1. Fast-Switching Mixed A-Cation Organic-Inorganic Hybrid Perovskite TFTs.
- Author
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Hoang, Nhu Thi To, Haque, Farjana, Ji, Jeoungmin, and Mativenga, Mallory
- Subjects
INDIUM gallium zinc oxide ,PEROVSKITE ,THIN film transistors ,LEAD iodide ,CRYSTAL grain boundaries ,SURFACE roughness - Abstract
We use a popular organic-inorganic hybrid perovskite, methyl-ammonium lead iodide (MAPbI3), for thin-film transistors (TFTs). Given the sensitivity of organic-based perovskites to wet processes, we employed an inverted coplanar TFT structure with a UV-treated, high- ${k}$ $\text{AlO}_{\textit {x}}$ gate insulator and deposited the perovskite from solution into a photoresist bank as the final process step. We also explored the impact of substitutional doping of the MAPbI3 with a smaller inorganic cation, cesium (Cs+), or the larger organic cation, formamidinium (FA), to form the mixed-A cation perovskites, $\text{FA}_{\textit {x}}$ MA1-xPbI3 and CsxMA1-xPbI3, respectively. We demonstrated a significant improvement in the TFT switching speed and ON/ OFF ratio with CsxMA1-xPbI3 but failed to achieve any transistor operation with FAxMA1-xPbI3. Incorporation of Cs into MAPbI3 reduced bulk and interfacial trap states and improved film density and morphology, whereas incorporation of FA resulted in increased surface roughness and thicker grain boundaries. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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