1. Structure-dependent localized surface plasmon resonance characteristics and surface enhanced Raman scattering performances of quasi-periodic nanoarrays: Measurements and analysis.
- Author
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Dong Chen, Jun Zhou, Rippa, Massimo, and Petti, Lucia
- Subjects
SURFACE plasmon resonance ,SERS spectroscopy ,NANOSTRUCTURED materials ,GOLD ,ELECTRON beam lithography ,NEAR-field microscopy ,FINITE element method ,BIOSENSORS - Abstract
A set of periodic and quasi-periodic Au nanoarrays with different morphologies have been fabricated by using electron beam lithography technique, and their optical properties have been examined experimentally and analyzed theoretically by scanning near-field optical microscope and finite element method, respectively. Results present that the localized surface plasmon resonance of the as-prepared Au nanoarrays exhibit the structure-depended characteristics. Comparing with the periodic nanoarrays, the quasi-periodic ones demonstrate stronger electric field enhancement, especially for Thue-Morse nanoarray. Meanwhile, the surface enhanced Raman scattering (SERS) spectra of 4-mercaptobenzoic acid molecular labeled nanoarrays show that the quasi-periodic nanoarrays exhibit distinct SERS enhancement, for example, a higher enhancement factor of ~10
7 is obtained for the Thue-Morse nanoarray consisted of square pillars of 100nm size. Therefore, it is significant to optimally design and fabricate the chip-scale quasi-periodic nanoarrays with high localized electric field enhancement for SERS applications in biosensing field. [ABSTRACT FROM AUTHOR]- Published
- 2015
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