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Start Over Author "Bosca, Federica" Topic diels-alder reaction
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1. Microwave-Assisted Synthesis and Physicochemical Characterization of Tetrafuranylporphyrin-Grafted Reduced-Graphene Oxide.

Author

Bosca, Federica, Orio, Laura, Tagliapietra, Silvia, Corazzari, Ingrid, Turci , Francesco, Martina, Katia, Pastero , Linda, Cravotto, Giancarlo, and Barge, Alessandro

Subjects
*PORPHYRINS, *FURANS, *DIELS-Alder reaction, *GRAPHENE oxide, *MICROWAVES, *SURFACE morphology
Abstract

This work describes the design of a modified porphyrin that bears four furan rings linked by 1,2-bis-(2-aminoethoxy)ethane spacers. This unit is a well-suited scaffold for a Diels-Alder reaction with commercial reduced-graphene oxide, which is also described in this paper. A new hybrid material is obtained, thanks to efficient grafting under microwave irradiation, and fully characterized in terms of structure (UV, TGA, Raman) and morphology (HR-TEM and AFM). Potential applications in photo- and sonodynamic therapy are envisaged. [ABSTRACT FROM AUTHOR]

Published
2016
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