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Thermal modification is the most important commercial modification procedure. Thermally modified (TM) wood has improved durability, but its performance does not meet expectations predominately under moist conditions. To reduce water uptake of TM wood, Norway spruce specimens were treated with suspensions of a natural wax by dipping impregnation (DipI) or by vacuum-pressure impregnation (VPI). Wax-treated specimens were subsequently TM at 185, 200, 215, and 230°C. Control specimens were heated up to 100°C only. Contact angle (CA), short-term and long-term water uptake, bending strength, and performance against wood decay fungi of the resulting material were determined. The results show that a combination of wax treatment and thermal modification have a synergistic effect that considerably improves hydrophobicity, reduces liquid water uptake, slows down water vapor uptake, and improves the resistance against fungal decay of the treated material. [ABSTRACT FROM AUTHOR]

The use of wood in outdoor, above-ground applications is increasing in Europe. To further increase wood usage, more information related to service life and maintenance costs must be provided. Water exclusion efficacy (WEE) is one of the most important factors influencing service life and strongly correlates to wood moisture dynamics, surface properties, and hydrophobicity (WEE as a whole). WEE can be improved with modifications and hydrophobic treatments. The aim of this study was to elucidate which wood surface properties affect WEE and to note changes over time caused by artificial or natural aging. Wood samples of oak (Quercus), sweet chestnut (Castanea sativa), European larch (Larix decidua), Scots pine heartwood and sapwood (Pinus sylvestris), Norway spruce (Picea abies), and beech (Fagus sylvatica) were used to investigate this phenomenon. The moisture performance of the wood samples was improved with thermal modification, wax, oil, and biocide treatment. In total, 17 materials were prepared. After treatment, four different aging procedures were applied. Before and after aging, Fourier transform infrared spectra, colour, and contact angle were determined. The analysis of untreated wood based materials indicated that durability and hydrophobicity are related. Of all the treatments, wax performed the best and retained high hydrophobicity even after the most severe aging method (outdoor exposure). [ABSTRACT FROM AUTHOR]