1. Some Problems in the Theory of Perovskite Ferroelectrics.
- Author
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Maksimov, E. G., Matsko, N. L., Ebert, S. V., and Magnitskaya, M. V.
- Subjects
DIELECTRICS ,POLARIZATION (Electricity) ,FERROELECTRIC crystals ,ELECTRONS ,MATHEMATICAL analysis ,PHYSICS - Abstract
A brief review is given on the studies of ferroelectricity in perovskites. Early phenomenological theories of displacement-type ferroelectrics are considered. Two markedly different approaches based on density-functional theory are described. In one approach, the electron density of crystal is determined as a sum of Bloch functions. In the other, it is constructed as a superposition of the electron densities of individual ions. The latter approach gives a microscopic justification for the old phenomenological theories. We show that some phenomena in perovskites, which seemingly are of the order-disorder origin, can be explained by quasi-one-dimensional peculiarities of lattice dynamics. [ABSTRACT FROM AUTHOR]
- Published
- 2007
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