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Dielectric and conducting properties of unintentionally doped bulk and Sn-doped thin film β - Ga 2 O 3 samples were studied using time-domain terahertz spectroscopy. Complex permittivity and optical conductivity spectra from 0.25 to 2.5 THz were obtained experimentally over a broad temperature range. The low-temperature spectra of the unintentionally doped sample were fit using a model involving two oscillators. The parameters of one of them show an unusual temperature dependence, in particular, a pronounced increase in the oscillator strength upon heating above 50 K. This is interpreted as an absorption due to thermally activated charge carriers moving in localized potential minima linked to the unintentional doping. Upon heating, the influence of this optical conductivity mechanism strongly increases, and the sample becomes opaque in the THz range near 100 K. The nanocrystalline Sn-doped Ga 2 O 3 thin film sample exhibits a much higher optical conductivity than the unintentionally doped bulk sample, and its spectra are remarkably stable over a broad temperature range (4–750 K). This first study of β - Ga 2 O 3 based on phase-sensitive THz spectroscopy reveals how the impurities influence the high-frequency conductive properties of the material. [ABSTRACT FROM AUTHOR]

Polarized terahertz transmittance and infrared reflectivity measurements were performed on selected lead zirconate crystals atT= 10 K. The fit of the spectra enabled us to obtain all three principal components of its anisotropic dielectric function and the corresponding parameters of the polar phonon modes. [ABSTRACT FROM AUTHOR]