15 results on '"Alexandra Zevalkink"'
Search Results
2. Experimental validation of high thermoelectric performance in RECuZnP2 predicted by high-throughput DFT calculations
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Alexander Dunn, Anubhav Jain, Sevan Chanakian, Junsoo Park, Arthur Mar, Alexandra Zevalkink, Amit Bhattacharya, Jan-Hendrik Pöhls, Sabah K. Bux, Nick Friesen, Brea E. Hogan, and Alex M. Ganose
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Materials science ,Phonon scattering ,Condensed matter physics ,Scattering ,Process Chemistry and Technology ,Ab initio ,02 engineering and technology ,Crystal structure ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,01 natural sciences ,0104 chemical sciences ,Mechanics of Materials ,Electrical resistivity and conductivity ,Thermoelectric effect ,General Materials Science ,Density functional theory ,Electrical and Electronic Engineering ,0210 nano-technology - Abstract
Accurate density functional theory calculations of the interrelated properties of thermoelectric materials entail high computational cost, especially as crystal structures increase in complexity and size. New methods involving ab initio scattering and transport (AMSET) and compressive sensing lattice dynamics are used to compute the transport properties of quaternary CaAl2Si2-type rare-earth phosphides RECuZnP2 (RE = Pr, Nd, Er), which were identified to be promising thermoelectrics from high-throughput screening of 20 000 disordered compounds. Experimental measurements of the transport properties agree well with the computed values. Compounds with stiff bulk moduli (>80 GPa) and high speeds of sound (>3500 m s−1) such as RECuZnP2 are typically dismissed as thermoelectric materials because they are expected to exhibit high lattice thermal conductivity. However, RECuZnP2 exhibits not only low electrical resistivity, but also low lattice thermal conductivity (∼1 W m−1 K−1). Contrary to prior assumptions, polar-optical phonon scattering was revealed by AMSET to be the primary mechanism limiting the electronic mobility of these compounds, raising questions about existing assumptions of scattering mechanisms in this class of thermoelectric materials. The resulting thermoelectric performance (zT of 0.5 for ErCuZnP2 at 800 K) is among the best observed in phosphides and can likely be improved with further optimization.
- Published
- 2021
3. Exceptionally high electronic mobility in defect-rich Eu2ZnSb2−xBix alloys
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Sevan Chanakian, David Uhl, Junsoo Park, Valeri Petkov, Sabah K. Bux, Fivos Drymiotis, Alexandra Zevalkink, and David Neff
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Diffraction ,Materials science ,Condensed matter physics ,Renewable Energy, Sustainability and the Environment ,Band gap ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Synchrotron ,0104 chemical sciences ,law.invention ,Thermoelectric figure of merit ,Effective mass (solid-state physics) ,Distribution function ,law ,Speed of sound ,General Materials Science ,0210 nano-technology ,Order of magnitude - Abstract
The Zintl compound Eu2ZnSb2 was recently shown to have a promising thermoelectric figure of merit, zT ∼ 1 at 823 K, due to its low lattice thermal conductivity and high electronic mobility. In the current study, we show that further increases to the electronic mobility and simultaneous reductions to the lattice thermal conductivity can be achieved by isovalent alloying with Bi on the Sb site in the Eu2ZnSb2−xBix series (x = 0, 0.25, 1, 2). Upon alloying with Bi, the effective mass decreases and the mobility linearly increases, showing no signs of reduction due to alloy scattering. Analysis of the pair distribution functions obtained from synchrotron X-ray diffraction revealed significant local structural distortions caused by the half-occupied Zn site in this structure type. It is all the more surprising, therefore, to find that Eu2ZnBi2 possesses high electronic mobility (∼100 cm2 V−1 s−1) comparable to that of AM2X2 Zintl compounds. The enormous degree of disorder in this series gives rise to exceptionally low lattice thermal conductivity, which is further reduced by Bi substitution due to the decreased speed of sound. Increasing the Bi content was also found to decrease the band gap while increasing the carrier concentration by two orders of magnitude. Applying a single parabolic band model suggests that Bi-rich compositions of Eu2ZnSb2−xBix have the potential for significantly improved zT; however, further optimization is necessary through reduction of the carrier concentration to realize high zT.
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- 2020
4. Soft anharmonic phonons and ultralow thermal conductivity in Mg3(Sb, Bi)2 thermoelectrics
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Tyson Lanigan-Atkins, Mario Calderón-Cueva, Ayman Said, Douglas L. Abernathy, Jingxuan Ding, Olivier Delaire, Alexandra Zevalkink, and Arnab Banerjee
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Multidisciplinary ,Materials science ,Condensed matter physics ,Phonon scattering ,Scattering ,Phonon ,Anharmonicity ,Materials Science ,SciAdv r-articles ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,01 natural sciences ,0104 chemical sciences ,Thermal conductivity ,Thermoelectric effect ,0210 nano-technology ,Ternary operation ,Research Articles ,Research Article ,Applied Physics - Abstract
The atomistic origin of ultralow thermal conductivity in promising new thermoelectrics is revealed by experiments and simulations., The candidate thermoelectric compounds Mg3Sb2 and Mg3Bi2 show excellent performance near ambient temperature, enabled by an anomalously low lattice thermal conductivity (κl) comparable to those of much heavier PbTe or Bi2Te3. Contrary to common mass-trend expectations, replacing Mg with heavier Ca or Yb yields a threefold increase in κl in CaMg2Sb2 and YbMg2Bi2. Here, we report a comprehensive analysis of phonons in the series AMg2X2 (A = Mg, Ca, and Yb; X = Bi and Sb) based on inelastic neutron/x-ray scattering and first-principles simulations and show that the anomalously low κl of Mg3X2 has inherent phononic origins. We uncover a large phonon softening and flattening of low-energy transverse acoustic phonons in Mg3X2 compared to the ternary analogs and traced to a specific Mg-X bond, which markedly enlarges the scattering phase-space, enabling the threefold tuning in κl. These results provide key insights for manipulating phonon scattering without the traditional reliance on heavy elements.
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- 2021
5. Ultralow Thermal Conductivity in Diamond-Like Semiconductors: Selective Scattering of Phonons from Antisite Defects
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Taishan Zhu, Brenden R. Ortiz, Vladan Stevanović, Lídia C. Gomes, Alexandra Zevalkink, G. Jeffrey Snyder, Eric S. Toberer, Wanyue Peng, David M. Smiadak, Prashun Gorai, and Elif Ertekin
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Condensed matter physics ,Phonon scattering ,Phonon ,Scattering ,General Chemical Engineering ,Diamond ,02 engineering and technology ,General Chemistry ,engineering.material ,Stannite ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Thermal conductivity ,Molecular vibration ,Materials Chemistry ,engineering ,Kesterite ,0210 nano-technology - Abstract
In this work, we discover anomalously low lattice thermal conductivity (
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- 2018
6. Praseodymium Telluride: A High-Temperature, High-ZT Thermoelectric Material
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Bruce Dunn, Jean-Pierre Fleurial, David M. Smiadak, Brea E. Hogan, Paul von Allmen, Kathleen Lee, Dean Cheikh, Alexandra Zevalkink, Trinh Vo, and Sabah K. Bux
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Materials science ,Condensed matter physics ,Praseodymium ,Fermi level ,chemistry.chemical_element ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,01 natural sciences ,0104 chemical sciences ,symbols.namesake ,chemistry.chemical_compound ,General Energy ,Effective mass (solid-state physics) ,chemistry ,Seebeck coefficient ,Telluride ,Thermoelectric effect ,symbols ,Density of states ,0210 nano-technology - Abstract
Summary Refractory rare-earth tellurides with the Th 3 P 4 structure type have attracted considerable interest as high-performance thermoelectric materials since the 1980s due to their high dimensionless figure of merit ( ZT ). Extensive work has been conducted on La 3−x Te 4 with peak ZT values greater than 1.1 at 1,273 K. The high ZT of La 3-x Te 4 is in part due to a large peak in the density of states near the Fermi level from the La 5d states. Here, we revisit Pr 3−x Te 4 , for which our electronic structure calculations predict a favorable modification of the density of states by the introduction of praseodymium's 4f electrons. This was experimentally verified by preparing Pr 3−x Te 4 samples with varying Pr vacancy concentrations using a mechanochemical synthesis approach. The thermoelectric properties were measured and a ZT of 1.7 at 1,200 K was achieved with Pr 2.74 Te 4 . The 50% improvement in peak ZT compared with La 3−x Te 4 resulted from an increased effective mass, improved Seebeck coefficient, and lower thermal conductivity.
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- 2018
7. Investigation of (001), (010), and (100) surface termination and surface energies of the Zintl Ca5Ga2Sb6
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David M. Smiadak, Yue Qi, Alexandra Zevalkink, Jie Pan, and Monique N. Noel
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Materials science ,Intermetallic ,Ionic bonding ,Crystal growth ,Surfaces and Interfaces ,Condensed Matter Physics ,Surface energy ,Surfaces, Coatings and Films ,Crystal ,Crystallography ,Zintl phase ,Covalent bond ,Materials Chemistry ,Surface reconstruction - Abstract
Zintl Phases are a class of intermetallic compounds that combine ionic and covalent bonding to form charge-balanced structures, leading to semiconducting properties. The Ca5M2Sb6 family of Zintl compounds, (M =Al, Ga, In), have demonstrated promising thermoelectric efficiency, meaning they can be used to convert a temperature gradient into useful electrical energy. Ca5M2Sb6 compounds crystallize in a highly anisotropic structure comprised of chains of corner-linked MSb4 tetrahedra, in which each neighboring chain is joined via Sb-Sb covalent bonds, forming an infinite polyanionic “ladder”. In the present study, we used first principles calculations to study various surface terminations of the Ca5Ga2Sb6 structure as a mechanism to understand its crystal growth morphology. Our results indicate that the calcium stoichiometry of the crystal surface plays an important role in surface reconstruction, specifically leading to the formation or breaking of covalent bonds. Our results suggest that surface energy as a function of stoichiometry and crystallographic orientation is only one piece of the puzzle in understanding the growth habits of Ca5Ga2Sb6 crystals.
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- 2021
8. Publisher’s Note: 'Determination of single crystal elastic moduli of KTb3F10 by resonant ultrasound spectroscopy' [J. Appl. Phys 128, 165104 (2020)]
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Alexandra Zevalkink, Ashiwini Balodhi, Kelvin Chang, Susan M. Ennaceur, Albert Migliori, Kevin T. Stevens, and Sunil Kishore Chakrapani
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Resonant ultrasound spectroscopy ,Materials science ,Condensed matter physics ,General Physics and Astronomy ,Single crystal ,Elastic modulus - Published
- 2020
9. Determination of single crystal elastic moduli of KTb3F10 by resonant ultrasound spectroscopy
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Kevin T. Stevens, Albert Migliori, Alexandra Zevalkink, Ashiwini Balodhi, Kelvin Chang, Susan M. Ennaceur, and Sunil Kishore Chakrapani
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010302 applied physics ,Resonant ultrasound spectroscopy ,Materials science ,Condensed matter physics ,General Physics and Astronomy ,Crystal growth ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Debye frequency ,law.invention ,Thermal conductivity ,law ,Attenuation coefficient ,0103 physical sciences ,0210 nano-technology ,Faraday rotator ,Elastic modulus ,Single crystal - Abstract
KTb 3F 10 (KTF) has been developed in recent years as a candidate Faraday rotator material because of its cubic symmetry, high figures of merit, and low absorption coefficient. While considerable efforts have focused on crystal growth and optical properties, investigations of fundamental thermodynamic behavior of KTF have been limited. Here, we report elastic moduli C 11, C 12, and C 44 of single crystalline KTF measured by resonant ultrasound spectroscopy from 280 K up to 300 K and the obtained temperature derivatives of each modulus. We additionally report the single crystal elastic moduli of the rare-earth garnet Y 3Al 5O 12 (YAG), yielding results that agree well with the prior literature. We found C 11 = 135.62 GPa, C 12 = 58.11 GPa, and C 44 = 44.81 GPa for KTF and C 11 = 332.43 GPa, C 12 = 109.58 GPa, and C 44 = 114.81 GPa for YAG at room temperature. The present results have been compared with previous experimental and theoretical results and with common oxide and fluoride optical materials, revealing the relative softness of KTF. The low elastic moduli of KTF are, in turn, responsible for its low thermal conductivity and low Debye frequency compared to other laser host materials.
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- 2020
10. An unlikely route to low lattice thermal conductivity: small atoms in a simple layered structure
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Guido Petretto, Wanyue Peng, Gian-Marco Rignanese, Alexandra Zevalkink, and Geoffroy Hautier
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Resonant ultrasound spectroscopy ,Condensed Matter - Materials Science ,Materials science ,Condensed matter physics ,Phonon ,Anharmonicity ,Intermetallic ,Materials Science (cond-mat.mtrl-sci) ,FOS: Physical sciences ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Thermal expansion ,0104 chemical sciences ,3. Good health ,Condensed Matter::Materials Science ,General Energy ,Thermal conductivity ,Zintl phase ,Thermoelectric effect ,0210 nano-technology - Abstract
In the design of materials with low lattice thermal conductivity, compounds with high density, low speed of sound, and complexity at either the atomic, nano- or microstructural level are preferred. The layered compound Mg$_3$Sb$_2$ defies these prevailing paradigms, exhibiting lattice thermal conductivity comparable to PbTe and Bi$_2$Te$_3$, despite its low density and simple structure. The excellent thermoelectric performance ($zT$ $\sim$ 1.5) in $n$-type Mg$_3$Sb$_2$ has thus far been attributed to its multi-valley conduction band, while its anomalous thermal properties have been largely overlooked. To explain the origin of the low lattice thermal conductivity of Mg$_3$Sb$_2$, we have used both experimental methods and ab initio phonon calculations to investigate trends in the elasticity, thermal expansion and anharmonicity of $A$Mg$_2Pn_2$ Zintl compounds with $A$ = Mg, Ca, Yb, and $Pn$ = Sb and Bi. Phonon calculations within the quasi-harmonic approximation reveal large mode Gr\"uneisen parameters in Mg$_3$Sb$_2$ compared with isostructural compounds, in particular in transverse acoustic modes involving shearing of adjacent anionic layers. Measurements of the elastic moduli and sound velocity as a function of temperature using resonant ultrasound spectroscopy provide a window into the softening of the acoustic branches at high temperature, confirming their exceptionally high anharmonicity. We attribute the anomalous thermal behavior of Mg$_3$Sb$_2$ to the diminutive size of Mg, which may be too small for the octahedrally-coordinated site, leading to weak, unstable interlayer Mg-Sb bonding. This suggests more broadly that soft shear modes resulting from undersized cations provide a potential route to achieving low lattice thermal conductivity low-density, earth-abundant materials., Comment: 11 pages, 9 figures
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- 2018
11. High-Temperature Thermoelectric Properties of the Solid–Solution Zintl Phase Eu11Cd6Sb12–xAsx (x < 3)
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Saneyuki Ohno, G. Jeffrey Snyder, Susan M. Kauzlarich, Weiwei Xie, Alexandra Zevalkink, Nasrin Kazem, and Gordon J. Miller
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Condensed matter physics ,Chemistry ,General Chemical Engineering ,Fermi level ,General Chemistry ,Pearson symbol ,symbols.namesake ,Crystallography ,Zintl phase ,Electrical resistivity and conductivity ,Seebeck coefficient ,Thermoelectric effect ,Materials Chemistry ,symbols ,Solid solution ,Monoclinic crystal system - Abstract
Zintl phases are compounds that have shown promise for thermoelectric applications. The title solid–solution Zintl compounds were prepared from the elements as single crystals using a tin flux for compositions x = 0, 1, 2, and 3. Eu_(11)Cd_6Sb_(12–x)As_x (x < 3) crystallize isostructurally in the centrosymmetric monoclinic space group C2/m (no. 12, Z = 2) as the Sr_(11)Cd_6Sb_(12) structure type (Pearson symbol mC58). Efforts to make the As compositions for x exceeding ~3 resulted in structures other than the Sr_(11)Cd_6Sb_(12) structure type. Single-crystal X-ray diffraction indicates that As does not randomly substitute for Sb in the structure but is site specific for each composition. The amount of As determined by structural refinement was verified by electron microprobe analysis. Electronic structures and energies calculated for various model structures of Eu_(11)Cd_6Sb_(10)As_2 (x = 2) indicated that the preferred As substitution pattern involves a mixture of three of the six pnicogen sites in the asymmetric unit. In addition, As substitution at the Pn4 site opens an energy gap at the Fermi level, whereas substitution at the other five pnicogen sites remains semimetallic with a pseudo gap. Thermoelectric properties of these compounds were measured on hot-pressed, fully densified pellets. Samples show exceptionally low lattice thermal conductivities from room temperature to 775 K: 0.78–0.49 W/mK for x = 0; 0.72–0.53 W/mK for x = 1; and 0.70–0.56 W/mK for x = 2. Eu_(11)Cd_6Sb_(12) shows a high p-type Seebeck coefficient (from +118 to 153 μ V/K) but also high electrical resistivity (6.8 to 12.8 mΩ·cm). The value of zT reaches 0.23 at 774 K. The properties of Eu_(11)Cd_6Sb_(12–x)As_x are interpreted in discussion with the As site substitution.
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- 2014
12. Thermoelectric properties of the Yb9Mn4.2−xZnxSb9solid solutions
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Yoshiki Takagiwa, Saneyuki Ohno, G. Jeffrey Snyder, Alexandra Zevalkink, and Sabah K. Bux
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Materials science ,Effective mass (solid-state physics) ,Thermal conductivity ,Condensed matter physics ,Renewable Energy, Sustainability and the Environment ,Electrical resistivity and conductivity ,Interstitial defect ,Thermoelectric effect ,General Materials Science ,General Chemistry ,Crystal structure ,Thermoelectric materials ,Solid solution - Abstract
Yb9Mn4.2Sb9 has been shown to have extremely low thermal conductivity and a high thermoelectric figure of merit attributed to its complex crystal structure and disordered interstitial sites. Motivated by previous work which shows that isoelectronic substitution of Mn by Zn leads to higher mobility by reducing spin disorder scattering, this study investigates the thermoelectric properties of the solid solution, Yb9Mn4.2−xZnxSb9 (x = 0, 1, 2, 3 and 4.2). Measurements of the Hall mobility at high temperatures (up to 1000 K) show that the mobility can be increased by more than a factor of 3 by substituting Zn into Mn sites. This increase is explained by the reduction of the valence band effective mass with increasing Zn, leading to a slightly improved thermoelectric quality factor relative to Yb9Mn4.2Sb9. However, increasing the Zn-content also increases the p-type carrier concentration, leading to metallic behavior with low Seebeck coefficients and high electrical conductivity. Varying the filling of the interstitial site in Yb9Zn4+ySb9 (y = 0.2, 0.3, 0.4 and 0.5) was attempted, but the carrier concentration (∼1021 cm−3 at 300 K) and Seebeck coefficients remained constant, suggesting that the phase width of Yb9Zn4+ySb9 is quite narrow.
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- 2014
13. Lattice hardening due to vacancy diffusion in (GeTe)mSb2Te3 alloys
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Michael G. Boehlert, Donald T. Morelli, David M. Smiadak, Spencer Mather, Jared B. Williams, Alexandra Zevalkink, and Wanyue Peng
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010302 applied physics ,Resonant ultrasound spectroscopy ,Phase transition ,Materials science ,Condensed matter physics ,Transition temperature ,General Physics and Astronomy ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,01 natural sciences ,Vacancy defect ,0103 physical sciences ,Thermoelectric effect ,Hardening (metallurgy) ,0210 nano-technology ,Elastic modulus - Abstract
GeTe-Sb 2Te 3 alloys have been widely studied for use in rewritable media, and in recent years, they have emerged as excellent thermoelectric materials, with reports of zT>2 for Ge-rich compositions. GeTe-Sb 2Te 3 alloys exhibit a solid-state phase transition from a layered structure with rhombohedral symmetry to a cubic rocksalt structure, which plays an important role in their thermoelectric behavior. Here, we investigate the impact of the phase transition on the thermal expansion and elastic moduli of (GeTe) 17Sb 2Te 3 using high-temperature X-ray diffraction and resonant ultrasound spectroscopy. The high-temperature elastic moduli of GeTe, Sb2Te3, and Bi 2Te 3 were also measured for comparison. While it is typical for materials to soften with increasing temperature due to thermal expansion, our study reveals anomalous hardening of the elastic moduli in (GeTe) 17Sb 2Te 3 at temperatures below the phase transition, followed by further hardening at the transition temperature. In contrast, the elastic moduli of GeTe, Sb 2Te 3, and Bi 2Te 3 soften with increasing temperature. We attribute the anomalous hardening of (GeTe) 17Sb 2Te 3 to the gradual vacancy diffusion accompanying the transition from a layered to a cubic structure. The stiffening elastic moduli lead to increasing speed of sound, which impacts the lattice thermal conductivity by flattening the temperature dependence.
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- 2019
14. The Zintl Compound Ca5Al2Sb6 for Low-Cost Thermoelectric Power Generation
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Alexandra Zevalkink, G. Jeffrey Snyder, Nicole Crisosto, and Eric S. Toberer
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Materials science ,business.industry ,Band gap ,Doping ,Analytical chemistry ,Ionic bonding ,Condensed Matter Physics ,Thermoelectric materials ,Electronic, Optical and Magnetic Materials ,Biomaterials ,Semiconductor ,Thermal conductivity ,Electrical resistivity and conductivity ,Thermoelectric effect ,Electrochemistry ,business - Abstract
Understanding transport in Zintl compounds is important due to their unusual chemistry, structural complexity, and potential for good thermoelectric performance. Resistivity measurements indicate that undoped Ca_5Al_2Sb_6 is a charge-balanced semiconductor with a bandgap of 0.5 eV, consistent with Zintl–Klemm charge counting rules. Substituting divalent calcium with monovalent sodium leads to the formation of free holes, and a transition from insulating to metallic electronic behavior is observed. Seebeck measurements yield a hole mass of ∼2m_e, consistent with a structure containing both ionic and covalent bonding. The structural complexity of Zintl compounds is implicated in their unusually low thermal conductivity values. Indeed, Ca_5Al_2Sb_6 possesses an extremely low lattice thermal conductivity (0.6 W mK^(−1) at 850 K), which approaches the minimum thermal conductivity limit at high temperature. A single parabolic band model is developed and predicts that Ca_(4.75)Na_(0.25)Al_2Sb_6 possesses a near-optimal carrier concentration for thermoelectric power generation. A maximum zT > 0.6 is obtained at 1000 K.Beyond thermoelectric applications, the semiconductor Ca_5Al_2Sb_6 possesses a 1D covalent structure which should be amenable to interesting magnetic interactions when appropriately doped.
- Published
- 2010
15. Glass-like lattice thermal conductivity and high thermoelectric efficiency in Yb_9Mn_(4.2)Sb_9
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Jeffrey Snyder, David Uhl, Jean-Pierre Fleurial, Alexandra Zevalkink, Sabah K. Bux, Oliver Janka, and Susan M. Kauzlarich
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Materials science ,Condensed matter physics ,Renewable Energy, Sustainability and the Environment ,Band gap ,business.industry ,Analytical chemistry ,Primitive cell ,General Chemistry ,Thermal diffusivity ,Heat capacity ,Wavelength-dispersive X-ray spectroscopy ,Semiconductor ,Transition metal ,Thermoelectric effect ,General Materials Science ,business - Abstract
Motivated by excellent thermoelectric performance in the well-known Yb-based Zintl compounds Yb_(14)MnSb_(11) and YbZn_(2−x)Mn_xSb_2, this study investigates the thermoelectric properties of Yb_9Mn_(4.2)Sb_9. Unlike most transition metal containing Zintl phases, Yb_9Mn_(4.2)Sb)9 contains a partially occupied Mn site and thus does not have a valence-precise stoichiometry. Samples were synthesized by direct ball milling of the elements, followed by hot pressing. Consistent with previous reports, X-ray diffraction and wavelength dispersive spectroscopy confirmed a narrow composition range near Yb_9Mn_(4.2)Sb_9. High temperature measurements of the electronic properties of Yb_9Mn_(4.2)Sb_9 indicate that it is a degenerate p-type semiconductor with a band gap sufficiently large for high temperature thermoelectric applications. Hall measurements reveal that Yb_9Mn_(4.2)Sb_9 has a high extrinsic carrier concentration (~10^(20) h^+ cm^(−3)), which is due to the deviation from the theoretical “Zintl composition” of Yb_9Mn_(4.5)Sb_9. The measured carrier concentration coincides with the optimum concentration predicted using a single parabolic band model. Measurements of the thermal diffusivity and heat capacity reveal an extremely low, temperature-independent lattice thermal conductivity in this compound (κ_L < 0.4 W mK^(−1)), which is due to both the large unit cell size (44 atoms per primitive cell) and substantial disorder on the Mn site. This favorable combination of optimized electronic properties and low lattice thermal conductivity leads to a promising figure of merit at high temperature (zT = 0.7 at 950 K).
- Published
- 2014
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