Search

LiFeP2O7and Li0.9Fe0.9Ti0.1P2O7were synthesised by solid-state reaction and ceramics were sintered. The structure of compounds was studied in the temperature range 300–700 K by X-ray diffraction. Ceramics’ surfaces were investigated by scanning electron microscope. Binding energies of Fe 2p, P 2p and O 1s core levels at ceramics’ surfaces have been determined by X-ray photoelectron spectroscopy and different valence states of Fe and P were detected. Elemental compositions of the compounds were studied by energy dispersive X-ray spectrometer. Impedance spectroscopy was performed in the frequency range 10 Hz–3 GHz and in the temperature interval 400–700 K. The changes of the activation energy of ionic conductivity at 528 and 550 K for LiFeP2O7and Li0.9Fe0.9Ti0.1P2O7, respectively, were found. The phenomena can be related to disordering in the unit cells of the compounds. [ABSTRACT FROM AUTHOR]

Copyright of Lithuanian Journal of Physics is the property of Lithuanian Academy of Sciences and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Abstract: Li1.3AlyYx−yTi1.7(PO4)3 (x=0.3; y=0.1, 0.2) solid electrolyte compounds were synthesized by solid state reaction and studied by X-ray diffraction. At room temperature the compounds belong to a rhombohedral symmetry (space group Rc) with six formula units in the unit cell. Ti 2p, O 1s, P 2p, Li 1s, Y 3d, and Al 2p core level XP spectra at Li1.3AlyYx−yTi1.7(PO4)3 (x=0.3; y=0.1, 0.2) ceramic surfaces have been determined by XPS. The measurements of the electrical properties of the ceramic samples in the frequency range 10Hz–1MHz were carried out by a two probe method and a four probe method. The measurements in the microwave range (3·105–3·109 )Hz were performed in a coaxial line, the part of the inner conductor which was replaced by the sample. The investigation of the electrical properties of the ceramic samples was carried out in air in the temperature range (300 to 700)K. The increase of the stoichiometric factor y of the compounds leads to the increase in the total and bulk conductivities of ceramics and decreases their activation energies. [Copyright &y& Elsevier]

Abstract: The powder of Li1+xAlyScx−yTi2−x(PO4)3 with x=0.3 and y=0.1, 0.15, 0.2 has been prepared by solid state reaction and the ceramics have been sintered. The results of X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS) and impedance spectroscopy up to 109 Hz are presented. At room temperature the compounds belong to the rhombohedral symmetry (space group R3̅c). Ti 2p, P 2p, O 1s, Sc 2p, Al 2p, and Li 1s core level XP spectra''s were fitted. The values of binding energies of core level XP spectra''s, splitting energies of Ti 2p3/2–Ti 2p1/2, Sc 2p3/2–Sc 2p1/2, P2p3/2–P2p1/2 spin-orbit doublets, and amount of the elements with different binding energies were found to be dependent on stoichiometric factor y. The elemental compositions are defined by EDX. Impedance spectroscopy study in the frequency range 10Hz–3GHz have shown three relaxation dispersion regions of electrical properties and the processes are thermally activated. The high frequency dispersion region may be attributed to the relaxation processes in bulk, while lower dispersion regions are related to the processes in grain boundaries and blocking Pt electrodes. [Copyright &y& Elsevier]

Abstract: The powder of Li1+ x + y Sc x Y y Ti2− x − y (PO4)3 (x =0.15–0.3, y =0.01–0.15) has been synthesized by solid phase reaction. The structure of the compounds was determined by X-ray diffraction patterns from the powder. The compounds belong to the rhombohedral symmetry (space group R3¯c) with Z =6 formula units in the lattice. Ceramic samples were sintered in air at temperature T s =1523 K varying sintering time (t s) from 1 to 5 h. The element compositions of ceramics were defined by XPS. The complex impedance (Z˜), electric conductivity (σ˜), dielectric permittivity (ɛ˜) of the ceramics in frequency range (106−1.2·109) Hz and temperature range (300−600) K were carried out. Two relaxation dispersions of the electric parameters were found for all compounds. The dispersions are caused by the ion transport in grains and grain boundaries of the ceramic samples. The values of the bulk (σ b), grain boundaries (σ gb) conductivities, their activation energies, and dielectric permittivity are dependent on stoichiometric parameters x, y and sintering conditions of the ceramics. [Copyright &y& Elsevier]