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Your search keyword '"Pestova, S. V."' showing total 3 results
Start Over Author "Pestova, S. V." Topic diterpenoids
3 results on '"Pestova, S. V."'

3. Synthesis of Abietane-derived Disulfides with Monosaccharide Fragments.

Author

Izmest'ev, E. S., Pestova, S. V., Rubtsova, S. A., and Kuchin, A. V.

Subjects
*DISULFIDES, *MOIETIES (Chemistry), *MONOSACCHARIDES, *HYDROXYL group, *THIOLS, *GLUCOSE
Abstract

A series of asymmetric disulfides was obtained in yields of 38–50% by the co-oxidation of a mixture of diterpene abietane-derived thiols and thiols synthesized from protected monosaccharides with galacto-, fructo-, and glucopyranose and ribofuranose fragments. After removal of the acetyl protection in the disulfide containing 1,2,3,4-tetra-O-acetyl-β-D-glucopyranose and dehydroabietane moieties, a disulfide with free glucose hydroxyl groups was obtained in a yield of 94%. [ABSTRACT FROM AUTHOR]

Published
2020
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