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The flexibility and insulating nature of polymeric dielectric materials are widely used in robotic and wearable electronic devices like electrical insulation, capacitive sensors, and electromechanical actuators. When combined with a phase transition-induced shape memory property, the resultant bistable electroactive polymer (BSEP) opens up new applications due to the rigid-to-rigid actuation of BSEP tremendously reducing the energy consumption for device operation while providing desirable strength for external loads. This dissertation focuses on investigating insulating, electroactive, and phase transition properties of BSEP, and adapting each aspect of the properties in the pursuit of innovative devices, such as rewritable photonic paper, smart windows with whole solar spectrum modulation, and wearable pressure sensors. An ink-free rewritable photonic paper has been invented through the interdisciplinary combination of photonic crystals, shape memory and electroactive properties of BSEP. The rewritable paper consists of a ferroferric oxide-carbon (Fe3O4@C) core–shell nanoparticle (NP)-based photonic crystal embedded in a BSEP. The nanocomposite can be repeatedly triggered to change into different shapes and colors due to the z-directional deformation that is induced by an electric field. The actuated shape and color can be maintained for a long term without energy input, and the stored images can then be rewritten over 500 times without noticeable degradation. Low energy consumption and simple erasing/rewriting are features that match the benefits of conventional paper as a zero-energy and long term data storage medium, but provide the additional advantage of rewritability. With pixelated electrode arrays, user-defined information can be actuated and erased at will which has been demonstrated through a seven-segment numerical display. A smart window with wide-band light modulation is designed solely based on the phase transition property of BSEP. One component of BSEP can be switched between semicrystalline and amorphous states through cooling below or heating above its melting temperature, leading to a reversible opaque-to-transparent transition. The opacity switching property of BSEP was further improved by mixing a more hydrophilic component to induce micro-scale phase separation, which is responsible for the whole solar spectrum light modulation due to Mie scattering. The resultant smart window achieves both high solar transmittance modulation of 70.2% and high luminous transmittance modulation of 80.4% which rivals the best reported smart windows and commercial privacy glasses with the highest privacy levels. This flexible smart window can also be mounted on curved surfaces for the need of windows with arbitrary shapes. This work is the first one to report an all-solid thermochromic smart window film without the inclusion of any metal/metal oxides or liquid crystals to enable a large light modulation over the whole solar spectrum.A flexible fiber-based pressure sensor is realized by applying a dielectric layer on the outside of a TEMPO-oxidized bacterial cellulose (TOBC)/silver nanowire (AgNW) conducting fiber. The pressure sensor can detect pressures up to 134 MPa with sensitivity of 101 � 10-4 kPa-1 due to its hierarchical structure and high conductivity. The porous structure of TOBC/AgNW helps increase the thickness deformation of the sensor with applied pressure, improving the sensing ability. Small pressures of human pulse and voice vibration can be detected with this sensitive pressure sensor. A machine learning classification model was implemented to recognize human’s speech where the prediction accuracy on a test dataset is > 90%. The ultrathin fibrous sensor (53 �m) is capable of high-resolution detection, and suitable as a comfortable and fashionable thread substitute for real wearable devices.The combined properties of BSEP with the proof-of-concept developments of rewritable paper, smart windows and wearable sensors demonstrate its potential for real-world applications. And an outlook for future research and suggested improvements for commercialization are discussed in the conclusion.

This paper investigates the influence of thermal pretreatment on kinetic parameters based on four kinetic models: Modified Gompertz, transference and logistic functions and first order equation. The kinetic modeling was applied on experimental results of previous study on producing methane from anaerobic digestion of Recycled Pulp and Paper Sludge (RPPS) under mesophilic conditions. We observed that the thermal pretreatment improve considerably improved the kinetic parameters mainly the methane production rate and the lag phase. Indeed, it can be noted that methane production rate μ increases significantly from a value of 4.72 to 16.27 Nml/h using logistic function for 1 g VS/L added load. Then the lag phase parameter λ has dramatically decreased from 5.46 to 1.04 h using logistic function for 1,5g VS/L added load. This means that the thermal pretreatment of RPPS accelerates the methane production process and saves time.

Bio-based additives received significant attention in pulp and paper properties improvement. For this, the most cited biochemical Cellulose Nano Fibrils (CNFs) and Cationic Starch (CS) were experimentally compared with the most declared synthetic chemical, Cationic Polyacrylamide (CPAM). SEM images showed better paper surface filling by the utilization of the chemicals. The three studied polymers, in solely or combination mechanism, improved mainly bagasse pulp and paper properties compared to the blank sample, except for pulp drainage, which decreased by CNFs to lower volumes presumably due to its intrinsic characteristics. Cationic polymers (CP) compared to CP/CNFs approaches increased pulp retention and drainage but decreased paper density and strengths. The best pulp retention and drainage achieved by CS followed by CPAM, while paper air persistency, density, and strength properties evaluated highest by CP/CNFs followed by CNFs. Generally, CS revealed a more significant improvement in pulp and paper properties than CPAM either with or without CNFs.

The world demand for paper has been increased due to the increasing population Therefore, to cop up the limited wood fiber resources introducing raw material in pulp and paper industries is necessary. The aims of this study to evaluate the pulp and paper-making properties of Caesalpinia decapetela based on proximate chemical composition, fiber morphology, pulping, bleaching, and physical test of the final product. The results proximate chemical analysis showed that C. decapetela has holocellulose content of 78.14±0.1 % and lignin content 18.0±0.04 %. Fiber morphology revealed that the fibers were 0.708 mm long, 18.63 μm width, and have 5.1 μm cell wall thicknesses. Kraft pulping of C. decapetale, was performed at different active alkali (5 %, 10 %, 15 %, 20 % and 25 %) and temperature (150, 160 and 170 °C), keeping the sulphidity 25 % constant. The pulp maximum yield 44.1 % was obtained at active alkali content of 15 %, temperature 160 °C, and cooking time 90 minutes. The effect of pulping on fiber morphology was studied using scanning electron microscopy which showed the surface of fiber before pulping was tight, orderly arranged and the texture was relatively hard. After pulping, there was the removal of lignin, hemicellulose, and cellulose. Due to this fiber become soft loosened and contain micro-pores. Pulp produced was bleached, sheet preparation and testing were performed. The prepared paper sheets have a tensile index of 28.19 Nm/gm, burst index of 1.359 kPa m 2 / gm 1.359\hspace{0.1667em}\text{kPa}\hspace{0.1667em}{\text{m}^{2}}/\text{gm} , and tear indices of 4.2 mN m 2 / gm 4.2\hspace{0.1667em}\text{mN}\hspace{0.1667em}{\text{m}^{2}}/\text{gm} . This study concluded C. decapetale can be the new raw material for pulp and paper making industries. However, pilot plant studies are required to check this raw material for the full recommendation of the pulp and paper industries.

The utilization of waste resulting from the pulp and paper industry as soil for technical and biological recultivation of disturbed lands, industrial waste discharges and other applications in line with their intended purpose use have been explored. Analysis of soil resulting from the frozen sediments of lignin settled sludge of JSC "BPPM" with the WAS resulting from the sewage treatment facilities have been carried out, chemical and agrochemical composition as well as toxicological properties have been studied. It is established that the resulting soil can intensify the recultivation succession of disturbed lands and contribute to plants growth and biomass increase, and their reproduction ability.

Alstonia boonei, an abundant lesser utilized species within the West African Subregion, was evaluated as an alternative raw material for pulp and paper production. The basic density (BD), fibre characteristics [fibre length (FL), fibre diameter (FD), lumen diameter (LD) and wall thickness (WT)], derived anatomical indices [Flexibility Ratio (FR), Slenderness Ratio (SR), Rigidity Coefficient (RC), Luce’s Shape Factor (LSF), Solids Factor (SF) and Runkel Ratio (RR)] and chemical composition (lignin, holocellulose, 1% NaOH solubility and ash contents) of A. boonei were studied to evaluate variation along the trunk (base, middle and top portions) and ascertain its suitability for pulp and paper production. Significant variations were observed in the density and fibre characteristics along the trunk of the tree. Although the FD was large, the observed adequate FL, thin-wall and large LD implied easy beating of fibres and manufacture of dense, smooth and strong papers. The favourable SF, RR, FR, RC, and LSF values obtained for the fibres would produce papers with suitable burst and tearing strengths and folding endurance. Chemically the lower lignin (< 30%), ash and 1% NaOH solubility and the high holocellulose contents of A. boonei, will generate a higher pulp yield. A. boonei although a low-density species, will be desirable for pulp and paper production.

We present how harmful different wood extractives carried over to paper mill with unbleached softwood Kraft pulp are for the strength of packaging papers and boards. The investigations were done by simulating industrial papermaking conditions in laboratory-scale trials for handsheet production. It was found that fatty acids are the most relevant compounds in the carryover pitch extractives (CPEs), as they readily interfere in fiber–fiber bonding strength, control the properties of CPE micelles, and are furthermore the most abundant compounds. Addition of cationic starch improved strength and evened out the strength differences of handsheets with different CPE compounds. Oleic acid (unsaturated fatty acid) was an exception, as it was above average harmful for paper strength without cationic starch and also heavily impaired the functioning of cationic starch. As a whole, these findings demonstrate that fatty acids, especially unsaturated ones, are the most relevant CPE compounds contributing to the reduced efficiency of cationic starch and decreased strength of unbleached softwood Kraft paper. This makes the cleaning of process waters by precipitating CPEs on the pulp fibers harmful for paper strength.

Scaling biosynthesis of bacterial nanocellulose (BNC) allowed samples of composite paper with an increased proportion of BNC to be obtained. This work aims to study BNC samples and bleached soft wood kraft pulp (BSKP) composite paper with a ratio of components varying across a wide range: 10:90, 30:70, 50:50, 60:40, 70:30, 90:10. The method of paper manufacturing was chosen based on the determinations of strength and deformation properties of composite samples with the BNC:BSKP ratio of 20:80. Surface application of BNT on BSKP handsheet provided for an increase in the strength values (tear resistance – by 37%, burst index – by 17%) and deformation characteristics (tension stiffness – by 66%, fracture work – by 8%, breaking length – by 4%) compared to a reference sample. The formation of composites is confirmed in all samples. Scanning electron spectroscopy revealed that paper composites comprise interlaced micro BSKP and nano BNC fibres. As the proportion of BNC in composites elevated, densification of the structure was observed due to an increased fraction of cross-linked nanosized elements. IR spectroscopy indicated the resemblance of cellulose structure in all samples. It was found that an increase in the degree of polymerisation of composite paper is directly proportional to an increase in the BNC amount in the samples. The filtering ability of composite paper samples against microorganisms in the culture liquid of the Medusomyces gisevii Sa-12 producer was studied. It should be noted that yeast retention is achieved with 70% BNC in the paper composite. The presented properties of the new material determine prospects for its use in filtering microorganisms.

Biodegradable paper cups coated with rice bran wax and whey protein isolate were designed to package popcorn. Coatings with different concentrations of whey protein isolate (5.5, 7.75, and 10% w/v) and rice bran wax (0.2, 0.4, and 0.6% w/v) were applied on the outer surface of the paper cups. Thickness, color changes, Young's modulus and tensile strength, water vapor transmission rate (WVTR) of the coated and uncoated cups, and also popcorns properties (pH, texture, and sensory properties) were evaluated. Water vapor transmission rate, Young's modulus, thickness, total color change index, and tensile strength of coated cups with the optimal coating formulation was 19.785 (g/m2 day), 11.810 (MPa), 276.583 (µm), 1.839, and 11.222 (MPa), respectively. The results showed that paper cup coating increased thickness and yellowness and reduced the brightness, Young's modulus, and WVTR. Coating had a positive effect on the pH and texture of popcorns packaged in coated cups than samples packed in uncoated cups (p, Biodegradable packaging is one of the best types of packaging that wishes not to harm the environment. Paper packaging coated with materials, such as rice bran wax and whey protein isolate, both of which are food waste, can improve paper color and resistance, and provide a good moisture barrier. This type of coating can be used in paper packaging of food such as snacks, noodle packaging, semi‐prepared foods, etc. This type of packaging can also maintain the physicochemical and sensory properties of food for a long time. Also, due to the edible nature of this type of coating, this coating can be used inside the package so that the printability of the packaging surface is not affected.

The aim of this study was to investigate the effect of using whey powder (different concentrations and treatment repetitions) as a probiotic agent on the quantitative and qualitative properties of stored bagasse intended for use in the pulp and paper industry. For this purpose, whey powder was added in three concentrations and the treatment was applied once or twice. After that, soda pulp was prepared under conventional conditions. Then, handsheets (80 g/m2) were made and tested in terms of paper properties, and the results were compared. The findings revealed that increasing the concentration of whey powder and the number of treatments significantly improved the pulp and paper characteristics, thus, using the treatment with 2% whey powder twice and 0.4% whey powder once led to the best results for bagasse protection in terms of quality of the raw material, pulp and handsheets.

Paper manufacturing on a global scale is a highly competitive market which requires to constantly improve the manufacturing process to be competitive. To decrease production cost paper manufactures, add filler material prior to sheet forming to replace costly wood fiber based raw material. This research project investigates the use of in-situ precipitated calcium carbonate produced in the presence of eucalyptus fiber material at a 41.0% filler level prior to beating. The in-situ filler containing eucalyptus fiber suspension was used on a 12’ (304mm) wide Laboratory Fourdrinier Paper Machine together with non-filler containing eucalyptus fiber material, and a commercial precipitated calcium carbonate filler material. The manufactured in-situ fiber suspension resulted in a higher ash retention compared to the addition of the powdered commercial PCC filler material. In addition to commercial filler material retention is improved at higher filler addition above 30%. The increased ash retention is linked to the increased micro fibrillation fiber material of the in-situ filler-fiber suspension forming neckless like particles on the fibers microfibrils. Mechanical paper properties showed an improvement for in-situ precipitated filler material compared to commercial filler material addition. Optical properties could be improved in comparison to the eucalyptus fiber without filler addition for in-situ precipitated filler material and a combination of in-situ and commercial filler material.

Transition towards carbon neutrality will require application of negative carbon emission technologies (NETs). This creates a new opportunity for the industry in the near future. The pulp and paper industry already utilizes vast amounts of biomass and produces large amounts of biogenic carbon dioxide. The industry is well poised for the use of bioenergy with carbon capture and storage (BECCS), which is considered as one of the key NETs. If the captured carbon dioxide can be used to manufacture green fuels to replace fossil ones, then this will generate a huge additional market where pulp and paper mills are on the front line. The objective of this study is to evaluate future trends and policies affecting the pulp and paper industry and to describe how a carbon neutral or carbon negative pulp and paper production process can be viable. Such policies include, as examples, price of carbon dioxide allowances or support for green fuel production and BECCS implementation. It is known that profitability differs depending on mill type, performance, energy efficiency, or carbon dioxide intensity. The results give fresh understanding on the potential for investing in negative emission technologies. Carbon capture or green fuel production can be economical with an emission trade system, depending on electricity price, green fuel price, negative emission credit, and a mill’s emission profile. However, feasibility does not seem to evidently correlate with the performance, technical age, or the measured efficiency of the mill.

The rapid economic growth and environmental concerns have led to high demands on paper and paper-based products in terms of variety, quantity, quality, and specialty. Enhancement and functionalization with additives are constantly required. Moving away from traditional petroleum-based additives, researchers have attempted to use “green” nanoadditives by introducing renewable environmentally friendly nanocellulose. This article studies the functions of nanocellulose as bio-additives (enhancer, retention and filtration reagent, and coating aid) in paper and paper products, and overviews the research development of nanocellulose-based additives and their applications in the paper industry for both efficient production and paper functionalization. The review shows that (1) a variety of nanocellulose-based bioadditives have been reported for various applications in paper and paper-based products, while commercially viable developments are to be advanced; (2) nanocellulose was mostly formulated with other polymer and particles as additives to achieve their synergistic effects; (3) major interests have concentrated on the nanocellulose in the specialty papers as representing more value added products and in the efficient utilization of recycled fibers, which remains most attractive and promising for future development. This report shall provide most useful database information for researchers and industries for paper recycling and enhancement, and paper-based products innovation and application.

The pulp and paper industry is highly energy-intensive. In mills that use chemical pulping, roughly half of the higher heating value of the cellulosic material used to manufacture the product typically is incinerated to generate steam and electricity that is needed to run the processes. Additional energy, much of it non-renewable, needs to be purchased. This review considers publications describing steps that pulp and paper facilities can take to operate more efficiently. Savings can be achieved, for instance, by minimizing unnecessary losses in exergy, which can be defined as the energy content relative to a standard ambient condition. Throughout the long series of unit operations comprising the conversion of wood material to sheets of paper, there are large opportunities to more closely approach a hypothetical ideal performance by following established best-practices.

The adsorption of locust bean gum (LBG) onto Northern Bleached Softwood Kraft (NBSK) pulp improved paper tensile and burst strength and lowered refining energy by strengthening inter-fibre bonding. Adsorption kinetics and isotherms were investigated to develop a fundamental understanding of the adsorption mechanism. The adsorption rate followed pseudo-second-order kinetics and the activation energy was 99.34 kJ·mol−1, suggesting chemisorption. The adsorption rate constant increased rapidly with temperature from 25 to 45 °C (k = 1.93 to 24.03 g·mg−1·min−1), but the amount adsorbed at equilibrium decreased (qe = 1.91 to 0.48 mg·g−1 o.d. fibre). LBG adsorption to NBSK at 25 °C was consistent with the Langmuir adsorption model for LBG n = 5.00, and the equilibrium constant Kf = 2.57 mg·g−1·(mg·L−1)−1/n at 25 °C. Favorable adsorption conditions for negatively charged LBG were identified: 25 °C for 10 min, low dosage level ( 150 r.p.m.), acidic or neutral conditions (pH 2–7) without salt addition. Graphic abstract

Introduction. The Shchuchiy Bay is located in the western part of the skerry area of Lake Ladoga near the town of Priozersk. For almost 20 years, the bay has experienced an anthropogenic impact from the ingress of untreated wastewater from the Priozersk Pulp and Paper Mill (PPM). Systematic microbiological studies of the Shchuchiy Bay ecosystem were started in the middle of the 1970s by the Institute of Limnology of the Russian Academy of Sciences and continued after the PPM closure in 1986. Materials and methods. The ecosystem of the bay was studied in detail during the growing season of 2013–2014; periodic studies were carried out in 2015–2018. Retrospective data were also used for the analysis. Water samples were taken at four stations from the surface horizon. The following microbiological indicators were determined: the abundance of bacterioplankton and the percentages of various morphological types of bacterial cells. Results and discussion. A comparison of the quantitative level of development of the bacterial community in the bay in different periods showed a gradual decrease in the abundance of bacterioplankton as the anthropogenic impact weakened after the closure of the Priozersky PPM from 12.40 million cells ml–1 in 1987 to an average value of 2.62±1.03 million cells ml–1 in 2013–2018. A positive correlation was found between the concentration of bacteria and water temperature. The percentage of rod-shaped microorganisms in the water of the bay also decreased as the anthropogenic impact weakened from 73.4 % in 1987 to 53.1±7.6 % in 2013–2018, which indicated an improvement in water quality. Conclusion. A stable decrease in the abundance of bacteria from the level characteristic of highly polluted and eutrophic water bodies to the level characteristic of mesotrophic and mesotrophic-eutrophic water bodies is a reliable criterion for the restoration of the ecosystem of the Shchuchiy Bay to the state characteristic of similar bays of Lake Ladoga.

Transforming Pulp and Paper (P&P) mills into Integrated Forest Biorefineries (IFBR) is a prominent solution to save Canadian P&P industry that has been facing decline of conventional paper demand. ...

Xylan is the primary hemicellulose in most hardwood species, especially in birch. Research has highlighted the exploitation of xylans as a strength-enhancing additive to paper due to the current trend for the effective utilization of biomass. In this paper, a new pulping process was proposed, which involved the extraction of xylan prior to pulping, followed by the re-adsorption of the pulp after the final stage in the digester, followed by a suitable bleaching process. The aim of this work was to bleach hardwood kraft pulp (brown pulp) with adsorbed birch xylan via hydrogen peroxide and study the effect of the bleaching parameters on the paper properties. The results showed that the optical properties of paper decreased; however, the mechanical properties increased after the brown pulp adsorbed birch xylan. During the bleaching process, better mechanical properties were obtained with shorter bleaching times and lower bleaching temperatures, initial pHs, and MgSO4 dosages. However, the optical properties were improved as the bleaching time, temperature, initial pH, and MgSO4 dosage were increased. The adsorption of birch xylan could effectively modify the mechanical properties of paper made from brown pulp under various phases.