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Intensive agricultural practices implemented to secure increased crop yields have potentially negative environmental effects due to the generation of sediment and nutrients from agricultural fields. The monsoon climate and current agricultural practices on mountainous landscapes of the Haean catchment in South Korea have significantly affected water quality by transporting sediment and nutrients to downstream water bodies. The aim of this study is to suggest strategies for a permanent reduction of sediment and nitrate from this catchment through an efficient application of best management practices (BMPs). We applied three BMPs; split fertilizer application (SF), winter cover crop cultivation (CC), and a combination of the two (SFCC) to major dryland crops (cabbage, potato, radish and soybean) in order to investigate their effectiveness at the catchment scale through the Soil and Water Assessment Tool (SWAT) model. We found that the SF scenario reduced nitrate pollution while sediment and crop yield did not change relative to the baseline (BL) scenario. The application of the CC scenario reduces both sediment and nitrate load while crop yields increased. The combination of split fertilization and cover cropping (SFCC) showed the highest positive effect on reducing sediment and nitrate and increasing crop yields compared to a single application. We estimated the variability in the effectiveness of BMPs for major crop types and could demonstrate that specific sites and crop types, such as soybean, were less influential in reducing sediment and nitrate loads. Those sites and crops could be considered for additional BMP measures to mitigate water deterioration by target pollutants. Recommendations for BMP applications should also consider minor crops and other land use types in order to reduce overall water pollution and efficiently improve crop yields in this catchment.

Summary The linkage between hydrologic dynamics and the delivery of nitrate and DOC (dissolved organic carbon) to streams was studied in the Haean catchment, a mixed land-use mountainous catchment in South Korea. Three monsoonal precipitation events were analyzed, which varied in total rainfall amount (39–70 mm) and intensities (mean: 1.6–5.6 mm h −1 ), by high-resolution (2–4 h interval) stream water-quality sampling along the topographic elevation gradient of the catchment, from an upland deciduous forest stream, over areas intensively used for agriculture (dryland farming and rice paddies) down to the catchment outlet. The dynamics of river-aquifer exchange were investigated at two piezometer transects at mid and lower elevations. DOC and nitrate sources and their transport pathways to the receiving surface waters differed between the forested and the agricultural stream site. In the forest stream, elevated DOC concentrations (max: 3.5 mgC l −1 ) during precipitation events were due to hydrologic flushing of soluble organic matter in upper soil horizons, with a strong dependency on pre-storm wetness conditions. Nitrate contributions to the forested stream occurred along shallow subsurface transport pathways. At the agricultural sites stream DOC concentrations were considerably higher (max: 23.5 mgC l −1 ) supplied from adjacent rice paddies. The highest in-stream nitrate concentrations (max: 4.1 mgN l −1 ) occurred at river reaches located in the lower agricultural part of the catchment, affected by groundwater inputs. Groundwater nitrate concentrations were high (max: 7.4 mgN l −1 ) owing to chemical fertilizer leaching from dryland fields forced by monsoonal rainfalls. Overall, this study demonstrates that the hydrologic dynamics resulting from the monsoonal climate drive the in-stream DOC dynamics in the forested 1st-order catchment whereas sources and mobilization of DOC in downstream agricultural areas are mainly controlled by the prevailing land-use type and irrigation management. Nitrate dynamics in higher order agricultural streams and their connected aquifers reflect combined effects of land-use type and monsoonal hydrology.

Low cost lime-based waste materials have recently been used to immobilize metals in contaminated soils. This study wasconducted to evaluate theeffects of oyster shells and eggshells as lime-based waste materials on immobilization of cadmium (Cd) and lead (Pb) in contaminated soil, as well as their effects on metal availability to maize plants (Zea mays L.). Oyster shells and eggshells were applied to soils at 1 and 5% w/w, after which they were subject to 420 days of incubation. The toxicity characteristic leaching procedure (TCLP) test was employed to determine the mobility of Cd and Pb in soils. The results showed that the addition of waste materials effectively reduced the metal mobility as indicated by the decrease in the concentration of TCLP-extractable Cd and Pb, and this was mainly due to significant increases in soil pH (from 6.74 in untreated soil to 7.85‐8.13 in treated soil). A sequential extraction indicated that the addition of such alkaline wastes induced a significant decline in the concentration of Cd in the exchangeable fraction (from 23.64% in untreated soil to 1.90‐3.81% in treated soil), but it increased the concentration of Cd in the carbonate fraction (from 19.59% in untreated soil to 36.66‐46.36% in treated soil). In the case of Pb, the exchangeable fraction was also reduced (from 0.67% in untreated soil to 0.00‐0.01% in treated soil), and the fraction of Pb bound to carbonate was slightly increased (from 16.61% in untreated soil to 16.41‐18.25% in treated soil). Phytoavailability tests indicated that the metal concentrations in the shoots of maize plant were reduced by 63.39‐77.29% for Cd and by 47.34‐75.95% for Pb in the amended soils, with no significant differences being observed for the amendment types and the application rates. Overall, these results indicate that oyster shells and eggshells can be used as low cost lime-based amendments for immobilizing Cd and Pb in contaminated soils.

Military shooting range soils contaminated by heavy metals have been subjected to remediation efforts to alleviate the detrimental effects of exposure on humans and the surrounding environment. Waste materials can be used as cost-effective soil amendments to immobilize heavy metals in contaminated soils. In this study, naturally occurring lime-based waste materials including egg shells, oyster shells, and mussel shells were assessed for their effectiveness toward heavy metal immobilization in military shooting range soil in Korea. Soil was treated in batch leaching experiments with 0, 2.5, 5, 10, and 15% of each lime-based waste material. The results showed that the lime-based waste materials effectively reduced water-soluble Pb at an application rate of 2.5% by weight of the soil. Increase in soil pH from 6.6 to 8.0 was considered to be the main chemistry of Pb immobilization, which was supported by the formation of insoluble Pb species at high pH values as confirmed by the visual MINTEQ thermodynamic model. In contrary, water-soluble Cu was increased in the lime-based waste material-treated soils when compared to the untreated soil. This was likely attributed to the formation of soluble Cu–DOC (dissolved organic carbon) complexes as all lime-based waste materials applied increased DOC contents in the soil. Therefore, care must be taken in selecting the appropriate amendment for immobilizing metals in shooting range soils.