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Review: [83 refs. [ABSTRACT FROM AUTHOR]

Review: [39 refs. [ABSTRACT FROM AUTHOR]

Chemical equations related to "Asymmetric Synthesis of N-Aryl Sulfinamides: Copper(I)-Catalyzed Coupling of Sulfinamides with Aryl Iodides via Kinetic Resolution" by Y. Liu and colleagues published in the "Tetrahedron Letters" periodical is presented.

The article presents chemical equations to the article "Enantioselective Formation of Cyano-Bearing All-Carbon Quaternary Stereocenters: Copper-Catalyzed N-Arylation via Kinetic Resolution" by Y. Long published in the journal "Synthesis" in 2015.

A series of title compounds is prepared as building blocks for functional chiral molecules. In situ precipitation of the racemate causes an amplification of the solution e.e. values and thus allows the isolation of the target compounds with excellent enantioselectivity. Only in the case of product (IIf), the e.e. of the solid is higher than that of the solution. The use of unsymmetrical educts of type (III) leads to formation of 2 monocyclization quinoline intermediates which finally afford the same spirolactam. [ABSTRACT FROM AUTHOR]

An abstract of the article "Copper-Catalyzed Intramolecular Desymmetric Aryl C-O Coupling for the Enantioselective Construction of Chiral Dihydrobenzofurans and Dihydrobenzopyrans" by W. Yang and colleagues is presented.

The method has been successfully applied in the syntheses of selective 5-HT1A receptor agonist MKC-242 (VIIIa) and selective α1D-adrenoceptor inhibitor WB4101 (VIIIb). [ABSTRACT FROM AUTHOR]

The products are obtained in good yields and with moderate enantiomeric excess. [ABSTRACT FROM AUTHOR]

The cyano group at the prochiral center plays a key role for the high enantioselectivity of the copper-catalyzed intramolecular N-arylation reactions to give tetrahydroquinoline and tetrahydrobenzoazepine derivatives. [ABSTRACT FROM AUTHOR]

The article presents chemical equations related to the article "Pd-Catalyzed Desymmetric Intramolecular O-Arylation Reaction: Enantioselective Synthesis of (3,4-Dihydro-2H-chromen-3-yl) methanols" by W. Yang, J. Yan. Y. Long and others published in the Journal "Organic Letters" in 2013 issue.

Kinetic resolution by copper-catalyzed N-arylation is reported for the first time. [ABSTRACT FROM AUTHOR]

The first highly enantioselective protocol for preparation of indolines and tetrahydroquinolines via Cu-catalyzed asymmetric desymmetrization of 2-propanamines and 3-pentaneamines, respectively is presented. [ABSTRACT FROM AUTHOR]