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Polymer materials, such as polymethylmethacrylate (PMMA), are widely used as insulators in vacuum. The insulating performance of a high-voltage vacuum system is mainly limited by surface flashover of the insulators rather than bulk breakdown. Non-thermal plasmas are an efficient method to modify the chemical and physical properties of polymer material surfaces, and enhance the surface insulating performance. In this letter, an atmospheric-pressure dielectric barrier discharge is used to treat the PMMA surface to improve the surface flashover strength in vacuum. Experimental results indicate that the plasma treatment method using Ar and CF4 (10:1) as the working gas can etch the PMMA surface, introduce fluoride groups to the surface, and then alter the surface characteristics of the PMMA. The increase in the surface roughness can introduce physical traps that can capture free electrons, and the fluorination can enhance the charge capturing ability. The increase in the surface roughness and the introduction of the fluoride groups can enhance the PMMA hydrophobic ability, improve the charge capturing ability, decrease the secondary electron emission yield, increase the surface resistance, and improve the surface flashover voltage in vacuum. [ABSTRACT FROM AUTHOR]

Dielectric barrier discharge excitated by pulsed power is a promising approach for producing nonthermal plasma at atmospheric pressure, but pulsed power generators vary widely in performance and should be chosen according to application requirements. In this paper, a repetitive unipolar nanosecond-pulse generator is constructed using resonant charging and one-stage magnetic compression circuits, where IGBT and magnetic switches are the key units, respectively. The generator is capable of providing repetitive pulses with a voltage of up to 30 kV and duration of 70 ns at a 300 Ω resistive load. Output pulse voltage can be adjusted by varying ac input voltage or trigger pulse-width. This compact and convenient generator has been used successfully to produce stable dielectric barrier discharge. [ABSTRACT FROM AUTHOR]

Dielectric barrier discharge (DBD) is proved to be an effective method for surface treatment of polymers over the past 20 years and is now widely used in the fields of surface modification. In this paper, surface treatment of polyethylene terephthalate (PET) films for improving the hydrophilicity using DBD excited by unipolar nanosecond pulses is presented. Two typical discharges exhibiting homogeneous and filamentary modes are obtained under certain experimental conditions, and then, they are used to modify the surface of PET films. The microstructure and properties of the film surface before and after treatment are characterized with water contact angle measurement, scanning electron microscope, atomic force microscope, and X-ray photoelectron spectroscope. The results show that, with the treatment power density of 192 and 158 mW/cm2 in filamentary and homogeneous modes, respectively, surface morphology and property after treatment are significantly changed, and the physical etching and introduction of oxygen-containing polar functional groups account for the decease of surface contact angle and the increase of surface roughness. Compared with the filamentary DBD treatment, the homogeneous DBD (HDBD) is more effective in surface treatment, such as lower contact angle, higher roughness, and more oxygencontaining function groups after treatment. It is attributed to the fact that the HDBD can achieve a uniform treatment and canmake the physical and chemical interaction much sufficient. [ABSTRACT FROM AUTHOR]

Nanosecond-pulse breakdown indicates special characteristics depending on the pulse rise-time and duration. Based on a repetitive nanosecond-pulse generator, breakdown phenomena of parallel-plane gaps in nitrogen were investigated with single pulse and repetitive bursts under different gap conditions. The relationships between applied voltage, pulse repetition frequency, breakdown time lag, repetitive pulse stress time and the number of applied pulses are presented. The curves regarding E-field strength, breakdown time lag and gas pressure are also obtained. The experimental results show that breakdown characteristics with repetitive nanosecond-pulses are different from that with single pulse. Repetitive nanosecond-pulse breakdown is concerned with the accumulation effect that is attributed to residual ions and metastable species survived from previous pulses. in addition, a modified empirical formula about E-field strength, breakdown time lag and gas density is given for the breakdown data. [ABSTRACT FROM AUTHOR]

Based on a Marx generator and a coaxial pulse forming line, an experimental investigation of surface flashover characteristics in vacuum is conducted by using nanosecond pulses of 10 ns rise time and 30 us full width at half maximum (FWHM). Insulator dielectrics chosen for this investigation are Teflon, PMMA and Nylon. The tested factors include gas pressure, cone angle of conical frustum, diameter and length of cylindrical insulator, material and shape of electrode, and contact style between insulator and electrodes. The effects of these parameters on the surface flashover characteristics are described and analyzed in this paper. In addition, the character of flashover time lag in the nanosecond range, and surface flashover theory in vacuum charged by nanosecond pulses are also discussed. [ABSTRACT FROM AUTHOR]

This paper illustrates images of dielectric-barrier discharge (DBD) excitated by repetitive unipolar nanosecond pulses in atmospheric air. Different images are obtained for three barrier dielectrics and various gap lengths. Discharge images show that the nanosecond-pulse DBD observed with the eye is a diffuse glowlike mode when air gap is 2 mm; clear filamentary discharge is seen with the eye in the case of air gap of 8 mm. The results show that gap length and dielectrics are the important factors influencing the transition from diffusive to filamentary discharges. [ABSTRACT FROM AUTHOR]

In the present work, the microwave dielectric ceramic (Ag0.5Bi0.5)- (MO0 SW0 S)O4 was prepared by using the solid-state reaction method. (Ag0.5Bi0.5)- (MO0.5W0.5)O4 was found to crystallize in the scheelite structure, in which Ag+ and Bi3+ occupy the A site randomly with 8-coordination while Mo6+ and W6+ occupy the B site with 4-coordination, at a sintering temperature above 500 °C, with lattice parameters a = b = 5.29469(2) Å and c = 11.62114(0) Å, space group I41/a (No. 88), and acceptable Rp = 9.38, Rwp = 11.2, and Rexp = 5.86. High-performance microwave dielectric properties, with permittivity ~26.3, Qf value ~ 10000 GHz, and temperature coefficient ~+20 ppm/°C, were obtained in the sample sintered at 580 °C. Its chemical compatibility with aluminum at its sintering temperature was revealed and confirmed by both X-ray and energy dispersive spectrometer analysis. This ceramic could be a good candidate for ultralow-temperature cofired ceramics. [ABSTRACT FROM AUTHOR]