1. Investigation of spin moment in Ga-substituted cobalt ferrite: magnetic Compton scattering and photoemission studies.
- Author
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Sharma, Arvind, Mund, H., Bapna, Komal, Tiwari, Shailja, Itou, M., Sakurai, Y., and Ahuja, B.
- Subjects
GALLIUM compounds ,COMPTON scattering ,MOMENTUM density ,ELECTRONIC structure ,PHOTOELECTRON spectroscopy ,DOPING agents (Chemistry) - Abstract
We have studied the spin-dependent electron momentum density distribution in CoGaFeO ( x = 0.2, 0.3) at a low temperature (8 K) using magnetic Compton scattering technique. Further, the effect of Ga doping on the electronic structure is studied using X-ray photoemission spectroscopy (XPS). It is revealed that doping of Ga substitutes the Fe ions predominantly at tetrahedral (P) site, which promotes a gradual immigration of small amount of Co ions from tetrahedral to octahedral (Q) site. Total spin moment increases remarkably on increasing the doping concentration of nonmagnetic Ga ( x = 0 → 0.3) in the base cobalt ferrite. It is seen that major contribution to total spin moment mainly arises from Co ions while itinerant electrons show negative polarization. On Ga doping, spin moment at Fe site increases dramatically with a minor increment at Co site. The increased spin moment is attributed to the increased Q/P occupancy ratio of Fe as well as Co ions as determined using XPS measurements. In contrast, orbital moment does not show such deviations, suggesting that a small amount of Ga doping can enhance the magnetization significantly, without inducing any significant distortion to modify the spin-orbit coupling. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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