L) competed with PFAS for active exchange sites. More importantly, the HSDM (R2 > 0.98)/EBC (R2 > 0.95) models provided an adequate fit to describe PFAS removal in a recycled wastewater.

Zwitterionic per- and polyfluoroalkyl substances are increasingly detected in aquatic environments. The magnitude of their concentration and increased frequency of detection worldwide raise questions on their presence in drinking water and associated health risk. Scientific knowledge on the identification of treatment technologies to effectively capture such zwitterionic PFAS from contaminated water sources remains largely unknown. In this study, we investigated the application of anionic organic scavenger ion exchange (IX) resins (A860), nonionic IX resins (XAD 4 and XAD 7), PFAS-specific resins (A694 and A592), and Ti

Ion exchange (IX) process is increasingly used as a cost-effective treatment for the removal of natural organic matter (NOM) from drinking water. However, fundamental studies under the influence of variable NOM characteristics and inorganic anions have often been overlooked. This is important given NOM characteristics (such as charge density and molecular weight) and inorganic anions concentrations are geographically and seasonally variable. We examined the performance of a strongly basic IX resin for the simultaneous removal of NOM, inorganic ions and micropollutants (Per- and polyfluoroalkyl substances (PFAS) and algal toxins), from different surface and recycled waters. The results indicated >70% removal of NOM for ∼20,000 Bed Volumes (BV) with an uptake of NOM fractions following the order of their respective charge densities. IX pore blockage and consequent site reduction was observed in the presence of higher molecular weight NOM fractions (breakthrough ∼7,000 BV). Moreover, NOM and inorganic ions breakthrough corresponded to ∼85–90% site occupancy (in meq) in the absence of pore blocking compounds. IX also provided simultaneous removal of inorganic ions (>90%) and charged micropollutants. Complete removals of Microcystin-LR and multiple long- and short-chained PFAS were achieved at environmentally relevant concentrations with dosages of 1,000 mg/L (or 4.5 mL/L) or higher.

Microcystin-LR (MCLR) is the most commonly encountered toxic microcystin variant. MCLR is usually present along with common surface water constituents such as inorganic ions and natural organic matter (NOM) which compete with MCLR for active sites during ion exchange (IX) process. Consequently, development of a multicomponent competitive model is essential for practical IX applications. This is critically important given that the NOM characteristics (charge density and molecular weight distribution) and inorganic ions concentrations are spatially variable and can change seasonally. In the present study, a systematic study was carried out into the multicomponent interactions of IX resin with inorganic ions and NOM during the MCLR removal process. This involved evaluation of MCLR removal in a single component system (i.e., MCLR only), a dual component system (MCLR and one other contaminant such as NOM), and a multiple component system (MCLR with NOM and different inorganic ions present in natural waters). A comprehensive understanding of the dynamic adsorption behavior showed that the experimental data for single component systems agree well with a Freundlich isotherm. For multicomponent interactions, the Equivalent Background Concentration (EBC) model which is derived from the Ideal Adsorption Solution Theory (IAST) provided the best correlation with the experimental data in natural waters. The concentrations of competing NOM and inorganic ions estimated by the EBC model were

Cyanobacterial blooms are becoming a serious challenge across the globe due to changing climate and rainfall patterns as a consequence of human activities. In the present study, the fundamental interactions involved during the removal of Microcystin-LR (MCLR), one of the most commonly occurring cyanobacterial toxins, were investigated by employing strongly basic anion exchange (IX) resins. Several factors including the stoichiometric coefficients, competitive fractions and solute affinities were determined under various concentrations of inorganic ions and natural organic matter. The results indicated that suphates were the most competitive fractions with high affinity (α (affinity coefficient) values ~ 9) followed by nitrates (α ~ 4.7) and NOM fractions (α ~ 4.5, p 0.05). The Equivalent Background Concentration Mode (EBC), that arises from the Ideal Adsorption Solution Theory (IAST), indicated a competitive fraction of ~2 μeq/L NOM, which approximates to10% of the initial NOM concentrations, indicating a small fraction of the NOM resulting in the competitive effect. Further, studies with natural surface waters indicated that the MCLR uptake could be modeled using the IAST-EBC model and the IX resin could simultaneously removal of90% of NOM, inorganic ions and MCLR at resin dosages of 3.6 meq/L or higher.

Perfluoroalkyl substances (PFAS) are drinking water contaminants of emerging concern due to their persistence in the environment and tendency to bio-accumulate. Although anionic ion exchange (IX) resins offer a cost-effective alternative for removing PFAS from natural waters, the studies on PFAS removal by IX under the influence of variable characteristics of the organic compounds present in the natural water sources, have been overlooked. This is critically important given that the organic matter (OM) characteristics are spatially variable and can change seasonally. In the present study, a strongly basic anion exchange resin was used to remove two of the most persistent PFAS, namely per-fluorooctanoic acid (PFOA) and per-fluorooctanesulfonic acid (PFOS). Factors influencing the uptake behavior included the PFOA and PFOS concentrations, resin dosage, and background OM characteristics, more specifically the charge density and molecular weight distribution of source water OM. The equivalent background concentration (EBC) was employed to evaluate the competitive uptake between OM and PFAS. Experimental data were fitted to different mathematical and physical models to evaluate the competitive interactions. Further, IX was able to achieve complete PFAS removal with simultaneous >60% dissolved organic carbon (DOC) removal. Evidence of size exclusion and pore blockage was also observed in the presence of humics and larger molecular weight organic fractions. Results of this study indicate that IX exhibits great potential for simultaneous OM and PFAS removal for drinking and potable water reuse applications.

MXenes are a new type of two-dimensional (2D) material which are rapidly gaining traction for a range of environmental, chemical and medical applications. MXenes and MXene-composites exhibit high surface area, superlative chemical stability, thermal conductivity, hydrophilicity and are environmentally compatible. Consequently, MXenes have been successfully employed for hydrogen storage, semiconductor manufacture and lithium ion batteries. In recent years, MXenes have been utilized in numerous environmental applications for treating contaminated surface waters, ground and industrial/ municipal wastewaters and for desalination, often outperforming conventional materials in each field. MXene-composites can adsorb multiple organic and inorganic contaminants, and undergo Faradaic capacitive deionization (CDI) when utilized for electrochemical applications. This approach allows for a significant decrease in the energy demand by overcoming the concentration polarization limitation of conventional CDI electrodes, offering a solution for low-energy desalination of brackish waters. This article presents a state-of-the-art review on water treatment and desalination applications of MXenes and MXene-composites. An investigation into the kinetics and isotherms is presented, as well as the impact of water constituents and operating conditions are also discussed. The applications of MXenes for CDI, pervaporation desalination and solar thermal desalination are also examined based on the reviewed literature. The effects of the water composition and operational protocols on the regeneration efficacy and long-term usage are also highlighted.

Per- and poly-fluoroalkyl substances (PFAS) represent a large family of anthropogenic organic compounds with a wide range of industrial and commercial applications. PFAS have become a global concern due to their toxicity and bio-accumulative properties. PFAS species have been ubiquitously detected in natural waters, wastewaters, sludge, and aquatic and terrestrial species which are anionic, zwitterionic and neutral. The ion exchange (IX) process for PFAS removal is an efficient technology for the remediation of PFAS-laden surface, ground and effluent wastewaters. This approach is more effective towards eliminating emerging short-chain PFAS which are not removed by carbon-based adsorption processes. This article presents a state-of-the-art review of PFAS removal from water via IX process. The evaluation and comparison of various IX resins in terms of kinetics and isotherms is presented. Literature data indicates that IX isotherm uptake capacity for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) can range up to 5 mmol/g on commercially available IX resins such as IRA 958 and IRA 67. The mechanism involved in the PFAS uptake process, such as diffusion, electrostatic interactions and hydrophobic effects are discussed. The effects of the eluent variability on the regeneration efficacy are also highlighted and the effect of single-use vs reuse for newly developed PFAS-specific IX resins are also examined based on the reviewed literature.

Treatment technologies such as ion exchange (IX) process exhibit promising potentials for the removal of toxic per- and poly-fluoroalkyl substances (PFAS) from natural waters. In recent years, industries have started manufacturing PFAS-specific resins which are typically operated in a single use-and-dispose mode until exhaustion. However, this increases the resin demand and the consequent operational cost and environmental burden of the IX process. In this study, the performance of a PFAS-specific resin (A592) was compared with that of a regenerative organic scavenger resin (A860) which is traditionally employed for dissolved organic matter (DOM) and micorpollutant removal. Comparative studies were performed to examine the removal of multiple long- and short-chain carboxylic, sulfonic, precursor and emerging PFAS (including GenX) from synthetic and natural waters. The A592 resin exhibited faster uptake kinetics for PFAS while simultaneously removing 10–15% of DOM. The A860 resin removed ~60–70% of DOM; however, it required approximately 3-fold higher contact times for achieving the same degree of PFAS removal when compared to the PFAS-specific resin. The resin breakthrough (Ctreated (PFAS) > 70 ng/L) was observed around 125,000 ± 5000 bed volumes (BVs) for the PFAS-specific resin (via multiple loading tests), while it ranged between 15,000–27,000 BVs for the organic scavenger. Yet, a mass balance on PFAS and DOM removal indicated ~90–98% site saturation (in milli-equivalents (meqs)) on both IX resins before exhaustion. More importantly, the regenerated organic scavenger resin (A860) exhibited PFAS and DOM removal capabilities for longer operational BVs when compared to A592 operated in a single-use-mode in natural waters.

We present the first study investigating optimized regeneration strategies for anionic ion exchange (IX) resins during the removal of persistent per- and poly-fluoroalkyl substances (PFAS, including GenX) from surface and treated wastewater effluents. IX regeneration studies are of critical importance from environmental perspectives. Specifically, the knowledge is essential for water utilities who presently operate IX (for PFAS removal) in a single use-and-dispose mode. In this study, legacy PFAS such as PFOA/PFOS were tested along with other harmful short-chained PFAS (PFBA/PFBS) and other toxic perfluorinated substitutes (GenX). Studies were performed on synthetic water (spiked with Suwannee River Natural Organic Matter (SRNOM), Fulvic Acid (SRFA) and Humic Acid (SRHA)), surface water, and wastewater effluents, and the regeneration was performed in batch stirred reactors. The resin service life with and without regeneration was investigated in the presence of background organic matter. In ultra-pure waters, all PFAS (C0 ∼10 μg/L, concentrations similar to that of natural waters) were effectively removed for >100,000 Bed Volume (BV) of operation. This was reduced to ∼23,500 BV in the presence of SRNOM (C0 = 5 mg C/L), 20,500 BV in SRFA and 8500 BV in SRHA, after which the saturated resins required regeneration. More importantly, all resin breakthrough (PFAS> 70 ng/L) corresponded to > 90% resin site saturation (in meqs), an essential information for optimizing IX loading. The competitive dissolved organic matter (DOM) fractions were estimated to be approximately 5–9% of the initial DOC, as estimated by the IAST-EBC model. Finally, it was identified that IX regeneration efficiency improved with increasing brine contact time but effectiveness plateaued for brine concentrations above 10% (W/V). Nonetheless, a regeneration with 10% NaCl solution with a contact time of 2 h was found to be optimal for IX operations in synthetic and natural waters. Therefore, this study provides key knowledge essential for the scientific community and the water industry on optimizing IX operational parameters for DOM and PFAS removal and would be highly valuable for systems which presently operate IX in a use-and-dispose mode.

Microcystins are the most commonly occurring cyanotoxins, and have been extensively studied across the globe. In the present study, a strongly basic anion exchange resin was employed to investigate the removal of Microcystin-LR (MCLR), one of the most toxic microcystin variants. Factors influencing the uptake behavior included the MCLR and resin concentrations, resin dosage, and natural organic matter (NOM) characteristics, specifically, the charge density and molecular weight distribution of source water NOM. Equivalent background concentration (EBC) was employed to evaluate the competitive uptake between NOM and MCLR. The experimental data were compared with different mathematical and physical models and pore diffusion was determined as the rate-limiting step. The resin dose/solute concentration ratio played a key role in the MCLR uptake process and MCLR removal was attributed primarily to electrostatic attractions. Charge density and molecular weight distribution of the background NOM fractions played a major role in MCLR removal at lower resin dosages (200 mg/L ∼ 1 mL/L and below), where a competitive uptake was observed due to the limited exchange sites. Further, evidences of pore blockage and site reduction were also observed in the presence of humics and larger molecular weight organic fractions, where a four-fold reduction in the MCLR uptake was observed. Comparable results were obtained for laboratory studies on synthetic laboratory water and surface water under similar conditions. Given their excellent performance and low cost, anion exchange resins are expected to present promising potentials for applications involving the removal of removal of algal toxins and NOM from surface waters.

This study investigated the efficiency of a strongly basic macroporous anion exchange resin for the co-removal of Microcystin-LR (MCLR) and natural organic matter (NOM) in waters affected by toxic algal blooms. Environmental factors influencing the uptake behavior included MCLR and resin concentrations, NOM and anionic species, specifically nitrate, sulphate and bicarbonate. A860 resin exhibited an excellent adsorption capacity of 3800 μg/g; more than 60% of the MCLR removal was achieved within 10 min with a resin dosage of 200 mg/L (∼1 mL/L). Further, kinetic studies revealed that the overall removal of MCLR is influenced by both external diffusion and intra-particle diffusion. Increasing NOM concentration resulted in a significant reduction of MCLR uptake, especially at lower resin dosages, where a competitive uptake between the charged NOM fractions and MCLR was observed due to limited active sites. In addition, MCLR uptake was significantly reduced in the presence of sulphate and nitrate in the water matrix. Moreover, performance of the resin proved to be stable from one regeneration cycle to another. Approximately 80% of MCLR and 50% of dissolved organic carbon (DOC) were recovered in the regenerated brine. Evidences of resin saturation and site reduction were also observed after 2000 bed volumes (BV) of operation. For all the investigated water matrices, a resin dosage of 1000 mg/L (∼4.5 mL/L) was sufficient to lower MCLR concentration from 100 μg/L to below the World Health Organization guideline of 1 μg/L, while simultaneously providing more than 80% NOM removal.

UV based advanced oxidation exhibits promising potential for the degradation of cyanobacterial toxins from natural waters. However, degradation is hindered by the presence of natural organic matter (NOM), which absorbs both 185 nm and 254 nm photons and scavenges hydroxyl radical (•OH), affecting mechanisms of UV/vacuum UV (VUV) degradation and requiring higher fluences (exposure times) to achieve microcystin reduction. In addition to obstructing UV/VUV degradation, NOM is associated with the formation of harmful disinfection by-products (DBPs) with drinking and recycled waters. Hence, technologies that are capable of removing NOM are desirable. In this study, we investigated the synergistic application of ion exchange (IX) resins and VUV for the removal of NOM and Microcystin-LR (MCLR) from natural waters. A pre-treatment with 1 mL/L dosage of IX resins removed >80% of the dissolved organic carbon (DOC) and UV254 absorbing compounds. This increased the MCLR degradation rates (up to three folds) in the tested surface waters. A progressive analysis on the degradation products indicated subsequent degradation of the toxic ADDA moiety of MCLR confirmed by the formation of compounds with a specific mass to charge ratio (m/z) of 835.5 855.3 and 791.4. More importantly, pre-treatment with IX resulted in reducing VUV’s electrical energy per order (EEO) by up to four folds and the overall chlorine demand by eight folds for surface waters. Hence, the results of this study indicate that a combined IX-VUV will be highly effective at reducing microcystins in impacted natural waters.

Carcinogenic GenX chemicals, heptafluoropropylene-oxide-dimer-acid (HFPO-DA), have been recently detected in surface, ground and recycled water sources worldwide. However, GenX removals under the influence of variable characteristics of the organic and inorganic compounds present in the natural water sources, have often been overlooked in scientific literature. This is critically important given that the ionic composition and characteristics of organic matter in natural waters are spatially and seasonally variable. A strongly basic anion exchange (IX) resin was used to remove GenX and two other perfluorinated ether acids (PFEAS) from natural surface and recycled water sources. Factors influencing the uptake behavior included the PFEAS concentrations, resin dosage, and background anion characteristics. The equivalent background compound was employed to evaluate the competitive uptake between natural organic matter (NOM), inorganic ions and PFEAS in natural water matrices. Experimental data were compared with different mathematical and physical models and it was depicted that approximately 4-6% of the initial NOM competed with PFEAS for active exchange sites. Further, IX was able to achieve complete PFEAS removal (Cfinal 60% NOM and >80% inorganic ions. Results of this study indicate that IX exhibits great potential for PFEAS removal from natural drinking water sources.