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Reducing the Pt-based electrocatalysts to sub-nanometer sizes is an effective way to achieve high utilization of noble metals. Herein, we report a successive route to synthesize carbon-supported bimetallic ruthenium-platinum electrocatalysts (Ru-Pt/C) with uniform dispersion and fine sizes. In this strategy, carbon-supported Ru nanoparticles (Ru/C) with a mean size of 1.4 nm are firstly prepared in a mixture of ethylene glycol and water, and the Pt precursors are then reduced in the presence of pre-formed Ru/C. The average diameter of the bimetallic Ru-Pt particles on carbon supports is 1.9 nm, which corresponds to one to two Pt layers deposited on the surface of Ru seeds. The as-prepared bimetallic Ru-Pt/C electrocatalysts are analyzed by the CO stripping voltammetry, a diagnostic electrochemical tool. Compared with the commercial PtRu/C catalyst and the control PtRu/C prepared by a conventional co-reduction method, the bimetallic Ru-Pt/C has higher electrochemical surface area (92.5 m g) and mass activity (483 A g) for methanol oxidation reaction. The strategy reported in this study is effective to produce fine bimetallic Ru-Pt particles (less than 2.0 nm) with uniform dispersion and high activity. [ABSTRACT FROM AUTHOR]

The development of a catalyst that is both effective and robust is desirable, but remains a challenge for those aiming to commercialize polymer electrolyte membrane fuel cells. Thus, a facile method is proposed to develop hierarchical and three-dimensional titanium nitride (TiN) architectures, with the robust non‑carbon material being implemented as the Pt support. The resulting catalyst (Pt/TiN) demonstrates high activity and stability, and the experimental data confirm the critical significance of the novel TiN support. [ABSTRACT FROM AUTHOR]