Sven Bernitt, V. Mäckel, William F. Schlotter, Peter Beiersdorfer, J. R. Crespo López-Urrutia, Andrey Surzhykov, E. W. Magee, Stefan Schippers, Alexander Graf, M.C. Simon, C. Beilmann, S. M. Kahn, J. Rudolph, Zoltán Harman, Maurice A. Leutenegger, Alfred Müller, Joachim Ullrich, K. Kubicek, Natalie Hell, Frederick S. Porter, Elmar Träbert, Sascha W. Epp, Joel Clementson, Joshua J. Turner, René Steinbrügge, S.N. Eberle, Gregory V. Brown, and Christoph H. Keitel
Fluorescence of iron ions induced by an X-ray laser allows the relative oscillator strength for Fe xvii emission to be determined; it is found to differ by 3.6σ from the best quantum mechanical calculations, suggesting that the poor agreement between prediction and observations of the brightest Fe xvii line is rooted in the quality of the underlying atomic wavefunctions used in the models. The interpretation of some of the spectral data from the Chandra and XMM-Newton orbiting X-ray missions has been complicated by discrepancies between theory and observation involving the emission lines from the highly charged Fe16+ ion, also known as Fe XVII. Specifically, the intensity of the strongest Fe XVII line, one of the brightest X-ray emissions from galaxies and stars, is generally weaker than predicted. Sven Bernitt et al. report the results of laboratory experiments in which a target of iron ions was fluoresced with femtosecond X-ray pulses from a free-electron laser. They find a relative oscillator strength that differs by 3.6σ from the best quantum mechanical calculations, suggesting that the poor agreement is rooted in the calculations of the underlying atomic dynamics and that the current astrophysical models are not at fault. Highly charged iron (Fe16+, here referred to as Fe xvii) produces some of the brightest X-ray emission lines from hot astrophysical objects1, including galaxy clusters and stellar coronae, and it dominates the emission of the Sun at wavelengths near 15 angstroms. The Fe xvii spectrum is, however, poorly fitted by even the best astrophysical models. A particular problem has been that the intensity of the strongest Fe xvii line is generally weaker than predicted2,3. This has affected the interpretation of observations by the Chandra and XMM-Newton orbiting X-ray missions1, fuelling a continuing controversy over whether this discrepancy is caused by incomplete modelling of the plasma environment in these objects or by shortcomings in the treatment of the underlying atomic physics. Here we report the results of an experiment in which a target of iron ions was induced to fluoresce by subjecting it to femtosecond X-ray pulses from a free-electron laser4; our aim was to isolate a key aspect of the quantum mechanical description of the line emission. Surprisingly, we find a relative oscillator strength that is unexpectedly low, differing by 3.6σ from the best quantum mechanical calculations. Our measurements suggest that the poor agreement is rooted in the quality of the underlying atomic wavefunctions rather than in insufficient modelling of collisional processes.