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Summary: Solar photovoltaic‐thermal (PV/T) collectors, are hybrid collectors used to convert solar radiation into usable thermal and electrical energy. Recently, the field of research on PV/T is has focused on improving the efficiency of the PV/T collector by replacing the conventional heat transfer fluids (HTFs) with nanofluids. This article investigates the effect of hybrid nanofluids mixture ratio on the useful energy and overall efficiency of a PV/T collector operating with Al2O3‐ZnO water nanofluid as the HTF. Experiments to measure the thermophysical properties of the hybrid nanofluids were conducted for various temperatures, volume concentrations, and mixture ratios, furthermore, accurate correlation models were proposed. Metrological data and energy output readings collected from the PV solar farm at Cyprus International University were used to validate our model. The study observed that at the optimum mixture ratio (0.47 of Al2O3 in the hybrid), the electrical, thermal, and exergy efficiencies of the PV/T collector are 13.8%, 55.9%, and 15.13% respectively. Also, the cell temperature drops by 21% when the mass flow rate is 0.1 kg/s as compared to when it is 0.01 kg/s. Finally, the study concludes that by using the Al2O3‐ZnO hybrid nanofluid an overall peak thermal efficiency of 91% can be attained, and this represents a 34% enhancement in the collector's performance when compared to water. [ABSTRACT FROM AUTHOR]

The amelioration of photovoltaic (PV) and photovoltaic/thermal (PV/T) systems have garnered increased research interest lately, more so due to the discovery of the thermal property augmentation of nanofluids. The overarching goal of this study is to conduct a comparative analysis of mono, hybrid, and ternary hybrid nanofluids utilized as fluids for heat transfer applications and particularly as cooling mediums in PV/T applications. Al2O3, ZnO, Al2O3-ZnO, and Al2O3-ZnO-Fe3O4 nanofluids are synthesized at 1% volume concentration using the two-step method. The zeta potential tests carried out showed that the fluids have high stability. The numerical model developed in this study was validated using real data culled from Cyprus International University. The findings in this study showed that the Al2O3-ZnO-Fe3O4 ternary hybrid nanofluid and ZnO mono nanofluid were more efficient heat transfer fluids for the PV/T system. The optimum relative electrical PV/T efficiency against that of the PV is 8.13% while the electrical and thermal enhancement recorded in this study was 1.79% and 19.06%, respectively, measured for the ternary hybrid nanofluid based PV/T system. This present study shows that despite the limitation of pumping power and pressure drop associated with nanofluid in thermal systems, the close performance evaluation criterion values as compared with water is positive for practical utilization of nanofluid in PV/T systems. [ABSTRACT FROM AUTHOR]