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We report high efficiency and low roll-off for blue electrophosphorescent organic light emitting devices based on a mixed host layer architecture. The devices were fabricated using a mixed layer of di-[4-(N,N-ditolyl-amino)-phenyl]cyclohexane, a hole transport material, and 2,8-bis(diphenylphosphoryl)dibenzothiophene, an electron transport material, as the host layer doped with the blue phosphor iridium (III) bis[(4,6-difluorophenyl)-pyridinato-N,C2′]picolinate. Using a mixed layer as the host allowed us to achieve high power efficiency (59 lm/W at 100 cd/m2), low turn-on voltage (2.7 V for >10 cd/m2), and low roll-off in these devices. [ABSTRACT FROM AUTHOR]

We report blue electrophosphorescent organic light emitting devices with an ambipolar host material, 4-(diphenylphosphoryl)-N,N-diphenylaniline (HM-A1), doped with FIrpic (iridium (III)bis[(4,6-difluorophenyl)-pyridinato-N,C2′]picolinate). The ambipolar nature of the host was verified using single carrier devices. The power efficiency of devices with PO15 (2,8-bis(diphenylphosphoryl)dibenzothiophene) electron transport layer (ETL) showed optimized performance when the ETL thickness was 500 Å, giving a peak power efficiency of 46 lm/W (corresponding external quantum efficiency (EQE) of 17.1%). The EQE and power efficiency at the brightness of 800 cd/m2 were measured with no light outcoupling enhancement and found to be 15.4% and 26 lm/W, respectively. [ABSTRACT FROM AUTHOR]

We have demonstrated a substantial enhancement in the efficiency of iridium (III) bis[(4,6-di-fluorophenyl)-pyridinate-N,C2′]picolinate based blue phosphorescent organic light-emitting devices (PHOLEDs). The efficiencies of PHOLEDs with conventional electron transport materials are low due to their low electron mobilities as well low triplet energies. High triplet energy electron transporting material with high electron mobility was used as a hole blocker to achieve efficient exciton confinement and good charge balance in the device thereby achieving a high current efficiency of 49 cd/A and an external quantum efficiency of 23%. [ABSTRACT FROM AUTHOR]

Abstract: We investigate the performance of FIr6-based deep-blue phosphorescent organic light-emitting devices (PHOLEDs) with three different electron transport materials, bathocuproine (BCP), 4,7-diphenyl-1,10-phenanthroline (BPhen), and tris[3-(3-pyridyl)mesityl]borane (3TPYMB), and study the effect of doping alkaline metals (Li and Cs) into these charge transport materials. External quantum efficiency (ηEQE ) of (20±1)% and peak power efficiency (ηP ) of (36±2) lm/W were achieved maintaining Commission Internationale de L’Eclairage (CIE) coordinates of (x =0.16, y =0.28) in p-i-n dual-emissive-layer (D-EML) deep-blue PHOLEDs with 3TPYMB as the electron transport material and 3TPYMB:Cs as the electron injection layer. The high efficiencies are attributed to the high triplet energy of 3TPYMB as well as the increased conductivity of 3TPYMB:Cs. [Copyright &y& Elsevier]