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This study analyzed the differences in ozone (O3) sensitivity in four different urban areas in China from February 2019 to January 2020 based on data on various near-surface pollutants from passive multi-axis differential optical absorption spectroscopy (MAX-DOAS) sites and nearby China National Environmental Monitoring Center (CNEMC) sites. Across the four cities, the nitrogen dioxide (NO2) and formaldehyde (HCHO) concentrations varied seasonally. Xianghe consistently displayed the lowest NO2 levels, suggesting reduced emissions compared to other cities. Guangzhou, a city with a robust economy and a high level of vehicle ownership, exhibited higher concentrations in spring. Summer brought elevated HCHO levels in Guangzhou, Xianghe, and Shenyang due to intensified photochemical processes. Autumn and winter showed higher HCHO concentrations in Guangzhou and Xianghe compared to Lanzhou and Shenyang. Overall, Guangzhou recorded the highest annual averages, due to its developed economy, while Xianghe's lower NO2 levels were offset by the elevated HCHO due to higher O3 values. The analysis delved into primary and secondary HCHO sources across seasons and used carbon monoxide (CO) and O3 data. Xianghe showcased the dominance of secondary sources in summer and autumn, while Lanzhou was characterized by primary dominance throughout the year. Shenyang mirrored Xianghe's evolution due to industrial emissions. In Guangzhou, due to the high levels of vehicular traffic and sunlight conditions, secondary sources predominantly influenced HCHO concentrations. These findings highlight the interplay between primary and secondary emissions in diverse urban settings. This study explored O3 sensitivity variations across seasons. Xianghe exhibited a balanced distribution among volatile organic compound (VOC)-limited conditions, nitrogen oxide (NOx)-limited conditions, and transitional influences. Lanzhou was mainly affected by VOC-limited conditions in winter and NOx-limited conditions in other seasons. Shenyang's sensitivity varied with the seasons and was primarily influenced by transitions between VOCs and NOx in autumn and NOx-limited conditions otherwise. Guangzhou experienced varied influences. During periods of high O3 pollution, all regions were affected by NOx-limited conditions, indicating the necessity of NOx monitoring in these areas, especially during summer in all regions and during autumn in Xianghe and Guangzhou. [ABSTRACT FROM AUTHOR]

Restrictions on human activities remarkably reduced emissions of air pollutants in China during the COVID-19 lockdown periods. However, distinct responses of O3 concentrations were observed across China. In the Beijing–Tianjin–Hebei (BTH) and Yangtze River Delta (YRD) regions, O3 concentrations were enhanced by 90.21 and 71.79% from pre-lockdown to lockdown periods in 2020, significantly greater than the equivalent concentrations for the same periods over 2015–2019 (69.99 and 43.62%, p < 0.001). In contrast, a decline was detected (−1.1%) in the Pearl River Delta (PRD) region. To better understand the underlying causes for these inconsistent responses across China, we adopted the least absolute shrinkage and selection operator (Lasso) and ordinary linear squares (OLS) methods in this study. Statistical analysis indicated that a sharp decline in nitrogen dioxide (NO2) was the major driver of enhanced O3 in the BTH region as it is a NOx-saturated region. In the YRD region, season-shift induced changes in the temperature/shortwave radiative flux, while lockdown induced declines in NO2, attributable to the rise in O3. In the PRD region, the slight drop in O3 is attributed to the decreased intensity of radiation. The distinct regimes of the O3 response to the COVID-19 lockdown in China offer important insights into different O3 control strategies across China. [ABSTRACT FROM AUTHOR]

The harm of VOCs emitted from industries to surrounding atmospheric environment and human health was well known and had received continuous attention. In order to improve the quality of urban atmospheric environment and the living environment of urban residents, a large number of original urban industries had been relocated to economically underdeveloped suburbs, which has significantly deteriorated the atmospheric environment in these areas and brought potential health risks to local vulnerable residents, which is actually an unfair manifestation under the background of economic development and ecological civilization construction. There were many residents near industrial parks, but there was a significant lack of VOCs monitoring equipment and data. At present, the time resolution of the most commonly used in situ method was seriously insufficient, and it was unable to quantify the diffusion/transport process of VOCs. It was urgent to have effective detection methods for industrial VOCs plume concentration and diffusion/transport process. In this study, we proposed a hyperspectral imaging technology, which can realize long-term continuous imaging monitoring on plume concentrations of formaldehyde (HCHO), glyoxal (CHOCHO) and benzaldehyde (C 6 H 5 CHO) and their corresponding diffusion processes. The deviation between the imaging and in situ sampling concentrations in the outlet was 4–19 %. The spatial resolution of this technique reached meter level, and the temporal resolution of one pixel was better than 20 s. In this study, we carried out hyperspectral imaging of aldehyde VOCs for a chemical facility, a petrochemical facility and an industrial park containing various types of enterprises in the Yangtze River Delta. The maximum observed concentration of HCHO was 120.44 ± 12.14 ug/m3 with the emission flux of 39.27 ± 3.97 g/h, which was emitted from a petrochemical facility in Shanghai. A diffusion/transport model was established, and we found that the spatial distribution of HCHO, CHOCHO and C 6 H 5 CHO for the chemical facility case in Shanghai were all mainly along the southeast-northwest direction during one year. The health risk assessment emphasized that residents within 10 km north of the outlet of the chemical facility in Shanghai should pay more attention to the health risks caused by industrial HCHO emissions. More systematically and comprehensively hyperspectral imaging of VOCs emissions for different types of enterprises and different processes were expected to performed to greatly promote the establishment of a dynamic emission inventory and an effective health risk evaluation system in the future. [Display omitted] • A new imaging remote sensing technique for VOCs was proposed. • The concentrations and emission fluxes of HCHO, CHOCHO and C 6 H 5 CHO were evaluated. • The deviation between hyperspectral imaging and in situ measurements were 4–19 %. • A diffusion/transport model was developed to analyze health risk caused by VOCs. [ABSTRACT FROM AUTHOR]