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This paper presents a technique for outdoor ceramic insulator pollution assessment based on partial discharge detection and analysis. Laboratory tests and data coming from a monitoring activity carried out on some insulators of transmission lines are reported. They support the effectiveness of partial discharge detection and analysis as a tool to carry out condition-based maintenance of insulators of overhead lines. In particular, it can be seen that partial discharge analysis highlights the mechanisms bringing insulators to flashover (dry band arc activity) and is, therefore, well suited to predict increasing pollution and imminent flashover. As a consequence, algorithms are proposed to provide a quantitative evaluation of pollution severity. [ABSTRACT FROM AUTHOR]