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Your search keyword '"Liang, Xing-Yong"' showing total 1 results
Start Over Author "Liang, Xing-Yong" Topic electrophiles
1 results on '"Liang, Xing-Yong"'

1. DMAP-promoted oxidative functionalization of α-amino ketones via oxygen delivery from water/alcohols.

Author

Wang, Ying-Wei, Liu, Xiao-Nan, Zheng, Jia, Su, Jian, Li, Qi-Jun, Cai, Xian-Rong, Wang, Qiang, and Liang, Xing-Yong

Subjects
NUCLEOPHILIC catalysis, KETONES, ELECTROPHILES, OXYGEN
Abstract

This paper shows a novel oxidative functionalization of α-amino ketones to yield the corresponding α-ketoamides and α-acylimidates. The reaction proceeds via oxygen delivery from water/alcohols in conjunction with an electron acceptor and 4-dimethylaminopyridine (DMAP). Mechanistic study indicates that DMAP exhibits a dual function of nucleophilic catalysis and proton abstraction. [ABSTRACT FROM AUTHOR]

Published
2024
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