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Your search keyword '"Stubbs, Naomi E."' showing total 1 results
Start Over Author "Stubbs, Naomi E." Topic depolymerization
1 results on '"Stubbs, Naomi E."'

1. Polyaminoborane main chain scission using N-heterocyclic carbenes; formation of donor-stabilised monomeric aminoboranes.

Author

Stubbs, Naomi E., Jurca, Titel, Leitao, Erin M., Woodall, Christopher H., and Manners, Ian

Subjects
*CARBENES, *DEPOLYMERIZATION, *SINGLE crystals, *THERMAL stability, *X-ray diffraction
Abstract

The reaction of N-heterocyclic carbenes with polyaminoboranes [MeNH–BH2]n or [NH2–BH2]n at 20 °C led to depolymerisation and the formation of labile, monomeric aminoborane–NHC adducts, RNH–BH2–NHC (R = Me or H); a similar NHC adduct of Ph2N=BCl2 was characterized by single crystal X-ray diffraction. [ABSTRACT FROM AUTHOR]

Published
2013
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