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1. Base-free Knoevenagel condensation catalyzed by copper metal surfaces.

Author

Schneider, E. M., Zeltner, M., Kränzlin, N., Grass, R. N., and Stark, W. J.

Subjects
COPPER catalysts, CONDENSATION reactions, COPPER surfaces, COPPER powder, ACETATES, BENZALDEHYDE
Abstract

For the first time Knoevenagel condensation has been catalyzed by elemental copper with unexpected activity and excellent isolated yields. Inexpensive, widely available copper powder was used to catalyze the condensation of cyanoacetate and benzaldehyde under mild conditions. To ensure general applicability, a wide variety of different substrates was successfully reacted. [ABSTRACT FROM AUTHOR]

Published
2015
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