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Mantle degassing transect across different tectonic units within a plate convergent setting has been well documented for oceanic convergent margins by systematic changes in geochemistry (e.g., 3He/4He, δ13C, and CO2/3He) of hydrothermal gases. However, little is known about spatial variations in volatile geochemistry across a continental convergent margin. In this study, we identify a mantle degassing transect in the southeastern Tibetan Plateau using He-CO2 systematics of hydrothermal gases, which extends from India-Asia continental convergent margin to intra-continent extensional region. δ13C-CO2 (−11.8‰ to −3.1‰) and CO2/3He (1.7 × 108 to 7.1 × 1011) values of hydrothermal gases show large variations that are consistent with modification by secondary physico-chemical processes, such as multi-component mixing, hydrothermal degassing, and calcite precipitation. Three levels of He degassing can be recognized based on 3He/4He dataset (0.01–5.87 RA) of the hydrothermal gas samples and their distances to volcanic centers. A magmatic level He degassing (35–74% mantle He) is found near active and/or Quaternary volcanoes fed by mantle-derived magmas. With increasing distance to volcanic centers, the outgassed magmatic volatiles are gradually diluted by crustal components (e.g., radiogenic 4He), defining a transitional level He degassing (13–33% mantle He). The 3He/4He values (8.16–8.48 RA) of olivine phenocrysts indicate a MORB (mid-ocean ridge basalts)-type mantle source for the magmatic and transitional levels of He degassing that are localized in Quaternary volcanic fields. In contrast, a background level He degassing (

A detailed petrological study is presented to constrain the origin of a suite of alkali olivine basalt and hawaiite (>5 wt% MgO) lavas that were erupted in a rift zone within the western Mexican arc (Trans-Mexican Volcanic Belt), adjacent to the Sangangüey andesitic stratovolcano, together with more evolved lavas (mugearites and benmoreites; 9 wt%) SB crystallized at higher temperatures and lower melt-water contents (0–1.3 wt%) compared to high-MgO arc basalts (≤5.7 wt% H2O) erupted in the west-central Mexican arc. The Sangangüey lavas with 5–8 wt% MgO display evidence of mixing between high-MgO alkali olivine basalts and low-MgO mugearites. It is proposed that the unique composition of the mugearites (i.e., low SiO2 contents and elevated FeO and TiO2 contents) is the result of partial melting of mafic lower crust driven by the influx of high-MgO intraplate basalts under relatively hot, dry, and reduced conditions. On the basis of crystal textures and compositional zoning patterns, it is shown that both phenocryst growth and magma mixing occurred rapidly, most likely during ascent along fractures, and not slowly during prolonged storage in a crustal magma chamber.

The Cretaceous Ngaou Boh anorogenic complex (NBAC) located in the far North Adamawa Plateau, the centre domain of the Cameroon Line constitutes a plutonic-volcanic ring association. The whole rock K-Ar datation yields a crystallization age of ca. 74 Ma. Plutonic rocks comprise abundant alkali feldspar granites, scarce clinopyroxene-amphibole gabbros and alkali feldspar syenites. Alkali feldspar granites are leucocratic, coarse to fine-grained; quartz and K-feldspars are the major rock-forming mineral, besides minor oligoclase, biotite and accessory phases as sphene, zircon and opaques. Alkali feldspar syenites are mesocratic coarse-grained, mainly composed of K-feldspars with small amounts of quartz and biotite. Volcanic rocks consist of a basanite-trachyte-rhyolite suite. Basanites contain olivine and diopside phenocrysts and a groundmass essentially composed of plagioclase and titanomagnetite. Biotite-clinopyroxene trachytes and clinopyroxene-amphibole rhyolites have an almost homogeneous modal composition, mainly made up of sanidine and anorthoclase microliths, scarce phenocrysts of quartz, and minor crystals of biotite, clinopyroxene (augite) amphibole (pargasite, sandagaite); Fe-Ti oxides (ilmenite, titanomagnetite) and fibreglass are often isolated in the groundmass. Plutonic rocks are alkaline, weakly metaluminous with some alkali feldspar granites displaying agpaitic or peralkaline feature. Incompatible Trace elements (HFSE and LILE) distribution and chondrite-normalized REE patterns evidence a significant petrogenetic link between clinopyroxene-amphibole gabbros, alkali feldspar syenites and alkali feldspar granites. All the analysed samples are enriched in incompatible elements, indicating melts from spinel and garnet-bearing mantle source close to OIB component. Indeed, the (Tb/Yb)N ratios of both basanites (2.3-2.5) and clinopyroxene-amphibole gabbros (1.4-1.9) suggest different parental magma sources. Alkali feldspar granites appear as residue of magma differentiation led by crystal fractionation of liquid derived from the partial melting of spinel peridotite mantle. Clinopyroxene-amphibole rhyolites and biotite-clinopyroxene trachytes (Mg#=0.0-15.4) derive through fractional crystallization from basanites (Mg#=64.3-60.1), the most primitive mafic parental melt. Both plutonic rocks and lavas trends evidence a bimodality highlighted by a pronounced “Daly gap”.

The Cenozoic basalts exposed in Bo Phloi Gem Field, Kanchanaburi Province, western Thailand are a host to different gem materials (e.g., sapphire, black spinel, black pyroxene and zircon) as well as other xenocrysts and xenoliths from the deep-seated formations onto the earth surface. However, only felsic xenoliths have never been investigated and reported in detail though they are in fact significant evidence of ancient tectonic processes of this area. In this study, the felsic xenoliths were sampled and classified, on the basis of petrochemistry, into granite, syenogranite, and syenite. However, they contain similar mineral assemblages including essentials of quartz, K-feldspar, and plagioclase with different proportions and accessories of biotite, zircon, and opaque minerals. Moreover, large phenocrysts of K-feldspar and plagioclase commonly present as a primary texture which are frequently corroded and replaced by ‘sieved texture’ with secondary cumulative fringe of tiny feldspar and quartz. These secondary textures clearly indicate quenching after re-heating during transportation by basaltic magma. Geochemical analyses indicate that the alkaline and peraluminous magma show enrichment of Rb and depletion of Ba, Nb, Ta, Ti with steep slope of LREE/HREE enrichment patterns. These evidences suggest low-degree partial melting of crustal materials related to the collisional S-type granite magmatism. In addition, U-Pb dating of zircon from a felsic xenolith yields 211.6±1.3 Ma comparable to the Late Triassic magmatism of the central belt granite in this region which is resulted from the collision between Sibumasu and Indochina terranes.

Inclusions of basaltic melt trapped inside of olivine phenocrysts during igneous crystallization provide a rich, crystal-scale record of magmatic processes ranging from mantle melting to ascent, eruption, and quenching of magma during volcanic eruptions. Melt inclusions are particularly valuable for retaining information on volatiles such as H2O and CO2 that are normally lost by vesiculation and degassing as magma ascends and erupts. However, the record preserved in melt inclusions can be variably obscured by postentrapment processes, and thus melt inclusion research requires careful evaluation of the effects of such processes. Here we review processes by which melt inclusions are trapped and modified after trapping, describe new opportunities for studying the rates of magmatic and volcanic processes over a range of timescales using the kinetics of post-trapping processes, and describe recent developments in the use of volatile contents of melt inclusions to improve our understanding of how volcanoes work. ▪ Inclusions of silicate melt (magma) trapped inside of crystals formed by magma crystallization provide a rich, detailed record of what happens beneath volcanoes. ▪ These inclusions record information ranging from how magma forms deep inside Earth to its final hours as it ascends to the surface and erupts. ▪ The melt inclusion record, however, is complex and hazy because of many processes that modify the inclusions after they become trapped in crystals. ▪ Melt inclusions provide a primary archive of dissolved gases in magma, which are the key ingredients that make volcanoes erupt explosively.

Oxygen isotopes are used to examine the well-documented magmatic evolution of alkaline volcanic rocks at The Pleiades in northern Victoria Land (NVL), Antarctica. Oxygen isotopes were measured in olivine, clinopyroxene, and plagioclase phenocrysts to better understand the origin and evolution of the sodic and potassic differentiation lineages. The volcanic rocks at The Pleiades evolved from a parental basanite by fractional crystallization in crustal magma chambers. Olivine which crystallizes first in the mafic magmas provides the initial oxygen isotope composition of the magmatic lineages. The δ18OOL values for the mafic lavas in the sodic lineage are lower than the potassic lineage. The primary melt derived from the metasomatized lithospheric mantle may have consumed a low-δ18O amphibole metasome. Subsequently, the melt would have evolved to the normal-δ18O potassic lineage magma by a large contribution from surrounding peridotite. In contrast, the sodic lineage magma might preserve low-δ18O characteristics because of insufficient reaction with the surrounding mantle peridotite. Intermediate rocks of the potassic lineage exhibit a wide variation in their oxygen isotope compositions and it deviates from the theoretical normal-δ18O trend. Hence, variable δ18OOL values of the intermediate rocks suggest that high-δ18O recorded in olivine could be reconciled with an assimilation of crustal rocks in NVL, and hydrothermally altered material may have contributed to low-δ18O signature of the olivines.

Evaluation of the petrogenetic history of continental flood basalt using mineral–chemical data has been sparingly used for several flood basalt provinces of the world. For the Deccan flood basalts, such attempts are still rudimentary. The present contribution highlights several facets of petrogenesis of the Eastern Deccan Volcanic Province using details of constituent phases including glass. The present-study area around Khandwa (21°49′N, 76°21′E) indicates the presence of three distinct lava flows, which were identified on the basis of physical volcanological features based on a three-tier classification. Moreover, the occasional presence of chilled dykes and feeder dykes has been documented. The lava succession rests above (apparent) cumulate gabbro basement. The lava flows, in general, are characterized by dominant pyroxene (mostly augite, locally pigeonite) and plagioclase, opaque (magnetite and ilmenite) and glass, whereas olivine is rare. Both of these principal mineral phases (namely, plagioclase and pyroxene) occur both as phenocrysts and groundmass, while opaque phases occur only as groundmass. Pyroxene and plagioclase are generally zoned due to the changing milieu of crystallization conditions. Pyroxene thermometry data show the equilibration temperature range of 1050–1300 °C. Except for two samples of Flow II and one sample of chilled zone, the pyroxene thermometry data are broadly similar to that obtained from magnetite–ilmenite thermometry. As expected, deduced glass thermometric data reveal a relatively higher temperature. Crystallization history of parental magma was quantitatively modeled using Petrolog 3 software. The results indicate that the parental magma underwent both equilibrium and fractional crystallization (for example initially crystallized olivine reacted with ambient liquid to give rise to pyroxene). Phenocrystal and groundmass plagioclase and pyroxene show distinct patterns of compositional zoning corresponding to fluctuating physical parameters within the magma. Some of the glass [especially from the chilled dyke, feeder dyke, and Upper Colonnade Zone (UCZ) of flow II and flow III] represents ‘higher magnitude pressure ambience’ (fossilized glass) which is distinct from ‘surficial glass’ caused by equilibrium quenching. The glass and pyroxene compositions (using tectonic discrimination diagrams) suggest a non-orogenic continental setting of the parent magma. It is concluded that the studied Deccan volcanism shows a complex interplay of repeated pulses of magma ascent, fluctuation of crystallization condition, effervescence, and local magma mixing.

Harvesting quantitative fO2 information from synchrotron μ-XANES measurements of Cr2+/ΣCr in olivine phenocrysts requires robust thermodynamic or empirical models that can accurately predict Cr2+/ΣCr in basaltic liquids as a function of fO2, temperature, and liquid chemistry. We present the results from a combined experimental-XANES study designed to illuminate how evolving liquid chemistry and decreasing temperature influence the equilibrium Cr2+/ΣCr ratios in crystallizing basaltic liquids. The Cr valence dataset produced from these experiments was fit with a symmetric regular solution model; this fitting generated a model equation that predicts the Cr2+/ΣCr in basaltic magmas. Using MELTS in conjunction with the newly calibrated Cr valence model, we calculated the Cr2+/ΣCr of a tholeiitic liquid undergoing isobaric equilibrium crystallization at 2.5 °C intervals. The modeling results indicate that Cr2+/ΣCr evolves dynamically in crystallizing liquids composition and may be partially decoupled from bona fide changes in magmatic fO2. These calculations suggest that the increasing iron content of the residual liquid is the most influential factor influencing the Cr2+/ΣCr of the residual liquid. Olivine normative tholeiitic liquids following a liquid line of descent parallel to an oxygen fugacity buffer curve experience significant decreases in the equilibrium Cr2+/ΣCr of their residual liquids. Our modeling also demonstrates that Cr2+/ΣCr values preserved in early olivine phenocrysts indeed reflect the magmatic fO2 conditions under which they grew; however, the effects of magmatic fO2 are also superimposed on the underlying influences of temperature and melt chemistry.

Aggregates of corundum crystals with skeletal to hopper morphology occur in pyroclastic rocks erupted from Cretaceous basaltic volcanoes on Mt Carmel, N. Israel. The rapid growth of the crystals trapped volumes of the parental Al2O3-supersaturated melt; phenocrysts of tistarite (Ti2O3) in the trapped melts indicate crystallization at oxygen fugacities 6–7 log units below the Iron-Wüstite buffer (fO2 = ΔIW − 6 to − 7), induced by fluxes of mantle-derived CH4-H2 fluids. Cathodoluminescence images reveal growth zoning within the individual crystals of the aggregates, related to the substitution of Ti3+ in the corundum structure. Ti contents are 2 wt%. Numerical modelling indicates that the first skeletal crystals grew in an open system, from a moving magma. The subsequent linear increase in Ti reflects growth in a partially closed system, with decreasing porosity; the exponential increase in Ti close to melt pockets reflects closed-system growth, leading to dramatic increases in incompatible-element concentrations in the residual melts. We suggest that the corundum aggregates grew in melt/fluid conduits; diffusion modelling implies timescales of days to years before crystallization was terminated by explosive eruption. These processes probably operate in explosive volcanic systems in several tectonic settings.

Alkaline basalts of Bafang and its environs are consisted of feldspars, olivines, pyroxenes and oxides which appear as phenocrysts, microphenocrysts and microcrysts. Feldspars are plagioclases (An67.97-15.84Ab69.19-30.43Or20.59-1.51) and anorthoclases (Ab68.11-61.20Or33.87-20.91An10.98-4.93). Plagioclases are the most abundant amount these feldspars. Anorthoclases appear only in mugearite (BAF 3 and BAF 37) the most differentiated of the studied alkaline-basalts. In High Magnesian basalt, (HMg-B) plagioclases are labradorites (An67.97-59.30Ab38.74-30.43Or2.75-1.60) and sanidine (An45.44-31.82Ab62.66-51.79Or5.52-2.77), whereas in Low Magnesian basalt (LMg-B) there are labrador (An67.4.75-51.96Ab44.98-33.72Or3.06-1.51), andesine (An45.44-31.82Ab62.66-51.79Or5.52-2.77), oligoclase (An26.65-15.84Ab69.19-63.57Or20.59-8.55) and anarthoclase (Ab68.11-61.20Or33.87-20.91An10.98-4.93). Olivines are magnesian (Fo86.7-50.1) and ferriferous (Fo48.8-37.8). In HMg-B, olivine are only magnesian. These olivines are chrysolites and hyalositerite. In LMg-B, olivines are magnesian and ferriferous with the predominance of ferriferous. They are chrysolites, hyalositerite and hortonolite. Pyroxenes are Ca, Mg and Fe clinopyroxenes. There are diopsides (Wo51.94-45.02En44.41-33.16Fs16.42-10.70) and augites (Wo44.88-43.64En41.03-37.04Fs18.25-14.43). Oxides are magnetites represented by ulvospinel (Usp90-75Sp2-7Mt5-23). Fractionation of ferromagnesian minerals (opaque oxide, olivine and pyroxene) is the main differentiation process. Two stages of fractional crystallization can be distinguished: the first stage comes with basanites and the second with hawaiites to mugearites. Chemical compositions of phenocrystals in studied basaltics lavas record signatures of magma recharge by pulsatory intrusions of new magma into the existing magma reservoir before the eruptions.

Intracrystalline distortions (like undulose extinction, dislocations, and subgrain boundaries) in olivine from naturally-deformed peridotites are generally taken as signs of dislocation creep. However, similar features in olivine phenocrysts that have been found in basaltic magmas are still not well understood. In particular, whether subgrain boundaries in olivine phenocrysts arise from plastic deformation or grain growth is still debated (in the latter case, they are essentially grain boundaries but not subgrain boundaries. Therefore, we used hereinafter subgrain-boundary-like structures instead of subgrain boundaries to name this kind of intracrystalline distortion). Here we carried out a detailed study on dislocations and subgrain-boundary-like (SG-like) structures in olivine phenocrysts from two Hawaiian basaltic lavas by means of petrographic microscopy, scanning electron microscopy, and transmission electron microscopy (TEM). Abundant and complex dislocation substructures (free dislocations, dislocation walls, and dislocation tangles) were observed in the decorated olivine grains, similar to those in olivine from peridotite xenoliths entrained by the Hawaiian basalts. The measured average dislocation density is (2.9±1.3)×1011 m−2, and is three to five orders of magnitude higher than that in laboratory-synthesized, undeformed olivine. TEM observations on samples cut across the SG-like structures by FIB (focused ion beam) demonstrated that this kind of structures is made of an array of dislocations. These observations clearly indicate that these structures are real subgrain boundaries rather than grain boundaries. These facts suggest that the observed high dislocation densities and subgrain boundaries cannot result from crystal crystallization/growth, but can be formed by plastic deformation. These deformation features do not prove that the olivine phenocrysts (and implicitly mantle xenoliths) were deformed after their capture by the basaltic magmas, but can be ascribed to a former deformation event in a dunitic cumulate, which was formed by magmatic fractionation, then plastically deformed, and finally disaggregated and captured by the basaltic magma that brought them to the surface.

The eastern Junggar Basin, controlled by continental extension (rift), was deposited by lacustrine dominated sediments during middle Permian Lucaogou period. An unusual porphyritic-like texture was observed in Lucaogou/Pingdiquan dark fine-grained organic-rich sediments in two sub-tectonic units in the basin. The “phenocrysts” are composed of two types of mineral assemblages. The first is a coarse euhedral calcite assemblage in the Jimusar Sag, and the second consists of dolomite, analcime, and pyrite in the Shishugou Sag. The lithological and mineralogical features indicate a hydrothermal origin for these phenocryst-like minerals. The chondrite-normalized rare earth element patterns show flat or positive Ce anomalies and negative Eu anomalies, which reflect a suboxic to anoxic, off-axis site from the center of the fault system, where the temperature of the hydrothermal fluid might be less than 250 °C. The high ratios of BaN/LaNat 1.6–65.5, strongly positive Sr anomalies at Sr/Sr* = 5.54–39.9, and relatively low87Sr/86Sr isotopes at 0.705002–0.705776 in the coarse calcite suggest an origin of mixed sources of lake water, underlying biogenetic sediments, and deep magmatic water. However, the low87Sr/86Sr ratios of 0.705321–0.705968 in the dolomite and δ34SV-CDTof 10.8‰–12.3‰ in the pyrite indicate that water–underlying-rock interaction and the abiotic thermochemical sulfate reduction of lake water or organic matter might have participated together resulting in the precipitation of the dolomite–analcime–pyrite assemblages in the Shishugou Sag.

Molecular formulae used to recalculate nepheline analyses generally have different numbers of oxygens (e.g. NaAlSiO4(Ne), KAlSiO4,(Ks), CaAl2Si2O8(An) and SiO2(Q)). A 32 oxygen cell has 16 T cations and 8 cavity sites, but ideal nepheline stoichiometry is not necessarily followed. Ca end-member □CaCaAl2Si2O4(CaNe) and excess silica end-member □SiSi2O4(Q’) calculation requires inclusion of both vacancy species as cavity cation values. Q’ parameter calculations can involve different assumptions and four parameters are described: Qxs; QSi; Q(Si–Al); and Qcavity; these should have closely similar values for high-quality, stoichiometric analyses.Representative published compositions are recalculated to assess whether authors followed ideal nepheline stoichiometry. Phenocrysts from peralkaline rocks and nephelinites typically exhibit Al deficiencies reflected in negative Δ(Al – cavity cation) parameters (ΔAlcc), negative ‘normative’ corundum (Al2O3,Cn), and anomalously low or negative Qxsparameters; for such rock types Q(Si–Al)provides a better estimate of excess silica contents. A ΔT-site (cation charge) parameter (ΔTcharge), is closely coupled to ΔAlccand end-member NaAlSiO4has a ΔAlcc/ΔTchargeratio of 1.4296; the derivation of this value is controlled by strict stuffed-tridymite, unit-cell constraints. Natural nephelines all contain excess silica with a mean ΔAlcc/ΔTchargeof ~1.134 reflecting their Si/Al ratio being > 1.Nepheline analyses with relatively low Al and Si and high Na (also Ca) contents are common; this might reflect the presence of small amounts (up to ~5%) of cancrinite as an alteration phase or perhaps even in solid solution. The compositions of alteration lamellae of Ca-rich cancrinite in altered nepheline phenocrysts in phonolites from the Marangudzi alkaline complex, Zimbabwe, are used to define diagnostic parameters for recognising such non-stoichiometry. These alteration lamellae formed hydrothermally from Ca-rich and K-poor fluids.An EXCEL file is provided to help researchers to standardise calculation of nepheline end-member molecular proportions.

The Emeishan large igneous province (ELIP) in SW China is considered to be a typical mantle-plume-derived LIP. The picrites formed at relatively high temperatures in the ELIP, providing one of the important lines of argument for the role of mantle plume. Here we report trace-element data on olivine phenocrysts in the Dali picrites from the ELIP. The olivines are Ni-rich, and characterized by high (>1.4) 100×Mn/Fe value and low (DNiol/melt) will decrease at high temperatures and pressures, the picrites derived from peridotite melting at high pressure, and that crystallized olivines at lower pressure, can generate high concentrations of Ni in olivine phenocrysts, excluding the necessity of a metasomatic pyroxenite contribution. Based on the Al-in-olivine thermometer, olivine crystallization temperature and mantle potential temperature (TP) were calculated atc. 1491°C andc. 1559°C, respectively. Our results arec. 200°C higher than that of the normal asthenospheric mantle, and are consistent with the role of a mantle thermal plume for the ELIP.

A Serra da Capoeira Grande e o Morro do Silvério, em Pedra de Guaratiba, constituem o prolongamento sudoeste do Maciço da Pedra Branca. A rocha dominante na região é um granito rosa com cristais de microclina tabular orientados na direção NE-SW. Variações faciológicas resultantes da irregularidade no tamanho de grãos, da razão fenocristais/matriz e da intensidade da lineação ocorrem em escala métrica a centimétrica e com contatos transicionais entre si. Enclaves de metassedimentos e de rochas ortoderivadas, com diferentes graus de assimilação, ocorrem ao longo de uma faixa linear NE-SW. Esses apresentam contornos lenticulares e orientação preferencial concordante com a direção dos megacristais de microclina e do bandamento ígneo. Dados de campo apontam para processos de segregação mecânica na formação dos subtipos, com granito equigranular, de granulação fina, como produto de segregação entre fenocristais e material intersticial. O arranjo espacial entre enclaves, granito equigranular e aglomerados de feldspato indicam terem os enclaves atuado como filtros retentores de fenocristais durante fluxo magmático. Concentrados de allanita ocorrem ao longo da zona enriquecida em enclaves, sugerindo a formação desse mineral por fluidos tardios, com mobilização de elementos terras favorecida pela maior permeabilidade da faixa.

The world-class San Rafael tin (-copper) deposit (central Andean tin belt, southeast Peru) is an exceptionally large and rich (>1 million metric tons Sn; grades typically >2% Sn) cassiterite-bearing hydrothermal vein system hosted by a late Oligocene (ca. 24 Ma) peraluminous K-feldspar-megacrystic granitic complex and surrounding Ordovician shales affected by deformation and low-grade metamorphism. The mineralization consists of NW-trending, quartz-cassiterite-sulfide veins and fault-controlled breccia bodies (>1.4 km in vertical and horizontal extension). They show volumetrically important tourmaline alteration that principally formed prior to the main ore stage, similar to other granite-related Sn deposits worldwide. We present here a detailed textural and geochemical study of tourmaline, aiming to trace fluid evolution of the San Rafael magmatic-hydrothermal system that led to the deposition of tin mineralization. Based on previous works and new petrographic observations, three main generations of tourmaline of both magmatic and hydrothermal origin were distinguished and were analyzed in situ for their major, minor, and trace element composition by electron microprobe analyzer and laser ablation-inductively coupled plasma-mass spectrometry, as well as for their bulk Sr, Nd, and Pb isotope compositions by multicollector-inductively coupled plasma-mass spectrometry. A first late-magmatic tourmaline generation (Tur 1) occurs in peraluminous granitic rocks as nodules and disseminations, which do not show evidence of alteration. This early Tur 1 is texturally and compositionally homogeneous; it has a dravitic composition, with Fe/(Fe + Mg) = 0.36 to 0.52, close to the schorl-dravite limit, and relatively high contents (10s to 100s ppm) of Li, K, Mn, light rare earth elements, and Zn. The second generation (Tur 2)—the most important volumetrically—is pre-ore, high-temperature (>500°C), hydrothermal tourmaline occurring as phenocryst replacement (Tur 2a) and open-space fillings in veins and breccias (Tur 2b) and microbreccias (Tur 2c) emplaced in the host granites and shales. Pre-ore Tur 2 typically shows oscillatory zoning, possibly reflecting rapid changes in the hydrothermal system, and has a large compositional range that spans the schorl to dravite fields, with Fe/(Fe + Mg) = 0.02 to 0.83. Trace element contents of Tur 2 are similar to those of Tur 1. Compositional variations within Tur 2 may be explained by the different degree of interaction of the magmatic-hydrothermal fluid with the host rocks (granites and shales), in part because of the effect of replacement versus open-space filling. The third generation is syn-ore hydrothermal tourmaline (Tur 3). It forms microscopic veinlets and overgrowths, partly cutting previous tourmaline generations, and is locally intergrown with cassiterite, chlorite, quartz, and minor pyrrhotite and arsenopyrite from the main ore assemblage. Syn-ore Tur 3 has schorl-foititic compositions, with Fe/(Fe + Mg) = 0.48 to 0.94, that partly differ from those of late-magmatic Tur 1 and pre-ore hydrothermal Tur 2. Relative to Tur 1 and Tur 2, syn-ore Tur 3 has higher contents of Sr and heavy rare earth elements (10s to 100s ppm) and unusually high contents of Sn (up to >1,000 ppm). Existence of these three main tourmaline generations, each having specific textural and compositional characteristics, reflects a boron-rich protracted magmatic-hydrothermal system with repeated episodes of hydrofracturing and fluid-assisted reopening, generating veins and breccias. Most trace elements in the San Rafael tourmaline do not correlate with Fe/(Fe + Mg) ratios, suggesting that their incorporation was likely controlled by the melt/fluid composition and local fluid-rock interactions. The initial radiogenic Sr and Nd isotope compositions of the three aforementioned tourmaline generations (0.7160–0.7276 for 87Sr/86Sr(i) and 0.5119–0.5124 for 143Nd/144Nd(i)) mostly overlap those of the San Rafael granites (87Sr/86Sr(i) = 0.7131–0.7202 and 143Nd/144Nd(i) = 0.5121–0.5122) and support a dominantly magmatic origin of the hydrothermal fluids. These compositions also overlap the initial Nd isotope values of Bolivian tin porphyries. The initial Pb isotope compositions of tourmaline show larger variations, with 206Pb/204Pb(i), 207Pb/204Pb(i), and 208Pb/204Pb(i) ratios mostly falling in the range of 18.6 to 19.3, 15.6 to 16.0, and 38.6 to 39.7, respectively. These compositions partly overlap the initial Pb isotope values of the San Rafael granites (206Pb/204Pb(i) = 18.6–18.8, 207Pb/204Pb(i) = 15.6–15.7, and 208Pb/204Pb(i) = 38.9–39.0) and are also similar to those of other Oligocene to Miocene Sn-W ± Cu-Zn-Pb-Ag deposits in southeast Peru. Rare earth element patterns of tourmaline are characterized, from Tur 1 to Tur 3, by decreasing (Eu/Eu*)N ratios (from 20 to 2) that correlate with increasing Sn contents (from 10s to >1,000 ppm). These variations are interpreted to reflect evolution of the hydrothermal system from reducing toward relatively more oxidizing conditions, still in a low-sulfidation environment, as indicated by the pyrrhotite-arsenopyrite assemblage. The changing textural and compositional features of Tur 1 to Tur 3 reflect the evolution of the San Rafael magmatic-hydrothermal system and support the model of fluid mixing between reduced, Sn-rich magmatic fluids and cooler, oxidizing meteoric waters as the main process that caused cassiterite precipitation.

Saindak is one of the typical porphyry Cu deposits (PCDs) in the Chagai magmatic arc in Pakistan. Ore-forming porphyries at Saindak PCD are mainly composed of tonalite. Here, we use geochemistry of apatite enclosed in plagioclase phenocrysts from the ore-forming tonalite to constrain the releasing and recharging processes of S and Cl in the underlying parental magma chamber during PCD mineralization. Although apatite inclusions have homogeneous intra-grain S and Cl compositions, there is significant inter-grain S and Cl variations in apatite inclusions located from core to rim in the hosting plagioclase. Such inter-grain S and Cl variation in apatites are coupled with the core-to-rim trends of An, FeO and Mg contents of the hosting plagioclase phenocryst. It indicates that the Saindak PCD likely formed by episodic injection of primitive magmas during the growth of an underlying magma chamber, rather than by one major injection or by addition of mafic melt derived from different source region. Each primitive melt injection introduced essential ore-forming materials such as S and Cl, which were rapidly and effectively released to the coexisting fluids, causing mineralization. Once primitive melt injection stops, signaling the end of growth of underlying magma chamber, mineralization will cease quickly although the hydrothermal system can still survive for a long time. However, the later released fluids are relatively depleted in ore-forming materials, and thus have lower capability to generate mineralization. Accordingly, predominant porphyry-type mineralizations occurred during the growth rather than waning stage of a magmatic system.

To provide new insights into the origin and evolution of kimberlitic magmas with different diamond concentrations from the Arkhangelsk diamond province in north-western Russia, we examined the major- and trace-element compositions of ilmenite from diamondiferous kimberlite of the Grib pipe and diamond-barren kimberlites from the Kepino cluster (Stepnaya and TsNIGRI–Arkhangelskaya pipes). Ilmenite from diamond-barren kimberlites shows lower Mg, Ti, Cr, Ni and Cu concentrations with increase in both Fe3+ and Fe2+ and Nb, Ta, Zr, Hf, Zn and V concentrations. The main differences between kimberlites with different diamond contents are the Nb and Zr concentrations and their correlation patterns with Mg and Cr concentrations. Ilmenite from the Grib kimberlite has Zr concentrations 300 ppm. Ilmenite crystallisation within the Grib kimberlite occurred under increasing oxygen fugacity (fO2), which may reflect assimilation of mantle peridotite by the kimberlitic magmas. Ilmenite from the Kepino kimberlites suggests its crystallisation under constant fO2, with the ilmenite composition being controlled by processes of fractional crystallisation of megacrystic minerals. These assumptions were confirmed with assimilation–fractional crystallisation calculations. On the basis of obtained data, we developed a model for the evolution of the kimberlitic magmas for both diamondiferous and barren kimberlites. The diamond-bearing kimberlitic magmas were generated under intense interaction of kimberlitic magmas with the surrounding lithospheric mantle. It may be that during early modification of the lithospheric mantle by kimberlitic magmas as well as with kimberlitic magmas’ local stretching and swift ascent, the capture of the mantle xenoliths was favoured over the crystallisation of phenocrysts. The formation of barren kimberlitic magmas may have occurred when the lithospheric mantle in the vicinity of ascending magmas was already geochemically equilibrated with them. It also is possible that the magma’s ascent slowed under conditions of dominantly compressive stresses with crystallisation of olivine and other megacrystic phases.

Electron microprobe analysis was conducted on plagioclase from the plagioclase ultraphyric basalts (PUBs) erupted on the Southwest Indian Ridge (SWIR) (51°E) to investigate the geochemical changes in order to better understand the magmatic processes occurring under ultraslow spreading ridges and to provide insights into the thermal and dynamic regimes of the magmatic reservoirs and conduit systems. The phenocryst cores are generally calcic (An74–82) and are depleted in FeO and MgO. Whereas the phenocryst rims (An67–71) and the plagioclase in the groundmass (An58–63) are more sodic and have higher FeO and MgO contents than the phenocryst cores. The crystallization temperatures of the phenocryst cores and the calculation of the equilibrium between the phenocrysts and the matrix suggest that the plagioclase cores are unlikely to have crystallized from the host basaltic melt, but are likely to have crystallized from a more calcic melt. The enrichment in incompatible elements (FeO and MgO), as well as the higher FeO/MgO ratios of the outermost phenocryst rims and the groundmass, are the result of plagioclase-melt disequilibrium diffusion during the short residence time in which the plagioclase crystallized. Our results indicate that an evolved melt replenishing under the SWIR (51°E) drives the eruption over a short period of time.

Introduction: The Tashly-Tau massif is a small olivine-hornblende gabbro stock that represents the earliest manifestations of the products of differentiated magmatism in the Khudolaz complex. The complex has a complicated geological structure. Therefore, the detailed petrological and geochemical studies of individual massifs using numerical simulation of crystallisation parameters make it possible to determine the formation features of the Khudolaz complex as a whole. The aim of the study is to reconstruct the paleogenesis of the gabbroids of the Tashly-Tau massif, which is also important because of the massif’s sulphide Cu-Ni mineralisation. Methodology: Rock forming minerals of the gabbroids were studied using an optical microscope Axioskop 40 and a scanning electron microscope Tescan Mira 3. The chemical composition of the rocks was determined using the X-ray fluorescence analysis and inductively coupled plasma mass spectrometry. The isotopic composition of Sr and Nd was studied using thermal ionisation spectrometry. To model the petrogenesis, numerical COMAGMAT modelling and the method of geochemical thermometry were used. Results and discussion: The petrological and geochemical study of the rocks in the Tashly-Tau massif was carried out. It showed an extensive presence of the hornblende, titanous magnesiohastingsite (~50 wt. %). The gabbroids are characterised by their relative enrichment in large-ion elements (Cs, Rb, Sr, Ba) and depletion in high field strength elements (Nb, Ta, Zr, Hf, REE). Based on the geochemical data, it was concluded that the magmatic melt was poorly differentiated. The numerical simulation showed that the rocks were formed from magma, consisting of ~20 wt. % olivine phenocrysts (Fo 76) and water-saturated basalt melt (~1.7 wt. % H2O). The melt is characterised by high alumina and iron content and moderate magnesium content. The Sr-Nd isotopic composition of the rocks refers to little crustal contamination of the primitive melt. They are characterised by high positive values of eNd(Т) (+5.2...+10.3) and a low content of radiogenic strontium. A mantle reservoir of the PREMA type could be a source of the parent melt. Conclusions: The obtained results are important for understanding the formation nature of the complicatedly differentiated Khudolaz complex, specialised in sulphide mineralisation. This complex is unique to the Urals. It was shown that the use of numerical simulation of water-saturated basalt systems can be quite effective until the crystallisation of hydroxyl-containing rock forming minerals (the hornblende).

Актуальность изучения современного вулканизма заключается в понимании сложных процессов дифференциации, ассимиляции и смешения магм, зафиксированных в минералого-петрогеохимических и текстурно-структурных особенностях строения современных вулканитов. С другой стороны, с базитовым вулканизмом повышенной щелочности современных островодужных систем зачастую связано экономически значимое оруденение цветных и благородных металлов. Целью настоящей работы является изучение и интерпретация минералогических и петрохимических особенностей лав действующего вулкана Батур (о. Бали, Индонезия). Объектами исследования являются вулканиты, отобранные из лавовых потоков 1964 г. извержения действующего вулкана Батур. Породы современного островодужного магматизма и встречающиеся в них минералы изучены методами оптической и электронной микроскопии с применение энергодисперсионной спектроскопии. Химический состав основных петрогенных компонентов получен с помощью силикатного анализа, микроэлементный состав - с помощью масс-спектрометрии с индуктивно-связанной плазмой. В результате проведенных исследований было установлено, что все образцы изученных вулканитов имеют порфировую структуру и содержат вкрапленники плагиоклаза (17…23 об. %), оливина (3 об. %) и пироксена (2 об. %), расположенных в мелкозернистой массе мезостазиса, содержащего плагиоклазы, титаномагнетит, пироксен и вулканическое стекло. Для порфировых вкрапленников плагиоклаза характерна «ячеистая» структура, которая проявлена в виде ориентированных расплавных включений (~0,05 мм), содержащих первичный силикатный и сульфидный расплавы. По петрохимическим показателям породы относятся к высокоглиноземистым базальтам (Al2O3≥18,0). Сложный характер зональности порфировых вкрапленников плагиоклазов согласуется с быстрым охлаждением исходных расплавов, когда выделяющийся плагиоклаз не может прийти в равновесие с оставшейся еще жидкой магмой, по средневзвешенному составу он относится к лабрадор-битовниту. Оливин сочетает несколько вариантов перераспределения железа в своем составе. Отмечается прямая зональность с накоплением железа в краевых частях зерен, специфичные «структуры распада» с фазой «окси-оливина» и однородные кристаллы оливина с магнезиальностью Mg#(Fo) [=Mg/(Fe2++Mg)*100 %] ~ 66. Повышенная железистость оливина и примесь в нем MnO служат свидетельством того, что изучаемые породы являются производными базальтовых растворов с щелочным уклоном. По представлению авторов механизм формирования изучаемой серии андезибазальтов имеет следующий сценарий формирования. В период интенсивного вулканизма 1964 г. извержения вулкана Батур магматическая камера периодически обогащалась высокомагнезиальным (оливиновым) базальтом через определенные промежутки времени. Далее этот расплав поднимался в верхнюю часть камеры с последующим фракционированием оливина и клинопироксена при кристаллизации плагиоклаза и накоплением его в верхней части магматической камеры. В период поступления новой порции родоначального расплава существующая смесь не успевала прийти в равновесие с поступившей порцией расплава, изливаясь на поверхность и формируя лавы высокоглиноземистого базальта. Включения глобулей ковеллина и халькопирита в расплавных включениях порфировых вкрапленников плагиоклаза свидетельствуют о существовании высокофракционированного сульфидного расплава на более глубинном уровне. The relevance of the modern volcanism study is to understand the complex processes of the magma differentiation, assimilation and mixing that recorded in the mineralogical, structural and petrochemical features of volcanic rock units. On the other hand, economically significant deposit of non-ferrous and noble metals is often associated with basic volcanism of increased alkalinity in modern island-arc systems. The main aim of this work is to study and interpret the mineralogical and petrochemical features of the lavas from the active Batur volcano (Bali Island, Indonesia). Objects: samples of lava from the 1964 Batur eruption. Methods. The rock units of modern island arc lavas and the minerals found in them have been studied by optical and electron microscopy using energy dispersive spectroscopy analysis. The major elements of the rock units were obtained using silicate analysis, while trace element composition - using inductively coupled plasma mass spectrometry analysis. As a result of the conducted studies it was found that all samples of the lavas from Batur volcano have porphyry structure and contain phenocrysts of plagioclase (17...23 vol. %), olivine (3 vol. %) and pyroxene (2 vol. %) located in the fine-grained ground mass containing plagioclase, titanomagnetite, pyroxene and volcanic glass. The phenocrysts of plagioclase are characterized by a «sieve-textured domains» structure, with oriented melt inclusions (~0,05 mm) containing primary silicate and sulfide melts. The petrochemical parameters of the Batur lavas suggest that they correspond to highalumina basalts (Al2O3≥18,0). The complex structure of zonal plagioclase phenocrysts is consistent with the rapid cooling of the initial melts, when the released plagioclase cannot come into equilibrium with the remaining liquid magma. Its bulk chemical composition corresponds to labrador-bytownite. Olivine reveals several variants for iron redistribution in its composition including zonal crystals with iron accumulation in the marginal parts of grains, specific «excolutions structures» and homogeneous olivine crystals with Mg#(Fo) [=Mg/(Fe2++Mg)*100 % atomic ratio] component ~66,0. The increased iron content and manganese oxide alloy (Mn2+) in olivine may indicate that the Batur lavas are derivatives from the olivine basalt with an alkaline bias. Presumably, during the period of intense volcanism Batur volcano eruption in 1964, the magma chamber was periodically enriched with olivine basalt at some regularity. Further, this melt rose to the upper part of the chamber, followed by fractionation of olivine and clinopyroxene during crystallization of plagioclase and their accumulation in the upper part of the magma chamber. During the period of the input of a new portion of the initial melt, the existing mixture had not come into equilibrium with the incoming portion of the melt, has erupted to the surface and formed the lavas of high-alumina basalt. The presence of covellite and chalcopyrite globules in melt inclusions in the phenocrysts of plagioclase may be the evidence of the existence of a highly fractionated sulfide melt at a deeper level.

At the Black Mountain porphyry Cu-Au deposit in the Baguio district, Northern Luzon (Philippines), pre- and synmineralized rocks preserve magmatic and hydrothermal minerals (e.g., plagioclase, amphibole, titanite, and epidote) spanning the complete paragenesis of the deposit. Strontium isotope values in early crystallized plagioclase phenocrysts from all felsic porphyries can be divided into two types. The type-I plagioclase crystals show relatively homogeneous Sr isotope values (0.7035–0.7038, 1σ

Postorogenic volcanic rocks of different Tertiary ages are very common in the Sava-Vardar Zone of the Dinarides and in the southeastern part of adjoing Pannonian Basin. South of the Sava-Vardar Zone, in central Bosnia, Tertiary volcanic rocks occur within ophiolite sequences and genetically related sedimentary formations of the Dinaride Ophiolite Zone. Central Bosnia volcanic rocks are mostly dacites, and highly subordinately andesites as the members of the high-K calc-alkaline series.It appears from the mineralogical and petrographic characteristics obtained some insight into the processes that occurred during the genesis of the rocks. The presence of primary igneous minerals: clinopyroxene, orthopyroxene, hornblende and biotite from ferromagnesian minerals, and plagioclase, sanidine and quartz, indicates that the fractional crystallization played a significant role in the genesis of the rocks. Reaction edge on many rounded quartz phenocrysts indicates the possibility of magma mixing with the formation of Tertiary volcanic rocks of the central Bosnia. On magma mixing different temperature and chemical composition also indicates the existence of zoned plagioclase and amphibole phenocrysts.Complex compositional and zoning patterns of biotite and plagioclase phenocrysts and disequilibrium microstructures of plagioclase and quartz phenocrysts suggest interaction of fractionating, mantle derived melts with continental crust during a shalow level pre-eruptive stage and mixing with small amount of devolatilized phlogopite-phyric mafic magma before eruption.

The Třebic Pluton (TP) comprises plutonic rocks of the ‘durbachite series’, i.e., ultrapotassic biotite–amphibole quartz melasyenites–melagranites with conspicuous K-feldspar phenocrysts and abundant mafic enclaves. The TP with its satellite bodies intruded the eastern Moldanubian Zone (orogenic root of the Variscan Bohemian Massif) at c. 338 Ma. Overall, the entire TP durbachite series (SiO2 = 52–67 wt%) remains highly magnesian, reduced, and (except when strongly contaminated) metaluminous. The durbachitic rocks are markedly enriched in lithophile elements (esp. Cs, Rb, Th, U, K and Pb) and LREE; in contrast, the contents of high-field strength elements (Nb, Ta, and Ti) and Sr are much lower, resulting in conspicuous negative anomalies in Primitive mantle-normalized multielement plots. The proposed petrogenetic model requires re-enrichment of the depleted, harzburgitic lithospheric mantle by deeply subducted crustal material of the Saxothuringian lower plate, directly and/or via (U)HP melt/fluid. This process produced phlogopite-rich metasomes (phlogopite harzburgites and/or glimmerites). The metasomes re-melted soon thereafter by a short thermal pulse caused by slab break-off or decompression melting of rising diapirs of the relatively light metasomatized mantle, yielding primary ultrapotassic melts (87Sr/86Sr337 > 0.712 and $$\varepsilon_{{{\text{Nd}}}}^{337}$$ ≤ 7.6). Upon their passage through the Moldanubian upper plate, ultrapotassic primary magmas mixed with felsic anatectic melts (87Sr/86Sr337 – 6.5). K-feldspar-driven fractional crystallization ± accumulation represented only a late modifying influence. The occurrence of such ultrapotassic enriched/crustally contaminated mantle-derived magmatism complicates any conventional mass-balance assessments of relative roles of crustal recycling vs. growth in hot collisional orogens, e.g., Variscides or Himalayas.

The mechanisms of the occurrence of nonequilibrium oxygen isotope fractionation between olivine and plagioclase phenocrysts and the groundmass of rocks (from alkaline basalts to alkaline rhyolites) of Changbaishan volcano are considered. The basaltic trachyandesite–trachyte–comendite–pantellerite rock series shows a systematic increase of the δ18O values of feldspar (from 5.4 to 7.8‰) and the rock groundmass (from 5.6 to 7.1‰). In contrast, the δ18О values of olivine decrease from 5.35‰ typical of mantle peridotites to significantly lower values (3.88–4.14‰). This is accompanied by changes in olivine composition from the Mg-rich (Fo = 74–79) to almost pure fayalite (Fo = 1), thus indicating a positive correlation between the Mg–number and δ18О of olivine. It is shown that feldspar and the rock groundmass are close to the oxygen isotopic equilibrium, whereas olivine–rock groundmass and olivine–feldspar pairs did not approach the oxygen isotopic equilibrium. The main mechanisms leading to the oxygen isotopic disequilibrium in the mineral–melt system are considered. An approach to the estimation of oxygen isotope equilibrium between the phenocrysts and melts is proposed. It takes into account the degree of melt polymerization (NBO/T ratio). This approach makes it possible to explain the positive correlation between δ18О values and olivine Mg-numbers in the Changbaishan lavas, as well as the occurrence of low δ18O values (down to +3‰) in ferrous olivine from alkaline–salic rocks. The δ18О values observed in the olivine and the rock groundmass reflect changes in the degree of melt polymerization during crystal fractionation. The proposed model does not require an additional geological process, in particular, the contribution of a low–δ18О material in the formation of the Changbaishan differentiated rock series.

To understand the petrogenesis and magma evolution history in the Eastern Manus Basin (EMB), geochemistry of pyroxene and plagioclase mineral phenocrysts in basaltic andesites and dacites were reported. The plagioclase-melt thermometry showed that, plagioclase in dacites crystalized in 1 027.2–1 028.5°C under 3.37–5.08 kbar, whereas in basaltic andesite was 1 181.5–1 187.0°C under 1.79–4.46 kbar. Pyroxene compositions and invariable La/Sm vs La values of whole rock powders indicate that lavas were erupted in rapid cooling rate and mainly controlled by fractional crystallization (FC). In addition, oscillatory zonings in plagioclase and pyroxene phenocrysts indicated small local perturbations and degassing episodes in the magma chamber. Some high Mg# clinopyroxene antecrysts were found in EMB lavas. The highest Mg# of parental EMB melts is 69, which falls into the range of initial partial melts from upper mantle peridotite source (68–75). In terms of isotopic compositions, the EMB lavas most likely originated from Indian-type MORB mantle which was influenced by subduction components. In details, the subduction components are mainly derived from the dehydration of a subducted altered oceanic crust, and the contribution of sediment influence is minor. The Pb isotopic compositions and end member modeling further suggest that the source of subduction components is more likely from the Pacific Plate instead of the Solomon Plate.

Minerals that contain platinum-group elements (PGEs) and occur in some magmatic Cu-Ni sulfide deposits have been ascribed to crystallization from an originally PGE-rich sulfide liquid. The occurrence of PGE-bearing minerals (PGMs) in some sulfide-undersaturated primitive melts has been envisaged and recently reported, whereas direct crystallization of PGMs in sulfide-saturated silicate magmas is seemingly hindered by strong partitioning of PGE into immiscible sulfide melts. In this study, we discovered abundant nanoparticles containing noble metals in association with sulfide melt inclusions entrapped inside primitive olivine phenocrysts (Fo85–92) from the recent basaltic magma of the Tolbachik volcano (Kamchatka arc, Russia). These nuggets occur in swarms on the surface of the sulfide globules and are represented by native metals, sulfides, and alloys of Pd, Pt, Au, Pb, and Bi. The nuggets on different globules can be either Pd- or Pt-rich nuggets, and the compositions are highly variable, even among adjacent nuggets. We argue that the diffusive supply of Pd from the external nuggets can be responsible for significant uptake of Pd (up to 2 wt%) in the sulfide melt. We consider direct crystallization of PGMs in a primitive basaltic melt undergoing sulfide unmixing, and possibly sulfide breakdown due to oxidation, as another mechanism additional to their “classic” origin from the PGE-rich sulfide melt in response to solidification.

Thin fallout tuffs are common in the terrestrial deposits of the Eocene Duchesne River Formation on the flanks of the Uinta Mountains of eastern Utah. Their ages and compositions provide new insight into the tectonic events and magmatic history of the western Cordillera and provide important constraints on the Cenozoic land mammal chronology. Whole-rock compositions of the volcanic ash show that they underwent post-emplacement argillic alteration, typical of a wetland/floodplain depositional setting. However, immobile element ratios and abundances, such as Zr/Ti, La/Nb, and Y are typical of rhyolites formed in a subduction-related setting. Glass shards preserved in one sample all had SiO2 values >75%, typical of high-silica rhyolite. Preserved phenocrysts in the ash beds include quartz, sanidine, plagioclase, and biotite with variable amounts of accessory zircon, apatite, titanite, and allanite. Biotite compositions have Fe/(Fe+Mg) ratios typical of calc-alkaline igneous rocks and clusters of chemical compositions suggest a genetic relationship to three or four separate eruptions. Sanidine compositions from five samples range from Or73 and Or79. Only one sample had preserved plagioclase with compositions ranging between An22 – An49. Allanite from the ash beds has lower total rare earth elements (REE) concentrations than allanite from other well-studied rhyolites. Titanite in one sample has lower concentrations of REE, Fe, and Al than expected of rhyolites and is probably detrital.Plagioclase and sanidine from two different tuff beds near the middle of the Duchesne River Formation yielded analytically indistinguishable 40Ar/39Ar ages of 39.47 ± 0.16 Ma and 39.36 ± 0.15 Ma, respectively. These dates, along with the compositional data seem to limit the eruptive source for these fallout tuffs to the northeast Nevada volcanic field, one of the few volcanically active regions of western North America at the time. These new radiometric ages, along with stratigraphic relations and previously published ages for tuffs in the Bishop Conglomerate (which unconformably overlies the Duchesne River Formation), constrain the timing of late Laramide uplift in the region from 39 to about 37 Ma and post-Laramide epeirogenic uplift from 34 Ma to 30 Ma. Finally, the ages also provide additional evidence that the Duchesnean North American Land Mammal Age ended in the Eocene, which was originally named and defined from the Duchesne River Formation.

Late Pleistocene tephras derived by large explosive volcanic eruptions are widespread in the Mediterranean and surrounding areas. They are important isochronous markers in stratigraphic sections and therefore it is important to constrain their sources. We report here tephrochronology results using multiple criteria to characterize the volcanic products of the Late Pleistocene Ciomadul volcano in eastern-central Europe. This dacitic volcano had an explosive eruption stage between 57 and 30 ka. The specific petrological character (ash texture, occurrence of plagioclase and amphibole phenocrysts and their composition), the high-K calc-alkaline major element composition and particularly the distinct trace element characteristics provide a strong fingerprinting of the Ciomadul volcano. This can be used for correlating tephra and cryptotephra occurrences within this timeframe. Remarkably, during this time there were several volcanic eruptions produced tephras with similar glass major element composition. However, these tephras differ from Ciomadul ones by glass trace element abundances, ratios of strongly incompatible trace elements and distinctive mineral cargo that serve as discrimination tools. We used (U-Th)/He zircon dates combined with U-Th in-situ rim dates along with luminescence and radiocarbon dating to constrain the age of the explosive eruptions of Ciomadul that yielded distal tephra layers, but lack of identified proximal deposits.

Silicic magmas span a wide range of eruptive styles between explosive and effusive, and transitions between these styles are commonplace. Yet the triggers of switches in eruptive style remain poorly understood. Eruptions are mostly driven by degassing of magmatic water and their eruption style - effusive or explosive - is likely governed by the efficiency of outgassing as well as magma ascent rate. Microlites and phenocrysts are often purported to promote heterogeneous bubble nucleation and outgassing, both key variables in the degassing dynamics that become crucial in controlling the eruptive style. Here, in order to shed light on the role of nature, size and abundance of crystals on degassing of silicic magma, we experimentally investigate (heating-induced) vesiculation in a multiphase (microlite- and phenocryst-bearing), low-water content, and bubble-free, natural rhyolite. The experiments were conducted at magmatic temperature (∼900-1100 °C) and atmospheric pressure in an optical dilatometer. Our results indicate that microlites exert a large influence on bubble nucleation while the effect of phenocrysts is subordinate. Amongst the microlite phases, bubbles nucleate more easily on Fe-Ti oxides than other mineral phases. Bubble coalescence and connectivity are, in contrast, enhanced by the phenocrysts, more than microlites, in low-crystallinity magma. Comparing the bubble textures of the post-experimental samples with those produced in a phenocryst-free and microlite-poor silicic magma, we observe that the phenocryst- and microlite-bearing magma exhibits significantly more bubble coalescence and connectivity, as well as higher bubble number densities. These findings help to constrain the roles that pre- and syn-eruptive crystalline phases may play in degassing processes during ascent of silicic magma.

We report olivine chemistry in basaltic rocks from the Mt. Cameroon Volcanic area, which is used as a proxy to understand mantle and early igneous processes along the ocean-continent segment of the Cameroon Volcanic Line. Most primitive olivine phenocrysts in this study have forsterite contents of 86–87.5%. Their Li concentrations are below 3.5 ppm and occur in similar concentrations in all the samples. Ni has a large range in concentration, with some values as low as 742 ppm and others as high as 2500 ppm. The concentrations of Ca are in the range 2666–3755 ppm and that of Mn in the range 1283–2358 ppm. Olivine Ca/Al ratios are higher than those from both MORB and some within plate settings (e.g., Hawaii). Bulk rocks have low SiO2 (39.3–40.4 wt%) and high CaO/Al2O3 (0.72–1.03). The high olivine Ca/Al ratios, low bulk rocks SiO2 contents, and high bulk rocks CaO/Al2O3 ratios require a peridotite mantle source modified by carbonate-rich fluids. The plot of bulk rocks SiO2 vs. CaO similarly indicates CO2- enrichment. This metasomatic reaction may be regarded as the main source of volcanic hazardous CO2 along the CVL; such as in lakes Nyos and Monoun in 1986 and 1984 respectively, where approximately 2000 human and countless animal deaths were recorded.

Olivine is one of the most abundant phases in kimberlites and cratonic lamproites, where it occurs as mantle-derived xenocrysts and magmatic phenocrysts or rims overgrowing xenocrystic cores, indicating its prevalence throughout most of the crystallisation sequence of these magmas. Thus, olivine can provide valuable insights into kimberlite and lamproite petrogenesis. Here, we present a detailed study of olivine compositional zoning in two lamproites (P2 and P12) of the Mesoproterozoic Wajrakarur kimberlite-lamproite field in southern India and use these data to propose a genetic link between lamproites and kimberlites in the region. Olivine macrocrysts (i.e., anhedral grains >1 mm) from the P2 and P12 intrusions are strongly zoned. Comparisons with olivine from mantle xenoliths worldwide demonstrate that the cores of olivine macrocrysts are xenocrysts derived from disaggregated mantle wall-rocks. The internal zones and overgrowth rims of olivine macrocrysts and the cores of olivine phenocrysts from P2 and P12 contain magmatic Mg-chromite and Ti-magnetite inclusions and hence crystallized from the host lamproite melt. These magmatic olivine zones show increasing Mg# (molar Mg/(Mg + Fe2+)), CaO and MnO contents with decreasing NiO. This reverse differentiation trend appears to be a characteristic feature of olivine in lamproites from the Wajrakarur field. To evaluate potential petrogenetic links between coeval lamproites and kimberlites from Wajrakarur, the composition of olivine xenocrysts (i.e., macrocryst cores) was compared with that of early crystallized olivine in P2, P12 and previously studied kimberlites and lamproites. The average Mg# of olivine macrocryst cores is directly correlated with the average Mg# of magmatic olivine in lamproites and kimberlites from Wajrakarur. Coupled with their indistinguishable Sr-Nd-Hf isotope compositions, these data suggest derivation of the Wajrakarur lamproites and kimberlites from a common source, The more Fe-rich composition of liquidus olivine in the Wajrakarur lamproites compared to coeval kimberlites suggests a higher degree of assimilation of metasomatised Fe-richer lithospheric mantle by the lamproites and provides a plausible explanation for the different petrological features of the Wajrakarur lamproites and kimberlites Our results suggest that cratonic lamproites can have a remarkably similar petrogenetic history to kimberlites. ISSN:0024-4937

Co-auteur étranger; International audience; The variability in intensity and style shown by explosive volcanism has been traditionally explained by a complex interplay among melt composition and pre-eruptive volatile content, which modulate magma ascent and conduit dynamics. However, magmas having similar compositions may becharacterized by subtle textural changes affecting magma rheology and eventually explosive dynamics. Here we study five eruptions occurred at Cotopaxi volcano (Ecuador) in the last 2000 years characterized by a small variation in magma composition but spanning a wide range of intensity to investigate how these parameters control variations in eruption dynamics. We combined eruption source parameters (ESPs), obtained from the application of recent models to all the available field data, with new textural data and state-of-the-art conduit dynamics modeling. We found that, despite having variable microlite content and texture, the effect of microlite on magma rheology is partly counterbalanced by variablephenocryst abundance, resulting in a comparable total crystal content. The combination of modeling results with textural data and ESPs suggests that subtle variability in crystal content and magma composition may be accompanied by strong feedback effects among crystallization, changes in melt/ magma viscosity and volatile exsolution, with microlite crystallization resulting in a rapid change of magma rheology and modifications in the explosive dynamics. By combining ESPs with quantitative textural data (i.e. melt normalized vesicle number density) and conduit modeling, we also show how general observed correlations between composition and texture of juvenile products with eruption intensity are not evident when applied to eruptions characterized by a small compositional range.

International audience; Many asteroids in the main belt have spectra like those of Mighei-type CM chondrites, but some Near Earth Objects (NEO) resemble less well known types of C2 chondrite. Northwest Africa (NWA) 12563, a new find with affinities to C2 chondrites, could help us understand the differences between observations of CM2 chondrites and bodies that are currently being studied by the Hayabusa2 and OSIRIS-REx space missions. NWA 12563 contains 14% chondrules supported by 86% fine grained matrix consistent with CM2 chondrites, but differs from them in other respects. In both matrix and chondrules, olivine is unaltered and pyroxene shows incipient alteration. Metal in chondrules is pseudomorphed by serpentine, and mesostasis is replaced by serpentine-saponite and chlorite. Many Type I chondrules have highly irregular shapes resulting from fracturing and selective metal replacement. Type II porphyritic chondrules are clusters of phenocrysts set in matrix-like material. Type II chondrules may be kinked and partially disbarred. The matrix of NWA 12563 differs from CM2 chondrites in the absence of tochilinite-cronstedtite intergrowths. It contains hydrated and oxidized amorphous silicate (Fe3+/∑Fe ~75%) richer in magnesium than in other chondrites (with embedded sulfides). Serpentine-saponite is also present, as well as abundant framboidal magnetite.NWA 12563 has similarities to a number of ungrouped magnetite-rich and 18O-rich chondrites (Bells, Essebi, Niger I, WIS 91600, Tagish Lake, and MET 00432) that we call C2-ung1, as opposed to C2-ung2 chondrites (poorer in 18O and magnetite). The oxygen isotopic composition coupled with a magnetic susceptibility of log χ = 4.67 places NWA 12563 with these ungrouped chondrites in a cluster distinct from CM2 chondrites. NWA 12563 is closest to WIS 91600 among the C2-ung1 chondrites in alteration style and light element compositions. WIS 91600, however, has suffered light thermal metamorphism, suggesting that NWA 12563 might represent its altered but unheated precursor material within the same parent body if it were zoned. The average Vis-NIR spectrum of NWA 12563 matches the asteroid taxonomic class K and resembles that of CO3 Frontier Mountain (FRO) 95002, but its spectra range from very “red” in dark matrix areas and very “blue” in magnetite-rich areas. The average MIR spectrum shows features indicating phyllosilicates, aliphatic CH compounds, hydrated silicates, and olivine. It is significantly different from those of other chondrites including FRO 95002, and closest to Bells (from which it differs in carbon isotopic composition) and WIS91600. The variety of mineralogical, chemical and isotopic properties among C2-ung1 chondrites requires several different parent bodies. However, the high abundance of magnetite common to this cluster of ungrouped chondrites, and to a lesser extent CI chondrites, indicates that they should be considered as possible material from Bennu, which has an 18 µm magnetite signal in its spectrum not seen in the CM2 chondrites (Hamilton et al., 2019).

The eruption of the Tambora volcano in 1815 was initiated by two precursory Plinian falls and formed two generations of pyroclastic density current (PDC) deposits. In this study, we found slight changes in phenocrysts (modal mineralogy, content, and size), bulk-rock and feldspar microlite chemical compositions, and bubble and microlite number densities through the stratigraphic position. Plinian fall units are characterized by a lower phenocryst abundance (avg. of 5.1%), smaller phenocryst size (avg. of 0.06 mm2), and higher silica content (bulk-rock, 58–58.5 wt.%). The PDC deposits are characterized by a relatively higher crystal abundance (avg. of 12.1%), larger phenocryst sizes (avg. of 0.13 mm2), and lower silica content (bulk-rock, 56.7–57.9 wt.%). Therefore, the deposit stratigraphy and analyses suggest that phenocryst stratification in the magma chamber was established prior to the 1815 eruption and was thus responsible for yielding a slight contrast in bulk compositions. Feldspar microlite moves toward slightly more albitic compositions from Plinian falls to the PDCs, suggesting a slight decrease in the initial melt temperature from the upper to the lower magma chamber portion. Because the Plinian eruptions extracted the hottest magma, the degree of supercooling became low, and consequently yielded microlite-poor juveniles. By contrast, the PDCs experienced a larger degree of supercooling because the temperature was relatively low, thus yielding microlite-rich juveniles. Moreover, such temperature stratification coupled with the evidence of homogeneous melt composition (58.5–58.9 wt.% SiO2) and the minor evidence of crystal mush (at most 27%) might suggest that the Tambora case is still in the early stage of magmatic evolution under cooling from the surrounding rocks.

Tables, figures, and text that support results and discussion of this paper. Tables contain all measured and calculated data used in this study. Text includes results for plagioclase analyses and application of plagioclase-liquid hygrometer to hawaiites.

Field, microstructural and mineral compositional evidence from the Mesoproterozoic K-feldspar megacrystic Red Granite at Oncocua Platform (southwestern Angola) is consistent with crystal transfer from magma to wallrock during syntectonic intrusion. K-feldspar megacrystic Red Granite intruded during folding of wallrock tonalite. Enclaves of the wallrock tonalite are elongated parallel to Red Granite intrusive contacts, a K-feldspar megacryst and hornblende-defined magmatic foliation, and a gneissosity in the Red Granite. Stromatic layering present in the tonalite is crosscut by the Red Granite intrusive contacts or is isoclinally folded with fold axial planes and hinges filled with Red Granite. K-feldspar megacryst clusters and curved grain boundaries (i.e. contact melting), as well as thin Red Granite fold axial planar sheets containing K-feldspar megacrysts that are typically wider than the sheets themselves, are all consistent with melt loss and crystal accumulation during solidification. The wallrock tonalite also hosts K-feldspar megacrysts and hornblende phenocrysts that are interpreted to be the same population as those in Red Granite, on the basis of their size, shape, nature of inclusions, compositions and compositional zoning. We propose that these crystals were transferred from the intrusive Red Granite magma to the wallrock tonalite via magmatic conduits that subsequently collapsed due to external stresses, leaving behind the larger crystals. The pristine preservation of intrusive relations at Oncocua Platform may mean that crystal transfer from magma to wallrock is more common in incrementally assembled granitoid plutons than previously thought. Supplementary material: Mineral chemical data are available at https://doi.org/10.6084/m9.figshare.c.5448664

The Cocos Ridge, which is subducted beneath the Central American Volcanic Arc, has a complex tectonic evolution history due to plume-ridge interaction between the Galápagos plume and the Cocos—Nazca spreading center. This study presents major and trace element analyses of plagioclase and clinopyroxenes hosted by Cocos Ridge basaltic rocks that were drilled in three holes (U1381A, U1381C and U1414A) of Sites U1381 and U1414 on the Cocos Ridge close to the Middle America Trench during the Integrated Ocean Drilling Program (IODP) Expeditions 334 and 344. The results show that (1) plagioclases are mainly bytownite and labradorite with subordinate andesine, which are enriched in light rare earth elements (LREE) and some large-ion lithophile elements (LILE) and exhibit marked positive Eu anomalies, and (2) that clinopyroxenes are augites, which are depleted in highly incompatible elements such as LREE and LILE, have nearly flat heavy rare earth elements patterns (HREE) and lack Eu anomalies in chondrite-normalized rare earth element (REE) diagrams. During the ascent to the surface, the primary magmas experienced fractional crystallization of plagioclase, clinopyroxene, Ti-Fe oxides and possibly olivine (complete replacement of olivine by secondary minerals). The crystallization temperatures of plagioclase phenocrysts and microlites are 1050 to 1269 °C, and 866 to 1038 °C, respectively, and the pressures of plagioclase phenocrysts are 0.3–0.7 GPa. The crystallization temperatures of clinopyroxene phenocrysts/micro-phenocrysts is 1174–1268 °C, similar to those of plagioclase phenocrysts, suggesting some of clinopyroxene and plagioclase phenocrysts cotectic crystallized during early stage of magmatic evolution. In addition, the equilibrium pressures of clinopyroxene phenocrysts/micro phenocrysts are 0.02–0.97 GPa, implying that the clinopyroxene started to crystallize within the mantle, and magma evolution has undergone an early crystallization stage with clinopyroxene and no plagioclase.

This study reveals the petrographic and geochemical characteristics, physico-mechanical properties, and chemical alteration indices of Hisartepe volcanic rocks with basaltic andesite, trachyandesite, and andesite composition. Although all rocks have common groundmass plagioclase microlites, the porphyritic texture is majorly evident except for aphyric Asartepe samples. Phenocryst rates vary by location, and vesicle rates are around the maximum of 5%. The chemical alteration indices used to determine the degree of alteration of rocks are in a narrow range and indicate a weak and limited alteration. Plagioclase index of alteration (PIA) and sericitization index (SI) imply the alteration degree of plagioclase mineral abundance in most study area rocks. According to these indices, the most altered rocks in the study area are in the NE Davutlar and Hisartepe regions. Petrographic determination and XRD analysis of rocks verify these results. The rocks of the study area yielded uniaxial compressive strength (UCS) varying between 36.80 and 87.40 MPa classified as low and medium strength. Bohme abrasion of the study area rocks changes from 6.90 to 12.65 cm3/50 cm2 and increases with the degree of alteration and loss on ignition (LOI). The USC and point load strength values increase with the decrease in phenocryst sizes and ratios. The different results seen in the chemical alteration indices of volcanic rock samples taken from different locations are due to the modal mineralogy in rocks. Petrographic characteristics such as the phenocryst ratio and phenocryst size along with the alteration affect the mechanical properties of the volcanic rocks. As a result, the Sivritepe and Asartepe samples are the best samples in terms of engineering properties.

The Lower Oligocene Kal-e-kafi (East of Anarak, Central Iran) lamprophyres occur as stocks and dikes, which cross-cut the Eocene volcanic and Cretaceous sedimentary rocks. The predominant minerals of these lamprophyres are hornblende (magnesiohastingsite) and clinopyroxene (diopside) phenocrysts set in a fine- to medium-grained matrix of the same minerals plus plagioclase (labradorite to bytownite), sanidine, apatite, and magnetite. Secondary minerals are chlorite, magnetite, calcite, and epidote. Petrography, mineral chemistry, and whole rock compositions classify these rocks as calc-alkaline lamprophyre, in general, and spessartite in particular. These samples have intermediate compositions (SiO2 ~ 58 wt %). The chondrite-normalized REE patterns and primitive mantle-normalized multi-element spider diagram of Kal-e-kafi lamprophyres are remarkably parallel and suggest that these dikes and stocks were derived from the same parental magma and underwent similar melt extraction. These rocks are enriched in alkalies, large-ion lithophile elements (e.g., Rb, Ba, K), and light rare-earth elements (e.g., La, Ce), and exhibit moderate to high fractionation in LREE patterns, with an average La/Lu ratio of 112. The large amount of hydrous fluids coming from the subducted slab rather than sediments caused to the enrichment and metasomatism of subcontinental lithospheric mantle source. Crustal contamination and assimilation of host rocks also played role in the genesis of these lamprophyres. Geochemical characteristics of the studied rocks suggest that parental magma have been derived from partial melting of a metasomatized amphibole-bearing spinel lherzolite of lithospheric mantle, which was previously modified by dehydration of a subducting slab. Subduction of oceanic crust around the Central-East Iranian Microcontinent (CEIM) is the most reasonable mechanism to explain enrichment in volatiles of the mantle, and the lamprophyric magmatism of the Kal-e-kafi area in Lower Oligocene times. Several tectonomagmatic discrimination diagrams indicate that the Kal-e-kafi lamprophyres occurred during postcollisional period of lithospheric extension.

Olivine phenocrysts in basalts erupted in the Kaikohe-Bay of Islands volcanic field (KBIVF), a cluster of Quaternary monogenetic edifices in northern New Zealand, provide an opportunity to investigate magma source and assembly. The phenocryst population has both cognate and non-cognate origins with respect to the carrier magma. Common large subhedral-euhedral phenocrysts with compositions of Fo80–86 are autocrysts, having nucleated in a melt equivalent of the host whole-rock (~Mg#56–63). A subordinate population of large subhedral-euhedral phenocrysts that are Mg-rich (>Fo86) nucleated in a melt more mafic (>Mg#65). These are antecrystic and are likely to have a deep cumulate origin, perhaps the product of fractionation of a primitive parental magma. Smaller anhedral phenocrysts have compositions (~Fo70–75) that would have crystallised in a more evolved melt (~Mg#42–48). These are xenocrysts from stalled and fractionated crystal mush zones or intrusions in the mid and upper crust. Other small phenocrysts (Fo66–79) are euhedral and reversely zoned with mafic mantle zones (Fo80–85). They also nucleated in a more evolved crustal magma, but subsequently experienced magma-mixing with a more mafic magma. The olivine assemblage requires a vertically extensive magma system through the crust and upper mantle involving deep cognate crystallisation, and recycling of non-cognate crystals from deep and shallow intrusive bodies. This in accord with varied origins for the accompanying plagioclase and clinopyroxene populations in the rocks demonstrated in previous studies. This study presents the first δ18O analyses of olivines from monogenetic volcanoes in New Zealand. SIMS analysis of cognate and cumulate olivine phenocrysts in KBIVF basalts, and those from other volcanoes in northern New Zealand basaltic fields, show that they are non-zoned (δ18O ± 0.4‰). The inter-crystal range at most volcanoes is narrow (0.5‰), although the olivine population at a few volcanoes are more varied (range up to 1.25‰), requiring more than one source. The isotopic data for the more northern fields KBIVF (δ18O mean = 5.60‰; range = 5.12–6.20‰) and Whangarei volcanic field (δ18O mean = 5.50‰; range = 4.98–6.12‰) include values higher than that of olivine from MORB-HIMU sources, and overlap those associated with EMI/EMII sources or subduction zone magmas. Whole-rock trace element and Pb-isotope data from these fields have been interpreted as the result of subduction-induced contamination of the mantle wedge, a relic signal from now extinct Miocene-Pliocene arc volcanism. The magma compositions are also consistent with source depths above the garnet facies zone. This could explain the higher olivine δ18O values. In contrast, olivines from more southern fields do not display this O-isotope signature, consistent with postulated greater source depths.

The composition of mantle-derived basalts reflects the geochemical nature of their source regions in the mantle. Olivine is generally the first mineral to crystallize from basaltic melts, with the composition of this mineral providing important constraints on primary magma compositions. This study presents new whole-rock major- and trace-element, Sr-Nd-Hf isotopic, olivine compositional, and mineral O isotopic data for Cretaceous basalts within the Luxi and Jiaodong areas of east-central China. These data provide insights into the processes that caused the compositional differences between the two types of basaltic rocks. The first type was erupted during the Early Cretaceous with high SiO 2 contents and Mg# values [100 Mg/(Mg + Fe 2+ ), molar ratio], and low (Fe 2 O 3 ) T and TiO 2 contents. These basalts have island-arc basalts (IAB)-like trace-element patterns and enriched Sr-Nd-Hf isotopic compositions with high ( 87 Sr/ 86 Sr) i ratios and negative e Nd (t) and e Hf (t) values. They also contain phenocrysts of olivine and clinopyroxene that have consistently high δ 18 O values. The most primitive olivine phenocrysts within these basalts have Ni and Mn contents and Fe/Mn ratios similar to those of olivine from mid-ocean-ridge basalts (MORB). The second type generally has basanite compositions and was erupted during the Late Cretaceous, with low SiO 2 contents and Mg# values, and high (Fe 2 O 3 ) T and TiO 2 contents. These basanites have ocean-island basalt (OIB)-like trace-element patterns and depleted Sr-Nd-Hf isotopic compositions with low ( 87 Sr/ 86 Sr) i ratios and positive e Nd (t) and e Hf (t) values. Olivine and orthopyroxene phenocrysts within these basalts have low δ 18 O values whereas the clinopyroxene phenocrysts have variable δ 18 O values. The most primitive olivine phenocrysts contain more Ni but less Mn and have higher Fe/Mn ratios than olivine formed in MORB settings. The contrasting geochemistry of these two types of basalts is indicative of derivation from mantle source regions with different compositions, reflecting different types of subduction-related crust-mantle interaction. The Early Cretaceous basalts were derived from an arc-like, isotopically enriched mantle domain that was formed at subarc depths by the metasomatic reaction of mantle wedge peridotite with felsic melts derived from the subducted continental crust during a Triassic continental collision event. In contrast, the Late Cretaceous basanites were derived from an OIB-like isotopically depleted mantle domain generated at postarc depths by the metasomatic reaction of mantle wedge peridotite with felsic melts derived from subducting oceanic crust of the Paleo-Pacific Plate.

International audience; Hydrous melting experiments on a basaltic andesite from Late Volcano in the Tonga Arc were conducted at 900–1250 °C and 1 atm to 2.5 GPa, with a range of added H2O concentrations (0–9 wt%). These were used to constrain conditions of phenocryst precipitation in the basaltic andesite and to better understand the processes of magmatic differentiation beneath Tongan volcanoes. Comparison between the products of experiments and Tongan lavas indicates that basaltic andesites from Late crystallised plagioclase + augite + pigeonite ± orthopyroxene while water-saturated at comparatively low pressures (≤0.2 GPa) but high temperatures (≥1000 °C). Glasses produced at 950 °C and 0.2 GPa are similar in composition to dacites from neighbouring volcanoes, including Fonualei. This confirms previous interpretations of dacite magma genesis by crystal fractionation of plagioclase and clinopyroxene from basaltic andesite parent magmas, rather than by partial melting of lower crust. This produces decreases in Dy/Yb with increasing SiO2 without a role for amphibole, probably due to the high temperatures and low alkali concentrations involved. Tongan magmas are primarily tholeiitic, and their high water contents bring into question previous hypotheses that attribute the tholeiitic trend to low concentrations of magmatic H2O. Attributes inherited from the Tongan parent magmas, including low alkali concentrations, appear to drive tholeiitic differentiation, regardless of water content.

Kimberlites are often closely associated, both in time and space, with a wide variety of alkaline ultramafic rock types, yet the question of a genetic relationship between these rock types remains uncertain. One locality where these relationships can be studied within the same cluster is the Karelian craton in Finland. In this study we present the first petrographic, mineral and whole-rock geochemical results for the most recently discovered kimberlite cluster on this craton, which represents an example of the close spatial overlap of kimberlites with ultramafic lamprophyres. The Kuusamo cluster incorporates seven bodies [Kasma 45, Kasma 45 south, Kasma 47, Kalettomanpuro (KP), Kattaisenvaara (KV), Dike 15 and Lampi] distributed along a 60 km NE–SW corridor. Hypabyssal samples from KV, KP, Kasma 45 and Kasma 47 consist of altered olivine macrocrysts and microcrysts and phlogopite phenocrysts in a groundmass of perovskite, apatite, spinel, ilmenite, serpentine, and calcite. These petrographic features combined with mineral (e.g. Mg-rich ilmenite, Al–Ba-rich, Ti–Fe-poor mica) and whole-rock incompatible trace element compositions (La/Nb = 0·8 ± 0·1; Th/Nb = 0·07 ± 0·01; Nb/U = 66 ± 9) are consistent with these rocks being classified as archetypal kimberlites. These Kuusamo kimberlites are enriched in CaO and poor in MgO, which, combined with the absence of chromite and paucity of olivine macrocrysts and mantle-derived xenocrysts (including diamonds), suggests derivation from differentiated magmas after crystal fractionation. Samples from Lampi share similar petrographic features, but contain mica with compositions ranging from kimberlitic (Ba–Al-rich cores) to those more typical of orangeites–lamproites (increasing Si–Fe, decreasing Al–Ti–Ba), and have higher bulk-rock SiO2 contents than the Kuusamo kimberlites. These features, combined with the occurrence of quartz and titanite in the groundmass, indicate derivation from a kimberlite magma that underwent considerable crustal contamination. This study shows that crustal contamination can modify kimberlites by introducing features typical of alkaline ultramafic rock types. Dike 15 represents a distinct carbonate-rich lithology dominated by phlogopite over olivine, with lesser amounts of titaniferous clinopyroxene and manganoan ilmenite. Phlogopite (Fe–Ti-rich) and spinel [high Fe2+/(Fe2+ + Mg)] compositions are also distinct from the other Kuusamo intrusions. The petrographic and geochemical features of Dike 15 are typical of ultramafic lamprophyres, specifically, aillikites. Rb–Sr dating of phlogopite in Dike 15 yields an age of 1178·8 ± 4·1 Ma (2σ), which is considerably older than the ∼750 Ma emplacement age of the Kuusamo kimberlites. This new age indicates significant temporal overlap with the Lentiira–Kuhmo–Kostomuksha olivine lamproites emplaced ∼100 km to the SE. It is suggested that asthenospheric aillikite magmas similar to Dike 15 evolved to compositions akin to the Karelian orangeites and olivine lamproites through interaction with and assimilation of MARID-like, enriched subcontinental lithospheric mantle. We conclude that the spatial coincidence of the Kuusamo kimberlites and Dike 15 is probably the result of exploitation of similar trans-lithospheric corridors.

The Mariana Trough, a relatively simple intra-oceanic back-arc basin, is ideal for investigating magmatic processes and mantle-crust interaction in a subduction setting. We present new major- and trace element compositions for 31 basaltic lava and glass samples from the Mariana Trough back-arc spreading center. The studied lavas include phenocrysts of plagioclase, olivine and pyroxene. Major element compositions show that these lavas range from tholeiitic basalt to basaltic andesite, and belong to a sub-alkali tholeiitic series produced by fluid-influenced fractional crystallization of primary basaltic melts. Trace element compositions show that these lavas are transitional between typical normal mid-ocean ridge basalts (MORB) and island arc basalt (IAB), and are enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs). Trace element ratios, e.g., Ba/Th, Pb/Ce, Th/Nd, La/Sm, Th/Nb, Ba/Nb and Th/Nb, indicate that the mantle from which these lavas were derived underwent modification resulting from the addition of multiple subduction components. Some typical trace element ratios (e.g., Ba/Nb- total subduction component, Ba/Th- shallow subduction, and Th/Nb-deep subduction component) from our new data and the literature suggest that a latitudinal variation exists in addition to subduction components, and indicates a more complex and heterogeneous distribution of subduction components in the Mariana back-arc region. We suggest that, (1) compared to back-arc locations at 18° N and 15.5° N, lavas from back-arc locations at 17° N indicate higher levels of modification by hydrous fluid released from the subducted slab, and (2) compared to back-arc locations at 17° N and 15.5° N, petrogenesis of lavas from back-arc locations at 18° N indicates a greater influence of sediment melt.

O Stock Serra da Acauã está inserido no contexto da atividade plutônica ediacarana, uma das mais importantes feições geológicas na Província Borborema, Nordeste do Brasil. O corpo está dividido em duas fácies: uma equigranular fina a média e outra inequigranular média a fracamente porfirítica com fenocristais de K-feldspato. Determinações U-Pb em zircão apontaram uma idade ediacarana de c.a 578 Ma para a sua cristalização. Petrograficamente, o stock consiste de um biotita monzogranitos hololeucocráticos a leucocráticos (M = 1,3 – 9,9%), com biotita sendo o máfico principal (0,5 a 8,1%). Minerais opacos, titanita, allanita, apatita e zircão são acessórios e as fases minerais mais precoces. As rochas que formam o stock são geoquimicamente similares, de caráter fracamente peraluminoso (1,00 ≤ A/CNK ≤ 1,04), com coríndon normativo e de assinatura transicional entre rochas alcalinas e calcioalcalinas. A variação do conteúdo de óxidos e elementos traço sugere o fracionamento de plagioclásio, biotita, titanita, apatita e magnetita durante a cristalização do magma. O diagrama para elementos terras raras mostra enriquecimento dos elementos terras raras leves em relação aos elementos terras raras pesados, com razões LaN/YbN entre 16,10 e 54,75, e anomalias negativas de Eu (Eu/Eu* de 0,66 a 0,90) compatíveis com fracionamento de plagioclásio. Dados referentes à temperatura de saturação de zircão somados a diagramas discriminantes geoquímicos permitem associar essas rochas a granitos tipo I altamente fracionados. O conjunto de dados permite correlacionar o magmatismo no contexto de granitoides calcioalcalinos de alto potássio, tardi a pós-tectônicos do Domínio Rio Piranhas-Seridó.

Four basaltic phenocryst samples of plagioclase, with compositions ranging from An48(andesine) to An64(labradorite), have been studied with single-crystal X-ray and neutron diffraction techniques. The samples were also subjected to a heating experiment at 1100°C for two weeks in an effort to minimize the Al–Si ordering in their structures. The average and the modulated structures of the samples (before and after the heating experiment) were compared, in order to understand the mechanism of the phase transition from the disordered C\bar 1 structure to thee-plagioclase structure. A comparison between the structures from neutron and X-ray diffraction data shows that the 〈T—O〉 distance does not solely depend on the Al occupancy as previously thought. A dramatic decrease of the Al–Si ordering is observed after heating at 1100°C for two weeks for all four samples, with an obvious change in the intensities of the satellite reflections (e-reflections) in the diffraction pattern. Evident changes in the modulation period were also observed for the more calcic samples. No obvious change in the Ca–Na ordering was observed after the heating experiment. Anin situheating X-ray diffraction experiment was carried out on the andesine sample (An48) to study the change in the satellite intensity at high temperature. A dramatic weakening of the satellite peaks was observed between 477°C and 537°C, which strongly supports the displacive nature of the initiation ofe2 ordering. Rigid-Unit Mode (RUM) analysis of the plagioclase structure suggests the initial position of thee-reflections is determined by the anti-RUMs in the framework.

New geochronological, geochemical and Sr-Nd-Hf isotopic data for the early Cretaceous Daying volcanic sequence, eastern Qinling Orogen, provides a probe into the nature of, and tectonic process operating in, the underlying Mesozoic mantle. The volcanic rocks in the sequence are composed of basaltic trachyandesite, pyroxene-andesite, trachyandesite and trachyte. They yield zircon U-Pb and whole-rock 40Ar/39Ar plateau ages of 134–124 Ma, roughly synchronous with the Cretaceous igneous rocks throughout the eastern Qinling and Dabie orogens. Clinopyroxene and plagioclase phenocrysts of the volcanic rocks exhibit simple normal zonation with higher mg-number and An content in the core relative to the rim. The amphibole is characterized by tschermakite and tschermakitic hornblende with mg-number of 50–67. The Daying volcanic rocks have variable SiO2 (54.27–63.44 wt%), Al2O3 (15.39–20.34 wt%), FeOt (5.23–9.94 wt%), and MgO (1.05–4.03 wt%) contents with low mg-number (26–49). They exhibit arc-like REE- and PM-normalized patterns with significant negative Nb-Ta anomalies, and highly- enriched Sr-Nd isotopic composition with (87Sr/86Sr)i ratios of 0.7066–0.7078 and eNd(t) values of −15.5 ∼ −11.0. Their zircons exhibit strongly negative eHf(t) values ranging from −27.3 to −17.2 and two-staged model ages from 2.90 Ga to 2.28 Ga. Such geochemical signatures suggest that the Daying volcanic rocks were derived from a hybridized source of the North China Craton enriched mantle with the input of some Yangtze crustal materials created by Triassic deep-subduction digestion. They also share similar eruption time, as well as elemental and Sr-Nd-Hf isotopic compositions, with those in the southern margin of the North China Craton, suggesting a northward subduction of the Yangtze block. It is proposed that the volcanic rocks are petrogenetically related to an early Cretaceous extensional event along the Qinling- Dabie Orogenic belt in response to unrooting of the thickened lithosphere.

A new occurrence of lamprophyre dyke is being reported from Saurashtra peninsula of Gujarat, north-western Deccan trap. The paper presents and discusses the detail mineralogy, field setting and whole rock major and trace element geochemistry. The newly discovered lamprophyre dyke intruded into the porphyritic olivine basalt flow. It is E-W trending dyke paralleling with Narmada rift trend, 200 m long and ∼1 m in width. Petrographic observations suggest the lamprophyre dyke is fine grained, porphyritic and shows typical panidiomoprphic texture. It contains phenocrysts of euhedral to subhedral amphibole (kaersutite), subhedral clinopyroxenes (diposide augite) and olivine pseudomorph enveloped in the groundmass composed of plagioclase, clinopyroxene and amphibole with carbonate, Ti-magnetite, zeolite and apatite occurring as accessory phases. Few clinopyroxenes show reaction and embayed margins thus indicating xenocrystic orgin. The normative chemistry of the lamprophyre dyke suggests alkaline nature with significant amount of olivine and nepheline. Whole rock geochemical data shows comparatively higher SiO2 than the other lamprophyres of the Deccan and similar to the MgO depleted lamprophyres of the Chhota Udepur alkaline province. The primitive mantle normalized multielements pattern shows absence of any high field strength element (HFSE) anomaly. Studied dyke displays more similarity with the earlier reported pre- Deccan alkaline lamprophyres and more particular with the Chhota Udepur lamprophyre. Occurrence of this new lamprophyre dyke from the Saurashtra region extends and confirms the presence of lamprophyre magmatism in the far north-western part of the Deccan.