1. Accurate and fast master equation modeling of triplet-triplet annihilation in organic phosphorescent emission layers including correlations
- Author
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M. Taherpour, C. van Hoesel, R. Coehoorn, P. A. Bobbert, Molecular Materials and Nanosystems, Macromolecular and Organic Chemistry, Center for Computational Energy Research, ICMS Core, and EIRES Chem. for Sustainable Energy Systems
- Subjects
Organic light emitting diode ,Disordered systems (theory) ,many-body calculations ,Approximate methods for many-body systems ,master equation ,Optoelectronics - Abstract
Triplet-triplet annihilation (TTA) in phosphorescent emission layers of modern organic light-emitting diodescompromises their performance and device lifetime. TTA can occur by a Förster-type interaction between twotriplets, leading to a loss of one of them. The TTA process gives rise to correlations in the positions of thesurviving triplets, which complicate its study. These correlations can in principle be accounted for exactly inkinetic Monte Carlo (KMC) simulations, but such simulations are computationally expensive. Here, we presentmaster equation modeling of TTA that accounts for correlations in a computationally efficient way. Cases withoutand with triplet diffusion, which partly washes out correlations, are considered. We calculate the influence ofTTA on transient photoluminescence experiments, where it leads to a deviation from exponential decay, and onsteady-state emission efficiency. A comparison with KMC simulations shows that our master equation modelingis an accurate and computationally competitive alternative.
- Published
- 2022
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