1. Adsorption equilibrium and kinetics on N-lauroyl- N-methylglucamide at air/water interface.
- Author
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Chai, J. L., Yang, X. D., Gao, Y. H., Chen, J. F., and Wang, Zh. N.
- Subjects
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ADSORPTION (Chemistry) , *SURFACE chemistry , *SOLUTION (Chemistry) , *DYNAMICS , *EQUILIBRIUM - Abstract
The adsorption equilibrium and kinetics of N-lauroyl- N-methylglucamide (MEGA-12) aqueous solution were studied. The critical micelle concentration, the maximum surface excess, and the minimum area per molecule of MEGA-12 were obtained as 2.48 × 10−4 mol/l, 4.883 × 10−6 mol/m2, and 0.34 nm2, respectively. The adsorption kinetics of MEGA-12 was studied by the maximum bubble pressure method. The result shows that in the initial stage or at small MEGA-12 concentrations, the adsorption process is diffusion-controlled; however, it changes to become adsorption-controlled at the end of the process. The effects of temperature, inorganic salts, alcohols, and ionic liquid on the adsorption kinetics were also discussed. [ABSTRACT FROM AUTHOR]
- Published
- 2008
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