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Due to its high theoretical capacity, silicon is a promising active material candidate for the negative electrode of lithium ion batteries. One way to reduce the severe degradation of silicon during charge/discharge cycling, is to use blends of different active materials and a well-balanced ratio of active and inactive materials. To ensure high-energy densities while still maintaining good electronic conductivity and ionic mobility, the necessity of nano-scale conductive carbons within a graphite/silicon composite was evaluated in this study. In particular, the correlation of silicon particle size and the presence of conductive additive was studied in electrodes, predominantly consisting of graphite (15 wt% silicon). Carbon black as conductive additive has a high contact surface area, which can enhance the electronic conductivity within the electrode and thus the rate capability, however, it can also propagate parasitic side reactions. It was determined that composite electrodes containing micron-sized silicon particles depend on the addition of conductive additives with regard to electrochemical performance. Due to high contact area and small transport distances, electrodes based on nano-sized silicon showed comparable capacity retention and a higher specific discharge capacity. Omitting conductive particles from these composite electrodes allowed lower binder amounts, while maintaining a good mechanical electrode integrity. [Display omitted] • Optimization of C/Si-based composite electrode formulation. • Impact of different Si particle sizes varying from nano-to micro-scale. • Evaluation of the necessity of conductive additives in C/Si-based electrodes. • Reduction of inactive material content to maximize energy density. [ABSTRACT FROM AUTHOR]