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Your search keyword '"Gopal, Kandasamy"' showing total 2 results
Start Over Author "Gopal, Kandasamy" Topic coupling reactions (chemistry)
2 results on '"Gopal, Kandasamy"'

1. Ruthenium Catalyzed Intramolecular C-S Coupling Reactions: Synthetic Scope and Mechanistic Insight.

Author

Sharma, Shivani, Pathare, Ramdas S., Maurya, Antim K., Gopal, Kandasamy, Roy, Tapta Kanchan, Sawant, Devesh M., and Pardasani, Ram T.

Subjects
*RUTHENIUM catalysts, *INTRAMOLECULAR catalysis, *CARBON compounds, *COUPLING reactions (Chemistry), *BENZOTHIAZOLE, *CHEMICAL kinetics, *COMPUTATIONAL chemistry
Abstract

A ruthenium catalyzed intramolecular C-S coupling reaction of N-arylthioureas for the synthesis of 2-aminobenzothiazoles has been developed. Kinetic, isotope labeling, and computational studies reveal the involvement of an electrophilic ruthenation pathway instead of a direct C-H activation. Stereoelectronic effect of meta-substituents on the N-arylthiourea dictates the final regioselective outcome of the reaction. [ABSTRACT FROM AUTHOR]

Published
2016
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2. ChemInform Abstract: Ruthenium Catalyzed Intramolecular C-S Coupling Reactions: Synthetic Scope and Mechanistic Insight.

Author

Sharma, Shivani, Pathare, Ramdas S., Maurya, Antim K., Gopal, Kandasamy, Roy, Tapta Kanchan, Sawant, Devesh M., and Pardasani, Ram T.

Subjects
*RUTHENIUM catalysts, *COUPLING reactions (Chemistry), *CARBON, *SULFUR, *RADIOLABELING, *ELECTROPHILIC addition reactions
Abstract

Kinetic, isotope labeling, and computational studies reveal the involvement of an electrophilic ruthenation pathway instead of a direct C-H activation for this reaction. [ABSTRACT FROM AUTHOR]

Published
2016
Full Text
View/download PDF

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