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The Early Miocene Taşkapı-Mecitli granitoid that is located in the northern section of the Eastern Anatolia Collision Zone has typical I-type, metaluminous and calk-alkaline characteristics. It also contains mafic microgranular / magmatic enclaves (MMEs). New Ar-Ar dating results show that the age of the Taşkapı-Mecitli granitoid is ∼23 Ma and it crystallised in the Early Miocene, in contrast to its previously known Cretaceous age. Identical crystallisation ages (∼23 Ma), similar mineral assemblages and geochemical compositions, and indistinguishable isotopic compositions of MMEs and host rocks imply that the MMEs are most consistent with a cumulate origin formed at earlier stages of the same magmatic system that produced the Taşkapı-Mecitli granitoid. MELTS modelling suggests that magma of the Taşkapı-Mecitli granitoid was the result of fractionation under a crustal pressure of 4 kbar, with a H 2 O content of 1.5%. EC-AFC model calculation reveals that the Taşkapı-Mecitli granitoid includes from 0.5% to 2% crustal assimilation rates. These rates indicate that crustal contamination can be negligible when compared to fractional crystallisation in the evolution of the magma beneath the Taşkapı-Mecitli granitoid. The partial melting model calculations and MORB-normalised trace element concentrations of the least evolved samples of the Taşkapı-Mecitli granitoid are consistent with those of mafic melts obtained from partial melting of interacting mantle- lower crust with a melting degree of 18%. The age (23 Ma) of the post- or syn-collisional Taşkapı-Mecitli granitoid suggests that the collision between Arabian and Eurasian plates could be before/around ∼23 Ma (Late Oligocene to Early Miocene). [ABSTRACT FROM AUTHOR]

Collision-related Quaternary mafic volcanism to the north of Lake Van (Eastern Anatolia, Turkey) occurred by eruptions from both volcanic centres and extensional fissures trending approximately north-south. We report new major, trace and rare earth element abundances, Sr-Nd-Pb isotope ratios and K-Ar ages for basaltic and more evolved hawaiitic and mugearitic lava flows. The new K-Ar ages indicate that magmatic activity occurred between 10 and 04 Ma. The volcanic products consist of mildly alkaline lavas, ranging in composition from basalt to hawaiite and mugearite. Energy-constrained assimilation and fractional crystallization (EC-AFC) model calculations suggest that the least evolved basaltic samples were unaffected by the combined effects of fractional crystallization and crustal contamination processes, in contrast to the more evolved hawaiitic and mugearitic lavas, which have experienced up to 2-3% crustal assimilation. Calculations based on crustal temperatures and Curie point depths indicate that the magma chamber, from which the basic to evolved lavas were derived, might be located at a depth of around 6-8 km, within the upper crust. Enrichment of large ion lithophile elements and light rare earth elements relative to high strength field elements, and higher 87Sr/86Sr and Pb isotopic ratios and lower 144Nd/143Nd of the least evolved basaltic samples indicate that the mantle source region of the Quaternary mafic magmas might have been enriched by melts that were derived from subducted sediments with a partial melting degree of around 10% rather than from Altered Oceanic Crust melts and fluids. Our model melting calculations show that the basaltic melts might have been produced by melting of a mantle source containing both amphibole and garnet with a partial melting degree of 3%. Results of our petrological models indicate that a metasomatized mantle source, which was infiltrated by a mixture of 93% mantle melt and 7% sediment melt plus 001% residual rutile, added to mantle melt, could have been the source composition of the basaltic melts that produced the Quaternary mafic volcanism. [ABSTRACT FROM AUTHOR]

The Pliocene Etrüsk stratovolcano, located in the northeast of Lake Van (Eastern Anatolia; Turkey), is one of the important volcanic centres in the Eastern Anatolian collision zone. Mt. Etrüsk overlies a widespread volcanic plateau, consisting of basaltic and hawaiitic lavas formed by fissure eruptions between 4.9–4.5 Ma. These basic lavas contain a phenocryst phase consisting of olivine, plagioclase and clinopyroxene. Trace element ratio diagrams imply that these basic magmas were generated from a mantle that contained a clear subduction component that is related to the subducted sediments rather than fluids or altered oceanic crust. Results of the melting models on the basaltic plateau lavas indicate that there was a marked variation both in the mantle source mineralogy (i.e. the ratio of garnet peridotite to spinel peridotite in the source varies between 60/40% and 40/60%) and the degree of melting (i.e. F between 0.8–4%). This can be explained by a model in which magmas were generated by partial melting of both metasomatised lithospheric and deeper asthenospheric mantle sources in an extensional setting in response to the partial delamination of the lithospheric mantle of Eastern Anatolia and then mixed with each other during Pliocene times. Central eruptions that formed the Etrüsk volcano lasted ~ 600 kyr between 4.3–3.7 Ma during Zanclean times. The estimated depth of the Etrüsk magma chamber is ~ 9–12 km. The volcano erupted lavas with a rather narrow compositional range from latite to rhyolite, which are either transitional or mildly alkaline in character. The Etrüsk lavas contain plagioclase, clino- and orthopyroxene, biotite, K-feldspar and rarely, minor amounts of olivine and amphibole in the phenocryst phase. A composite chemo-stratigraphic section of the volcano and petrological models indicate that the evolved lavas of the Etrüsk volcano differentiated from a parental magma composition, which is similar to that of the most primitive plateau basalt lavas underlying the volcano, via the AFC process, and experienced at least two major magma replenishment episodes at 4.1 Ma and 3.8 Ma during the magma chamber evolution. [ABSTRACT FROM AUTHOR]

In Eastern Anatolia, the Karayazı–Göksu basaltic plateau is one of the basaltic eruption centers of post-collisional volcanism, located between the convergence zone of the Arabian and Anatolian plates. The geological and geochemical evolution of the plateau is documented using new 40Ar/39Ar age data, major-and trace element abundances, mineral geochemistry, and isotope compositions (Sr–Nd–Hf) for better understanding the petrogenesis and mantle source characteristics. Samples yield whole-rock 40Ar/39Ar ages of 12.53 ± 0.05 and 12.68 ± 0.05 Ma for transitional basalts (Middle Miocene), 5.88 ± 0.20 Ma for tholeiitic lavas (Late Miocene), and 2.28 ± 0.03 and 2.48 ± 0.12 Ma for alkali members (Early Quaternary). The results suggest that the fractional crystallization of olivine and clinopyroxene in transitional, tholeiitic and lower alkaline lavas, and clinopyroxene in upper alkaline lavas, played a crucial role in their magmatic evolution without significant crustal contamination. Clinopyroxene-liquid equilibria indicate that the crystallization of transitional basalts occurred at the Moho and lower crust (temperature range 1157–1215 °C), tholeiitic basalts at the lower crust (temperature range 1154–1195 °C), alkaline basalts at lower to mid-crustal depths (temperature range 1083–1195 °C). The subduction-related metasomatism is in the form of melts derived from subducted sediments and decrease from Middle Miocene transitional to alkaline Early Quaternary basalts, as indicated by the Sr–Nd–Hf isotopes and Ba/La and Th/Yb contents. The Early Quaternary alkaline basalts contain contributions from isotopically depleted but chemically enriched (enriched-MORB-like) asthenospheric mantle domain. Major elements–based parameters and olivine mineral chemistry yield that Karayazı–Göksu basalts could not be derived from a sole peridotite mantle source; the pyroxenite/eclogite-like mantle component would have contributed to the members of the plateau. Three-component mixing results using Sr Nd isotopes indicate that the altered oceanic crust contributes to 0.5%–1% of the melt (crust vs. sediment about 65:35) for tholeiitic and alkaline basalts and reach up to 4% for transitional basalts (crust vs. sediment about 55:45). Melt equilibration depths of the basalts indicate that the lithospheric thickness of the region has not been changed on a large scale since the Middle Miocene to the Early Quaternary. [Display omitted] • Middle-Miocene to Early-Quaternary basaltic rocks. • Decreasing subduction influence from Middle Miocene to Early Quaternary. • E-MORB like asthenospheric mantle component for younger members. • Localized removal of Eastern Anatolian lithospheric mantle. [ABSTRACT FROM AUTHOR]

The Eastern Anatolian region provides a good example for collision–related volcanic activity. This activity started during the Middle Miocene and continued through the Pliocene and Quaternary. The new K − Ar ages reveal that the post–collisional Pliocene Timar basalts located in the East Anatolian Accretionary Complex (EAAC) erupted between 4.72 (Zanclean) and 3.29–2.93 Ma (Piacenzian). The Pliocene Timar basalts consist of plagioclase, clinopyroxene (augite), and olivine minerals and have glomeroporphyritic, intergranular, and ophitic textures. They display enrichment in light rare earth elements (LREEs) with (La/Yb) N values that range between 3.19 and 6.66 to 21.63–5.61. 87Sr/86Sr(i) and 143Nd/144Nd(i) isotopic ratios of the Timar basalts are 0.70599–0.70436 and 0.51277–0.51259, respectively. The εNd(t) values of these rocks range between 1.0116 and 1.0121. 87Sr/86Sr (i) and Nd(t) contents indicate crustal contamination during the emplacement of the Timar basalts. According to the Energy Constrained–Assimilation Fractional Crystallization (EC–AFC) model, this contamination rate is between ~1.4 and 4.4%. The melting model shows that the least evolved samples of the Timar basalts were formed by ~0.1–2% partial melting of the lherzolitic source. Primitive melts that constituent Timar basalts were occurred with partial melting of a magma source that has predominantly spinel bearing mineralogy. All data indicate that the origin of the parental melts of the Timar basalts is metasomatized lithospheric mantle source and then these melts reached the surface from the fissures that is related to extensional tectonics in Pliocene. • The post-collisional Pliocene Timar basalts in the Turkish-Iranian high plateau. • The Geochemical and geochronological features of the Timar basalts. • The partial melting of a metasomatized spinel–rich lithospheric mantle source. • The EC-AFC modelling for the Pliocene Timar basalts. [ABSTRACT FROM AUTHOR]

Abstract The Quaternary (0.66–0.63 Ma) nepheline basanites (ne - basanite) are the firstly observed volcanic products of Arabia-Eurasia collision on Bitlis Pötürge Massif. They composed of clinopyroxene, olivine, Ti-magnetite, Cr spinel, and nepheline. The forsterite compositions of olivines range between 73 and 83%, calcic clinopyroxenes show modest variations in Wo 48–57 -En 37–45 -Fs 5–7 and nephelines occur as minor minerals within the networks of other groundmass minerals. They are characterized by low SiO 2 (40.16–41.96 wt%), high MgO contents (8.54–9.73 wt%) and similar Sr Nd isotopic compositions with Arabian Plate volcanics. Mineral and whole rock thermobarometry yield crystallization pressure and a temperature range between 8 and 20 kbar and 1301 °C – 1035 °C respectively. Lavas have high Mg-number (>0.58), high Cr and Ni contents and strong LREE enrichment but depletion in Rb, K, and Pb. Trace elements together with Sr isotopic compositions inferred negligible assimilation of the local upper crustal material. The calculated average pressure and temperature of mantle melting for ne- basanites is 2,85 kbar and 1353 °C respectively. FC3MS (wt% FeO/CaO-3*MgO/SiO 2) parameter and melting models using REE data reveal Çatak basanites are products of amphibole and phlogopite bearing metasomatised lithospheric mantle in garnet stability field. They seem to originated from depths of ~ 85 km which corresponds to the base of the Arabian lithosphere in the region. Graphical abstract Unlabelled Image Highlights • The firstly observed collision related volcanics in Bitlis Suture Zone • The calculated average pressure and temperature of mantle melting is 2,85 kbar and 1353 °C. • They formed through the melts from Arabian Lithospheric mantle beneath the Bitlis Massif. [ABSTRACT FROM AUTHOR]