Search

Sensors based on conductive hydrogels have received extensive attention in various fields, such as artificial intelligence, electronic skin, and health monitoring. However, the poor resilience and fatigue resistance, icing, and water loss of traditional hydrogels greatly limit their application. Herein, an ionic conductive organohydrogel (PAC-Zn) was prepared for the first time by copolymerization of cardanol and acrylic acid in water/1,3-butanediol as a binary solvent system. A very small amount of cardanol (1% cardanol of total monomers) could not only significantly improve the tensile strength (∼4 times) and toughness (∼3 times) of PAA but also improve its extensibility. Due to the presence of 1,3-butanediol, PAC-Zn showed outstanding tolerance for freezing (-45 °C) and drying (over 85% moisture retention after 15 days of storage in a 37 °C oven). Compared with ethylene glycol and glycerol as antifreeze agents used in organohydrogels, the addition of 1,3-butanediol endowed the organohydrogel with not only similar frost resistance but also better mechanical performance. Besides, PAC-Zn exhibited fast resilience (almost no hysteresis loop) and excellent antifatigue ability. More importantly, a PAC-Zn organohydrogel-based sensor could detect human motion in real time (wrist, elbow, finger, and knee joints), revealing its fast response, good sensitivity, and stable electromechanical repeatability. In conclusion, the multifunctional PAC-Zn organohydrogel is expected to become a potential and promising candidate in the field of strain sensors under a broad range of environmental temperatures.

Effective and timely joint monitoring has been a significantly vital research direction in human healthcare. As an emerging technology, flexible electronics provides more possibilities and applicabilities for practical sensing and signal transmission. Here, we provide novel elastic MXene microfibers of controllable morphologies at a microscale through microfluidic technology for actual joint motion monitoring. Double-network hydrogels including covalently cross-linking polyacrylamide and ionically cross-linking alginate were chosen for superelasticity. For the improvement of the electrical conductivity of superelastic hydrogel microfibers, MXene was selected to mix with them. By introducing the cross-linker to the outer channel, microfibers with controllable diameters along with high electrical conductivities and tensile properties could be fabricated successfully. The practical value of the synthesized microfibers in joint movement sensing has been demonstrated by acting as the element of new motion sensors. Based on these features, it is believed that these elastic MXene hydrogel microfibers have high potential for rapid sensing and diagnosis of joint diseases.

In this study, a self-sorting sensor was developed with the ability to distinguish between different pressure regimes and translate the pressure to electrical signals. Specifically, the self-sorting sensor can distinguish between soft and hard pressure like the human skin, without any software assistance and complicated circuits. To achieve the self-sorting property, Janus-like jagged structures were prepared via an all-solution process of spontaneous chemical patterning; they comprised electrically semi-insulating vertices and highly conductive valleys. This unique structure facilitates the detection and determination of the intensities and types of pressure by providing a significant gap between the current levels of two types of states, similar to the function of fibers in the human tactile system. The fabricated sensors also exhibit high sensitivity and durability as well as low power consumption, as demonstrated by the electronic skin and ternary Morse signal applications. Compared with conventional wearable pressure sensors, this sensor can detect signals without additional programming; thus, it is highly suitable for delay-sensitive, energy-efficient sensor applications such as driverless vehicles, autonomous artificial intelligence technology, and prosthetic devices.

Owing to the characteristics of mimicking human skin's function and transmitting sensory signals, electronic skin (e-skin), as an emerging and exciting research field, has inspired tremendous efforts in the biomedical field. However, it is frustrating that most e-skins are prone to bacterial infections, resulting a serious threat to human health. Therefore, the construction of e-skin with an integrated perceptual signal and antibacterial properties is highly desirable. Herein, the dynamic supramolecular hydrogel was prepared through a freezing/thawing method by cross-linking the conductive graphene (G), biocompatible polyvinyl alcohol (PVA), self-adhesive polydopamine (PDA), and in situ formation antibacterial silver nanoparticles (AgNPs). Having fabricated the hierarchical network structure, the PVA-G-PDA-AgNPs composite hydrogel with a tensile strength of 1.174 MPa and an elongation of 331% paves way for flexible e-skins. Notably, the PVA-G-PDA-AgNPs hydrogel exhibits outstanding antibacterial activity to typical pathogenic microbes (e.g., Gram-negative Escherichia coli and Gram-positive Staphylococcus aureus), which effectively prevents bacterial infections that harm human health. With self-adhesiveness to various surfaces and excellent conductivity, the PVA-G-PDA-AgNPs composite hydrogel was used as strain sensors to detect a variety of macroscale and microscale human motions successfully. Meanwhile, the excellent rehealing property allows the hydrogel to recycle as a new sensor to detect large-scale human activities or tiny movement. Based on these remarkable features, the antibacterial, self-adhesive, recyclable, and tough conductive composite hydrogels possess the great promising application in biomedical materials.

Flexible pressure sensing is required for the excellent sensing performance and dexterous manipulation of the measured objects in their potential applications. Particularly, the ability to measure and discriminate the direction of force, contact surface, and contact location in real time is crucial for robotics with tactile feedback. Herein, a three-dimensional elastic porous carbon nanotube (CNT) sponge is synthesized by chemical vapor deposition, which is successfully applied in the piezoresistive sensor. In situ scanning electron microscopy study intuitively illustrates the characteristics that the microfibers of the CNT sponge distort and contact with each other under an external force. As a result, new conductive paths are created at the contact points between the CNT microfibers, which provides a basic sensing principle for a piezoresistive sensor. The CNT sponge-based sensor has an ultrahigh sensitivity in a wide pressure range (0-4 kPa for 4015.8 kPa-1), a rapid response time of 120 ms, and excellent durability over 5000 cycles. Moreover, a finlike flexible double-sided electronic skin (e-skin) is fabricated by a simple method to achieve force direction detection, which has potential applications in intelligent wearable devices and human-machine interaction.

Highly sensitive wearable textile pressure sensors represent the key components of smart textiles and personalized electronics, with potential applications in biomedical monitoring, electronic skin, and human-machine interfacing. Here, we present a simple and low-cost strategy to fabricate highly sensitive wearable textile pressure sensors for non-invasive human motion and physiological signal monitoring and the detection of dynamic tactile stimuli. The wearable textile sensor was woven using a one-dimensional (1D) weavable core-sheath nanofiber yarn, which was obtained by coating a Ni-coated cotton yarn electrode with carbon nanotube (CNT)-embedded polyurethane (PU) nanofibers using a simple electrospinning technique. In our design, the three-dimensional elastic porous nanofiber structure of the force-sensing layer and hierarchical fiber-bundled structure of the conductive Ni-coated electrode provide the sensor with a relatively large surface area, and a sufficient surface roughness and elasticity. This leads to rapid and sharp increases in the contact area under stimuli with low external pressure. As a result, the textile pressure sensor exhibits the advantages of a high sensitivity (16.52 N−1), wide sensing range (0.003–5 N), and short response time (~0.03 s). Owing to these merits, our textile-based sensor can be directly attached to the skin as usual and conformally fit the shape deformations of the body’s complex flexible curved surfaces. This contributes to the reliable real-time monitoring of human movements, ranging from subtle physiological signals to vigorous movements. Moreover, a large-area textile sensing matrix is successfully fabricated for tactile mapping of spatial pressure by being worn on the surface of wrist, highlighting the tremendous potential for applications in smart textiles and wearable electronics.

Conductive hydrogels have generated great interest in biomedical and electrical fields. However, conventional conductive hydrogels usually lack self-healing properties, which might be unfavorable for their application. Conductive self-healing hydrogels with excellent performance for applications in the biomedical and electrical fields are growing in number. In this review paper, the progress related to conductive self-healing hydrogels is summarized. The self-healing mechanism is classified to demonstrate the design and synthesis of conductive self-healing hydrogels and their applications in tissue engineering, wound healing, electronic skin, sensors and self-repaired circuits are presented and discussed. The future development of conductive self-healing hydrogels and problems that need to be solved are also described.

Conductive hydrogel-based epidermal strain sensors can generate repeatable electrical changes upon mechanical deformations for indication of the skin's physiological condition. However, this remains challenging for many conductive hydrogel sensors due to biomechanical mismatch with skin tissues and an unstable resistance variation response, resulting in non-conformable deformations with the epidermis and dermis, and consequently generating inaccurate monitoring of human movements. Herein, a conductive hydrogel that highly matches the skin is fabricated from dynamically hydrogen-bonded nanocrystallites of polydopamine-modified reduced graphene oxide (PDA-rGO) nanosheets composited with polyvinyl alcohol, namely the PDA-rGO/PVA hydrogel. PDA-rGO provides a large number of dynamic hydrogen-bonding interactions in the hydrogel, resulting in a skin-matching modulus (78 kPa) and stretchability. Moreover, the resultant hydrogel possesses excellent cytocompatibility and conductivity (0.87 S m-1), high sensitivity (gauge factor of compression: 20) at low strain and outstanding linearity at high strain as well as a stable resistance variation response. These desirable properties enable the application of the PDA-rGO/PVA hydrogel as a skin-friendly wearable sensor for real-time and accurate detection of both large-scale joint movements and tiny physiological signals, including the bending and relaxing of fingers, the wrist, elbow and knee joints, and wrist pulse and swallowing. Moreover, this hydrogel is integrated into a 2D sensor array that monitors strains or pressures in two dimensions, which is promising for electronic skin, biosensors, human-machine interfaces, and wearable electronic devices.

Stretchable conductors have been achieved by stacking conductive nanomaterials onto the surfaces of elastomeric substrates. However, many of them show a dramatic decrease in conductivity under strain without an efficient way for the conductive layer to release strain. Here, we report a transparent, stretchable, and self-healing conductor with excellent mechanoelectrical stability by introducing dynamic bonding between conductive nanomaterials and an elastomeric substrate. We prepare the conductor by semiembedding Ag nanowires (AgNWs) into a self-healing polydimethylsiloxane (PDMS)-based elastomer, which is modified with bipyridine (Bpy) ligand and further cross-linked by adding Zn

Conductive self-healing hydrogels (CSHs) that match the mechanical properties of biological tissues are highly desired for emerging wearable electronics. However, it is still a fundamental challenge to balance the trade-offs among the mechanical, electronic, and self-healing properties in CSHs. In this study, we presented supramolecular double-network (DN) CSHs by pre-infiltrating conductive polyaniline (PANI) precursor into the self-healable hydrophobic association poly(acrylic acid) (HAPAA) hydrogel matrix. The dynamic interfacial interactions between the HAPAA and PANI networks efficiently enhanced the mechanical performances of the HAPAA/PANI (PAAN) hydrogel and could compensate for the negative effect of the enhanced mechanical strength on self-healing. In addition, the interconnected PANI network endowed the PAAN hydrogel with high conductivity and excellent sensory performances. As such, the mechanical and electronic properties of the PAAN hydrogel were simultaneously enhanced significantly without compromising the self-healing performance of the HAPAA matrix, achieving balanced mechanical, electronic, and self-healing properties in the PAAN hydrogel. Lastly, proof-of-concept applications like human physiological monitoring electronics, flexible touch screens, and artificial electronic skin are successfully demonstrated using the PAAN hydrogel with the capability of restoring their electronic performances after the healing process. It is anticipated that such hydrogel network design can be extended into next-generation hydrogel electronics for human–machine-interfaces and soft robotics.

With good flexibility and biocompatibility, hydrogel-based sensors have been widely used in human motion detection, artificial intelligence, human-machine interface, and other fields. Previous research on hydrogel-based sensors has focused on improving the mechanical properties and signal transmission sensitivity. With the development of human smart devices, there is an increasing demand for hydrogel sensor comfort and more application functions, such as ultrathin structures and recognition functions for contact surfaces, which are realized with higher requirements for the thickness, flexibility, friction resistance, and biocompatibility of hydrogels. Inspired by the ultrathin and flexible characteristics of human organ biofilms, we constructed conductive hydrogel films by using the flim-casting and glycerol-H2O secondary hydration methods. This ultrathin structure enables the hydrogel films to have a high elongation at break of 523.3%, a stress of 3.5 MPa, and a good friction resistance. Combined with the excellent sensing properties (gauge factor = 2.1 and a response time of 200 ms), the hydrogel film-based sensor can not only record human motion signals but also recognize the surface texture and roughness of objects, such as glass, brushes, wood, and sandpaper with mesh sizes of 80, 50, and 24, accurately. In addition, this hydrogel film has a series of excellent properties such as UV shielding, antiswelling ability, and good biocompatibility. This research provides a novel way for the development of emerging soft-material smart devices, such as hydrogel-based electronic skin and soft robots.

Soft hydrogel materials can be applied for use in biosensors, wearable electronics, artificial skin, soft robots, and so on. Practical applications require the materials to have various properties such as high conductivity, toughness, self-healing, stretchability, and so on. However, achieving all these features in a single material remains challenging at present. Herein, the fabrication of novel composite carboxymethylcellulose/poly(acrylic acid)/polypyrrole/Al(III) (CMC/PAA/PPy/Al(III)) multifunctional hydrogels using a simple method is described. The mechanical and electrical self-healing properties are attained by multiple dynamic coordinations between Al3+ ions and carboxyl groups from CMC and PAA together with the hydrogen bonding between PPy and the –OH of CMC and/or the −COOH of PAA. The electrical conductivity is achieved by the conductive polymer PPy, free ions, and the synergistic effect between the PPy particles and the free ions. Moreover, desirable mechanical properties, such as stretchability (1344%), toughness, and mouldability are realized by establishing a balance between the chemical and physical crosslinking networks, and the nanostructure of PPy. Thus, the resultant hydrogels have potential applications in electronic skin, biomedical implants, and wearable electronic devices in the future.

Skin-like electronics that can provide comprehensively tactile sensing is required for applications such as soft robotics, health monitoring, medical treatment, and human-machine interfaces. In particular, the capacity to monitor the contact parameters such as the magnitude, direction, and contact location of external forces is crucial for skin-like tactile sensing devices. Herein, a flexible electronic skin which can measure and discriminate the contact parameters in real time is designed. It is fabricated by integrating the three-dimensional (3D) hollow MXene spheres/Ag NW hybrid nanocomposite-based embedded stretchable electrodes and T-ZnOw/PDMS film-based capacitive pressure sensors. To the best of our knowledge, it is the first stretchable electrode to utilize the 3D hollow MXene spheres with the essential characteristic, which can effectively avoid the drawbacks of stress concentration and shedding of the conductive layer. The strain-resistance module and the pressure-capacitance module show the excellent sensing performance in stability and response time, respectively. Moreover, a 6 × 6 sensor array is used as a demonstration to prove that it can realize the multiplex detection of random external force stimuli without mutual interference, illustrating its potential applications in biomimetic soft wearable devices, object recognition, and robotic manipulation.

A biocompatible, flexible, yet robust conductive composite hydrogel (CCH) for wearable pressure/strain sensors has been achieved by an all-solution-based approach. The CCH is rationally constructed by in situ polymerization of aniline (An) monomers in the polyvinyl alcohol (PVA) matrix, followed by the cross-linking of PVA with glutaraldehyde (GA) as the cross-linker. The unique multiple synergetic networks in the CCH including strong chemical covalent bonds and abundance of weak physical cross-links, i.e., hydrogen bondings and electrostatic interactions, impart excellent mechanical strength (a fracture tensile strength of 1200 kPa), superior compressibility (e = 80%@400 kPa), outstanding stretchability (a fracture strain of 670%), high sensitivity (0.62 kPa-1 at a pressure range of 0-1.0 kPa for pressure sensing and a gauge factor of 3.4 at a strain range of 0-300% for strain sensing, respectively), and prominent fatigue resistance (1500 cycling). As the flexible wearable sensor, the CCH is able to monitor different types of human motion and diagnostically distinguish speaking. As a proof of concept, a sensing device has been designed for the real-time detection of 2D distribution of weight or pressure, suggesting its promising potentials for electronic skin, human-machine interaction, and soft robot applications.

Flexible bioelectronics have promising applications in electronic skin, wearable devices, biomedical electronics, etc. Hydrogels have unique advantages for bioelectronics due to their tissue-like mechanical properties and excellent biocompatibility. Particularly, conductive and tissue adhesive hydrogels can self-adhere to bio-tissues and have great potential in implantable wearable bioelectronics. This review focuses on the recent progress in tissue adhesive hydrogel bioelectronics, including the mechanism and preparation of tissue adhesive hydrogels, the fabrication strategies of conductive hydrogels, and tissue adhesive hydrogel bioelectronics and applications. Some perspectives on tissue adhesive hydrogel bioelectronics are provided at the end of the review.

The conventional skin sensor detection of human physiological signals can be an effective method for disease diagnosis and health monitoring, but the poor biocompatibility, low sensitivity and complex design largely limit their applications. Developing natural nanofiller-reinforced composites as strain biosensors is an appealing solution to reduce environmental impacts and overcome technical bottleneck. Herein, a versatile nature skin-inspired composite film as flexible strain biosensor was developed based on cellulose nanocrystals-polyaniline (CNC-PANI) composites by utilizing their percolated conductive network in polyvinyl alcohol (PVA) matrix. The composite electronic skin showed robust mechanical strength (50.62 MPa) and high sensitivity (Gauge Factor = 11.467) with easy water-induced self-healing abilities. Moreover, we investigated the functioning mechanism of percolated network and the sensory behavior determined by CNC nanocomposite alignment. The percolation threshold of CNC-polyaniline (PANI) was determined at 4.278% and 5% CNC-PANI composite film shows the best overall sensing property. It was also discovered that the sensitivity of this type of conductive-filler electronic skin can be divided into two separate regions at different strain range due to its percolated network. With films prepared by dry casting and dip coating, the alignment of CNC-PANI also contributes to this unique change in electrical property. Generally, our results demonstrated the mechanism and tunability of conductive nanofiller-based composite strain biosensors as a potential alternative to commercial synthetic sensors.

In recent years, hydrogels with self-healing capability and conductivity have become ideal materials for the design of electrodes, soft robotics, electronic skin, and flexible wearable devices. However, it is still a critical challenge to achieve the synergistic characteristics of high conductivity, excellent self-healing efficiency without any stimulations, and decent mechanical properties. Herein, we developed a ferric-ion (Fe3+) crosslinked acrylic acid and chitosan polymer hydrogel using embedded polypyrrole particles with features of high conductivity (2.61S·m-1) and good mechanical performances (a tensile strength of 628%, a stress of 0.33 MPa, an elastic modulus of 0.146 MPa, and a toughness of 1.14 MJ·m-3). In addition, the self-healing efficiency achieved 93% in tensile strength after healing in the air for 9 h without any external stimuli. Therefore, with these outstanding mechanical, self-healing, and conductive abilities all in one, it is possible to fabricate a new kind of soft material with wide applications.

Ionic conductive hydrogel with multifunctional properties have shown promising application potential in various fields, including electronic skin, wearable devices and sensors. Herein, a highly stretchable (up to 2800% strain), tough, adhesive ionic conductive hydrogel are prepared using cationic nanocellulose (CCNC) to disperse/stabilize graphitic carbon nitride (g-C3N4), forming CCNC-g-C3N4 complexes and in situ radical polymerization process. The ionic interactions between CNCC and g-C3N4 acted as sacrificial bonds enabled highly stretchability of the hydrogel. The hydrogel showed high sensitivity (gauge factor≈5.6, 0–1.6% strain), enabling the detection of human body motion, speech and exhalation. Furthermore, the hydrogel based self-powered device can charge 2.2 μF capacitor up to 15 V from human motion. This multifunctional hydrogel presents potential applications in self-powered wearable electronics.

Electronic materials and devices that can mimic biological systems featured with elasticity, toughness, self-healing, degradability, and environmental friendliness drive the technological developments in fields spanning from bioelectronics, biomedical diagnosis and therapy, electronic skin, and soft robotics to Internet-of-Things with "green" electronics. Among them, ionic devices based on gel electrolytes have emerged as attractive candidates for biomimetic systems. Herein, we presented a straightforward approach to demonstrate soft ionic microdevices based on a versatile organohydrogel platform acting as both a free-standing, stretchable, adhesive, healable, and entirely degradable support and a highly conductive, dehydration- and freezing-tolerant electrolyte. This is achieved by forming a gelatin/ferric-ion-cross-linked polyacrylic acid (GEL/PAA) dual dynamic supramolecular network followed by soaking into a NaCl glycerol/water solution to further toughen the gelatin network via solvent displacement, thus obtaining a high toughness of 1.34 MJ·cm-3 and a high ionic conductivity (>7 mS·cm-1). Highly stretchable and multifunctional ionic microdevices are then fabricated based on the organohydrogel electrolytes by simple transfer printing of carbon-based microelectrodes onto the prestretched gel surface. Proof-of-concept microdevices including resistive strain sensors and microsupercapacitors are demonstrated, which displayed outstanding stretchability to 300% strain, resistance to dehydration for >6 months, autonomous self-healing, and rapid room-temperature degradation within hours. The present material design and fabrication approach for the organohydrogel-based ionic microdevices will provide promising scope for life-like and sustainable electronic systems.

Pressure/proximity sensing as the essential function of electronic skin (e-skin) has become an emerging technological goal for new-generation electronic devices in a wide variety of application fields, for example, smart electronics, human-machine interaction, and prosthetics. However, the current research lacks pressure/proximity detection of the stretched e-skin, which ignores the key elastic characteristic of skin and hinders the development of e-skin. Here, the pressure/proximity detection of the transparent e-skin in the stretching state is demonstrated based on poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS)/single-walled carbon nanotube (SWCNT). The high transparency of the e-skin realizes the visual imperception for wearable electronic systems. The perfect combination of stretchable SWCNT and highly conductive PEDOT:PSS endows the sensors with high stretchability and high discrimination capability toward strain, providing an effective way to overcome the interference of strain to realize accurate pressure/proximity detection of stretched e-skin at different strains.

Flexible piezoresistive pressure sensors obtain global research interest owing to their potential applications in healthcare, human–robot interaction, and artificial nerves. However, an additional power supply is usually required to drive the sensors, which results in increased complexity of the pressure sensing system. Despite the great efforts in pursuing self-powered pressure sensors, most of the self-powered devices can merely detect the dynamic pressure and the reliable static pressure detection is still challenging. With the help of redox-induced electricity, a bioinspired graphite/polydimethylsiloxane piezoresistive composite film acting both as the cathode and pressure sensing layer, a neoteric electronic skin sensor is presented here to detect not only the dynamic forces but also the static forces without an external power supply. Additionally, the sensor exhibits a fascinating pressure sensitivity of ∼103 kPa–1 over a broad sensing range from 0.02 to 30 kPa. Benefiting from the advanced performance of the device, various potential applications including arterial pulse monitoring, human motion detecting, and Morse code generation are successfully demonstrated. This new strategy could pave a way for the development of next-generation self-powered wearable devices.

Bionic electronic skin (E-skin) that could convert external physical or mechanical stimuli into output signals has a wide range of applications including wearable devices, artificial prostheses, software robots, etc. Here, we present a chameleon-inspired multifunctional E-skin based on hydroxypropyl cellulose (HPC), Poly(Acrylamide-co-Acrylic acid) (PACA), and carbon nanotubes (CNTs) composited liquid-crystal hydrogel. We found that the HPC could still form cholesteric liquid-crystal photonic structures with the CNTs additive for enhancing their color saturation and PACA polymerization for locating their assembled periodic structures. As the composite hydrogel containing HPC elements and the PACA scaffold responds to different stimuli, such as temperature variations, mechanical pressure, and tension, it could correspondingly change its volume or internal nanostructure and report these as visible color switches. In addition, due to the additive of CNTs, the composite hydrogel could also output these stimuli as electrical resistance signals. Thus, the hydrogel E-skins had the ability of quantitatively feeding back external stimuli through electrical resistance as well as visually mapping the stimulating sites by color variation. This dual-signal sensing provides the ability of visible-user interaction as well as antiinterference, endowing the multifunctional E-skin with great application prospects.

Self-powered electronic skin (E-skin) can be endowed with high robustness by employing self-healing materials. However, most self-powered E-skin employs two heterogeneous materials with high modulus mismatch at the interface and poor fully self-healing ability, which reduces the robustness of the whole device. Here, a conductive polyurethane elastomer (PUE) with excellent mechanical toughness and self-healing ability is prepared. Based on the self-healing insulated/conductive PUE homogeneous structure and triboelectric-electrostatic induction effect, a highly robust and self-powered E-skin (HRSE-skin) is developed. The HRSE-skin possesses stable mechanosensation capability during the 50% stretching deformation due to a low modulus mismatch in the homogeneous structure. In addition, the stretchability and mechanosensation capability of the HRSE-skin can be restored after the fracture owing to the fully self-healing ability of the homogeneous structure. Therefore, the HRSE-skin has high robustness of the whole device including stable service behaviors and excellent restorability. The developed HRSE-skin demonstrates high robustness in the detection of the force and bending angle of the prosthetic joint. This work solves the low robustness of self-powered E-skin by the preparation of conductive self-healing PUE and the construction of the homogeneous structure, which is important for the practical applications of self-powered E-skin in prosthetic limbs and advanced robotics.

The ability to image pressure distribution over complex three-dimensional surfaces would significantly augment the potential applications of electronic skin. However, existing methods show poor spatial and temporal fidelity due to their limited pixel density, low sensitivity, or low conformability. Here, we report an ultraflexible and transparent electroluminescent skin that autonomously displays super-resolution images of pressure distribution in real time. The device comprises a transparent pressure-sensing film with a solution-processable cellulose/nanowire nanohybrid network featuring ultrahigh sensor sensitivity (>5000 kPa−1) and a fast response time (1000 dpi) pressure imaging without the need for pixel structures. Our approach provides a new framework for visualizing accurate stimulus distribution with potential applications in skin prosthesis, robotics, and advanced human-machine interfaces., Electronic skin that spatially maps pressure distribution through imaging shows limited performance despite improvements to data acquisition. Here, the authors report ultraflexible, transparent electroluminescent skin capable of high-resolution imaging of pressure distribution over 3D surfaces.

Electronic skins are developed for applications such as biomedical sensors, robotic prosthetics, and human-machine interactions, which raise the interest in composite materials that possess both flexibility and sensing properties. Polypyrrole-coated cellulose nanocrystals and cellulose nanofibers were prepared using iron(III) chloride (FeCl3) oxidant, which were used to reinforce polyvinyl alcohol (PVA). The combination of weak H-bonds and iron coordination bonds and the synergistic effect of these components yielded self-healing nanocomposite films with robust mechanical strength (409% increase compared to pure PVA and high toughness up to 407.1%) and excellent adhesion (9670 times greater than its own weight) to various substrates in air and water. When damaged, the nanocomposite films displayed good mechanical (72.0-76.3%) and conductive (54.9-91.2%) recovery after a healing time of 30 min. More importantly, the flexible nanocomposites possessed high strain sensitivity under subtle strains (

A self-healing electrode is an electrical conductor that can repair internal damage by itself, similar to human skin. Since self-healing electrodes are based on polymers and hydrogels, these components are still limited by low electrical conductivity and mechanical strength. In this study, we designed an electrically conductive, mechanically strong, and printable self-healing electrode using liquid crystal graphene oxide (LCGO) and silver nanowires (AgNWs). The conductive ink was easily prepared by simply mixing LCGO and AgNWs solutions. The ultrathin (3 μm thick) electrode can be printed in various shapes, such as a butterfly, in a freestanding state. The maximum conductivity and strength of the LCGO/AgNW composite were 17 800 S/cm and 4.2 MPa, respectively; these values are 24 and 4 times higher, respectively, than those of a previously developed self-healing electrode. The LCGO/AgNW composite self-healed internal damage in ambient conditions with moisture and consequently recovered 96.8% electrical conductivity and 95% mechanical toughness compared with the undamaged state. The electrical properties of the composite exhibited metallic tendencies. Therefore, these results suggest that the composite can be used as an artificial electronic skin that detects environmental conditions, such as compression and temperature. This self-healing artificial electronic skin could be applied to human condition monitoring and robotic sensing systems.

Recent interest in the fields of human motion monitoring, electronic skin, and human–machine interface technology demands strain sensors with high stretchability/compressibility (ε > 50%), high sensitivity (or gauge factor (GF > 100)), and long-lasting electromechanical compliance. However, current metal- and semiconductor-based strain sensors have very low (ε < 5%) stretchability or low sensitivity (GF < 2), typically sacrificing the stretchability for high sensitivity. Composite elastomer sensors are a solution where the challenge is to improve the sensitivity to GF > 100. We propose a simple, low-cost fabrication of mechanically compliant, physically robust metallic carbon nanotube (CNT)-polydimethylsiloxane (PDMS) strain sensors. The process allows the alignment of CNTs within the PDMS elastomer, permitting directional sensing. Aligning CNTs horizontally (HA-CNTs) on the substrate before embedding in the PDMS reduces the number of CNT junctions and introduces scale-like features on the CNT film perpendicular to the tensile strain direction, resulting in improved sensitivity compared to vertically-aligned CNT-(VA-CNT)-PDMS strain sensors under tension. The CNT alignment and the scale-like features modulate the electron conduction pathway, affecting the electrical sensitivity. Resulting GF values are 594 at 15% and 65 at 50% strains for HA-CNT-PDMS and 326 at 25% and 52 at 50% strains for VA-CNT-PDMS sensors. Under compression, VA-CNT-PDMS sensors show more sensitivity to small-scale deformation than HA-CNT-PDMS sensors due to the CNT orientation and the continuous morphology of the film, demonstrating that the sensing ability can be improved by aligning the CNTs in certain directions. Furthermore, mechanical robustness and electromechanical durability are tested for over 6000 cycles up to 50% tensile and compressive strains, with good frequency responses with negligible hysteresis. Finally, both types of sensors are shown to detect small-scale human motions, successfully distinguishing various human motions with reaction and recovery times of as low as 130 ms and 0.5 s, respectively.

Polymer-based conductive hydrogels have the synergistic advantages of high conductivity and tissue-like properties, making them promising candidates for the construction of flexible electronic devices. However, conductive hydrogel materials can easily absorb microorganisms due to their high water content. To address the problem that conductive hydrogels are susceptible to infection by external pathogens when monitoring wounds and when used in implanted organs, tannic acid-borax (TA-B) complexes are introduced into classical dual network polyacrylamide/agarose (PAM/Agar) hydrogels to form PAM/Agar/TA-B hydrogel conductors. These hydrogels are antibacterial and have good mechanical properties, light transmission, electrical conductivity, and adhesion. TA-B increases the compressive stress of the PAM/Agar/TA-B hydrogel by 58.14% compared to a PAM/Agar hydrogel. The PAM/Agar/TA-B hydrogel can be used as an electronic conductor for electronic skin and wearable sensors. Outstanding biocompatibility allows the hydrogel to be used as a monitoring device at wounds to monitor heartbeat, skin wounds, and internal tissue status in real time. In summary, an antibacterial strain sensing matrix that is safe for human health monitoring is developed.

The development of electrically responsive sensors that interact directly with human skin and at the same time produce a visual indication of the temperature is in great demand. Here, we report a highly sensitive electronic skin (E-skin) sensor that measures and visualizes skin temperature simultaneously using a biocompatible hydrogel displaying thermoresponsive transparency and resistivity resulting from a temperature dependence of the strength of the hydrogen bonding between its components. This thermoresponsive hydrogel (TRH) showed a temperature dependence of not only the proton conductivity but also of its transmittance of light through a change in polymer conformation. We were able to use our TRH temperature sensor (TRH-TS) to measure temperature in a wide range of temperatures based on a change in its intrinsic resistivity (-0.0289 °C-1 ) and to visualize the temperature due to its thermoresponsive transmittance (from 7% to 96%). The TRH-TS exhibited high reliability upon multiple cycles of heating and cooling. The on-skin TRH-TS patch is also shown to successfully produce changes in its impedance and optical transparency as a result of changes in skin temperature during cardiovascular exercise. This work has shown that our biocompatible TRH-TS is potentially suitable as wearable E-skin for various emerging flexible healthcare monitoring applications.

The latest generation of wearable devices features materials that are flexible, conductive, and stretchable, thus meeting the requirements of stability and reliability. However, the metal conductors that are currently used in various equipments cannot achieve these high performance expectations. Hence, a mussel-inspired conductive hydrogel (HAC-B-PAM) is prepared with a facile approach by employing polyacrylamide (PAM), dopamine-functionalized hyaluronic acid (HAC), borax as a dynamic cross-linker agent, and Li+ and Na+ as conductive ions. HAC-B-PAM hydrogels demonstrate an excellent stretchability (up to 2800%), high tensile toughness (42.4 kPa), self-adhesive properties (adhesion strength to porcine skin of 49.6 kPa), and good self-healing properties without any stimuli at room temperature. Furthermore, the fabricated hydrogel-based strain sensor is sensitive to deformation and can detect human body motion. Multifunctional hydrogels can be assembled into flexible wearable devices with potential applications in the field of electronic skin and soft robotics.

Electronic fabrics that combine traditional fabric with intelligent functionalities have attracted increasing attention. Here an all-fabric pressure sensor with a wireless battery-free monitoring system was successfully fabricated, where a 3D penetrated fabric sandwiched between two highly conductive fabric electrodes acts as a dielectric layer. Thanks to the good elastic recovery of the spacer fabric, the capacitance pressure sensor exhibits a high sensitivity of 0.283 KPa

Recent research progress of relieving discomfort between electronics and human body involves serpentine designs, ultrathin films, and extraordinary properties of nanomaterials. However, these strategies addressed thus far each face own limitation for achieving desired form of electronic-skin applications. Evenly matched mechanical properties anywhere on the body and imperceptibility of electronics are two essentially required characteristics for future electronic-skin (E-skin) devices. Yet accomplishing these two main properties simultaneously is still very challenging. Hence, we propose a novel fabrication method to introduce kirigami approach to pattern a highly conductive and transparent electrode into diverse shapes of stretchable electronics with multivariable configurability for E-skin applications. These kirigami engineered patterns impart tunable elasticity to the electrodes, which can be designed to intentionally limit strain or grant ultrastretchability depending on applications over the range of 0 to over 400% tensile strain with strain-invariant electrical property and show excellent strain reversibility even after 10 000 cycles stretching while exhibiting high optical transparency (80%). The versatility of this work is demonstrated by ultrastretchable transparent kirigami heater for personal thermal management and conformal transparent kirigami electrophysiology sensor for continuous health monitoring of human body conditions. Finally, by integrating E-skin sensors with quadrotor drones, we have successfully demonstrated human-machine-interface using our stretchable transparent kirigami electrodes.

Sensitive, specific, yet multifunctional tattoo-like electronics are ideal wearable systems for "any time, any where" health monitoring because they can virtually become parts of the human skin, offering a burdenless "unfeelable" wearing experience. A skin-like, multifunctional electronic tattoo made entirely from gold using a standing enokitake-mushroom-like vertically aligned nanowire membrane in conjunction with a programmable local cracking technology is reported. Unlike previous multifunctional systems, only a single material type is needed for the integrated gold circuits involved in interconnects and multiplexed specific sensors, thereby avoiding the use of complex multimaterials interfaces. This is possiblebecause the programmable local cracking technology allows for the arbitrary fine-tuning of the properties of elastic gold conductors from strain-insensitive to highly strain-sensitive simply by adjusting localized crack size, shape, and orientations-a capability impossible to achieve with previous bulk cracking technology. Furthermore, in-plane integration of strain/pressure sensors, anisotropic orientation-specific sensors, strain-insensitive stretchable interconnects, temperature sensors, glucose sensors, and lactate sensors without the need of soldering or gluing are demonstrated. This strategy opens a new general route for the design of next-generation wearable electronic tattoos.

Flexible and wearable pressure sensors have attracted a tremendous amount of attention due to their wider applications in human interfaces and healthcare monitoring. However, achieving accurate pressure detection and stability against external stimuli (in particular, bending deformation) over a wide range of pressures from tactile to body weight levels is a great challenge. Here, we introduce an ultrawide-range, bending-insensitive, and flexible pressure sensor based on a carbon nanotube (CNT) network-coated thin porous elastomer sponge for use in human interface devices. The integration of the CNT networks into three-dimensional microporous elastomers provides high deformability and a large change in contact between the conductive CNT networks due to the presence of micropores, thereby improving the sensitivity compared with that obtained using CNT-embedded solid elastomers. As electrical pathways are continuously generated up to high compressive strain (∼80%), the pressure sensor shows an ultrawide pressure sensing range (10 Pa to 1.2 MPa) while maintaining favorable sensitivity (0.01-0.02 kPa

Conducting hydrogels have attracted attention as a special functional class of smart soft materials and have found applications in various advanced fields. However, acquiring all the characteristics such as conductivity, adequate adhesiveness, self-healing ability, stretchability, biocompatibility, and stimulating deformation responsiveness still remains a challenge. Inspired by the mechanism of bioadhesion in marine mussels, a multifunctional nanocomposite hydrogel with excellent adhesiveness to a broad range of substrates including human skin was developed with the help of synergistic multiple coordination bonds between clay, poly(N-isopropylacrylamide) (PNIPAM), and polydopamine nanoparticles (PDA-NPs). The prepared hydrogel showed controllable near-infrared (NIR) responsive deformation after incorporation of PDA-NPs as highly effective photothermal agents in the thermo-sensitive PNIPAM network. Meanwhile, the fabricated nanocomposite hydrogels showed excellent stretchability and conductivity, which make them attractive material candidates for application in various fields, such as electronic skin, wearable devices, and so on.