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We combine experiments and numerical simulations to investigate the low energy states and the emergence of topological defects in an artificial colloidal ice in the Cairo geometry. This type of geometry is characterized by a mixed coordination ($z$), with coexistence of both $z=3$ and $z=4$ vertices. We realize this particle ice by confining field tunable paramagnetic colloidal particles within a lattice of topographic double wells at a one to one filling using optical tweezers. By raising the interaction strength via an applied magnetic field, we find that the ice rule breaks down, and positive monopoles with charge $q=+2$ accumulate in the $z = 4$ vertices and are screened by negative ones ($q=-1$) in the $z = 3$. The resulting, strongly coupled state remains disordered. Further, via analysis of the mean chirality associated to each pentagonal plaquette, we find that the disordered ensemble for this geometry is massively degenerate and it corresponds to a frustrated antiferrotoroid., Comment: 4 figures

Ordered mechanical systems typically have one or only a few stable rest configurations, and hence are not considered useful for encoding memory. Multistable and history-dependent responses usually emerge from quenched disorder, for example in amorphous solids or crumpled sheets. In contrast, due to geometric frustration, periodic magnetic systems can create their own disorder and espouse an extensive manifold of quasi-degenerate configurations. Inspired by the topological structure of frustrated artificial spin ices, we introduce an approach to design ordered, periodic mechanical metamaterials that exhibit an extensive set of spatially disordered states. While our design exploits the correspondence between frustration in magnetism and incompatibility in meta-mechanics, our mechanical systems encompass continuous degrees of freedom, and are hence richer than their magnetic counterparts. We show how such systems exhibit non-Abelian and history-dependent responses, as their state can depend on the order in which external manipulations were applied. We demonstrate how this richness of the dynamics enables to recognize, from a static measurement of the final state, the sequence of operations that an extended system underwent. Thus, multistability and potential to perform computation emerge from geometric frustration in ordered mechanical lattices that create their own disorder., Comment: Supplementarey video: https://youtu.be/9FKM54Lb5gU

The notion of magnetic monopoles has puzzled physicists since the introduction of Maxwell's Equations and famously Dirac had hypothesized them in the context of quantum mechanics. While they have proved experimentally elusive as elementary particles, the concept has come to describe excitations or topological defects in various material systems, from liquid crystals, to Hall systems, skyrmion lattices, and Bose-Einstein condensate. Perhaps the most versatile manifestation of magnetic monopoles as quasiparticles in matter has been in so-called spin ice materials. There, they represent violations of the ice rule, carry a magnetic charge, and can move freely unbound. Spin ice emergent magnetic monopoles appear at the atomic scale in rare earth pyrochlores or at the nano-scale in artificial spin ices systems. Here we demonstrate for the first time that the notion of magnetic monopoles can be transported at the macroscopic scale. We have built a mechano-magnet realized via 3D-printing, that consists of mechanical rotors on which macroscopic magnets can pivot. By controlling the relative height of the rotors we can achieve different regimes for magnetic monopoles, including the free monopole state. We then explore their driven dynamics under field. In the future, integration of our proof of principle in an elastic matrix can lead to novel macroscopic mechano-magnetic materials, to explore unusual piezomagnetism and magnetostriction, with applications to actuators and soft-robotics., Comment: 8 pages + supplementary material

In the last decade, nanoscale resistive devices with memory have been the subject of intense study because of their possible use in brain-inspired computing. However, operational endurance is one of the limiting factors in the adoption of such technology. For this reason, we discuss the emergence of current-induced memristance in magnetic materials, known for their durability. We show analytically and numerically that a single ferromagnetic layer can possess GHz memristance, due to a combination of two factors: a current-induced transfer of angular momentum (Zhang-Li torque) and the anisotropic magnetoresistance (AMR). We term the resulting effect the anisotropic magneto-memristance (AMM). We connect the AMM to the topology of the magnetization state, within a simple model of a 1-dimensional annulus-shaped magnetic layer, confirming the analytical results with micromagnetic simulations for permalloy. Our results open a new path towards the realization of single-layer magnetic memristive devices operating at GHz frequencies., Comment: 20 pages + supplementary material; 31 pages in total; 11 figures; Introduction: https://www.youtube.com/watch?v=WbUTtJq8FfM&feature=youtu.be

The concept of spin ice can be extended to a general graph. We study the degeneracy of spin ice graph on arbitrary interaction structures via graph theory. Via the mapping of spin ices to the Ising model, we clarify whether the inverse mapping is possible via a modified Krausz construction. From the gauge freedom of frustrated Ising systems, we derive exact, general results about frustration and degeneracy. We demonstrate for the first time that every spin ice graph, with the exception of the 1D Ising model, is degenerate. We then study how degeneracy scales in size, using the mapping between Eulerian trails and spin ice manifolds, and a permanental identity for the number of Eulerian orientations. We show that the Bethe permanent technique provides both an estimate and a lower bound to the frustration of spin ices on arbitrary graphs of even degree. While such technique can be used also to obtain an upper bound, we find that in all the examples we studied but one, another upper bound based on Schrijver inequality is tighter., Comment: 12 pages double column; result unchanged, paper clarified

Mechanical metamaterials present a promising platform for seemingly impossible mechanics. They often require incompatibility of their elementary building blocks, yet a comprehensive understanding of its role remains elusive. Relying on an analogy to ferromagnetic and antiferromagnetic binary spin interactions, we present a universal approach to identify and analyze topological mechanical defects for arbitrary building blocks. We underline differences between two- and three-dimensional metamaterials, and show how topological defects can steer stresses and strains in a controlled and non-trivial manner and can inspire the design of materials with hitherto unknown complex mechanical response.

Competing ground states may lead to topologically constrained excitations such as domain walls or quasiparticles, which govern metastable states and their dynamics. Domain walls and more exotic topological excitations are well studied in magnetic systems such as artificial spin ice, in which nanoscale magnetic dipoles are placed on geometrically frustrated lattices, giving rise to highly degenerate ground states. We propose a mechanical spin-ice constructed from a lattice of floppy, bistable square unit cells. We compare the domain wall excitations that arise in this metamaterial to their magnetic counterparts, finding that new behaviors emerge in this overdamped mechanical system. By tuning the ratios of the internal elements of the unit cell, we control the curvature and propagation speed of internal domain walls. We change the domain wall morphology from a binary, strictly spin-like regime, to a more continuous, elastic regime. In the elastic regime, we inject, manipulate, and expel domain walls via textured forcing at the boundaries. The system exhibits dynamical hysteresis, and we find a first-order dynamical transition as a function of the driving frequency. We demonstrate a forcing protocol that produces multiple, topologically-distinct steady cycles, which are protected by the differences in their internal domain wall arrangements. These distinct steady cycles rapidly proliferate as the complexity of the applied forcing texture is increased, thus suggesting that such mechanical systems could serve as useful model systems to study multistability, glassiness, and memory in materials., Comment: 15 pages, 14 figures

Geometric frustration and the ice rule are two concepts that are intimately connected and widespread across condensed matter. The first refers to the inability of a system to satisfy competing interactions in the presence of spatial constraints. The second, in its more general sense, represents a prescription for the minimization of the topological charges in a constrained system. Both can lead to manifolds of high susceptibility and non-trivial, constrained disorder where exotic behaviors can appear and even be designed deliberately. In this Colloquium, we describe the emergence of geometric frustration and the ice rule in soft condensed matter. This Review excludes the extensive developments of mathematical physics within the field of geometric frustration, but rather focuses on systems of confined micro- or mesoscopic particles that emerge as a novel paradigm exhibiting spin degrees of freedom. In such systems, geometric frustration can be engineered artificially by controlling the spatial topology and geometry of the lattice, the position of the individual particle units, or their relative filling fraction. These capabilities enable the creation of novel and exotic phases of matter, and also potentially lead towards technological applications related to memory and logic devices that are based on the motion of topological defects. We review the rapid progress in theory and experiments and discuss the intimate physical connections with other frustrated systems at different length scales.

We propose the first Skyrmion Spin Ice, realized via confined, interacting liquid crystal skyrmions. Skyrmions in a chiral nematic liquid crystal behave as quasi-particles that can be dynamically confined, bound, and created or annihilated individually with ease and precision. We show that these quasi-particles can be employed to realize binary variables that interact to form ice-rule states. Because of their unique versatility, liquid crystal skyrmions can open entirely novel avenues in the field of frustrated systems. More broadly, our findings also demonstrate the viability of LC skyrmions as elementary degrees of freedom in the design of collective complex behaviors., Comment: 5 pages,4 pictures

Artificial particle ices are model systems of constrained, interacting particles. They have been introduced theoretically to study ice-manifolds emergent from frustration, along with domain wall and grain boundary dynamics, doping, pinning-depinning, controlled transport of topological defects, avalanches, and memory effects. Recently such particle-based ices have been experimentally realized with vortices in nano-patterned superconductors or gravitationally trapped colloids. Here we demonstrate that, although these ices are generally considered equivalent to magnetic spin ices, they can access a novel spectrum of phenomenologies that are inaccessible to the latter. With experiments, theory and simulations we demonstrate that in mixed coordination geometries, entropy-driven negative monopoles spontaneously appear at a density determined by the vertex-mixture ratio. Unlike its spin-based analogue, the colloidal system displays a "fragile ice" manifold, where local energetics oppose the ice rule, which is instead enforced through conservation of the global topological charge. The fragile colloidal ice, stabilized by topology, can be spontaneously broken by topological charge transfer., Comment: 12 pages, 6 figures

While particle-based ices are often considered essentially equivalent to magnet-based spin ices, the two differ essentially in frustration and energetics. We show that at equilibrium particle-based ices correspond exactly to spin ices coupled to a background field. In trivial geometries, such a field has no effect, and the two systems are indeed thermodynamically equivalent. In other cases, however, the field controls a richer phenomenology, absent in magnetic ices, and still largely unexplored: ice rule fragility, topological charge transfer, radial polarization, decimation induced disorder, and glassiness., Comment: 5 pages, 5 figures

The low-energy physics of (quasi)degenerate one-dimensional systems is typically understood as the particle-like dynamics of kinks between stable, ordered structures. Such dynamics, we show, becomes highly non-trivial when the ground states are topologically constrained: a dynamics of the domains rather than on the domains which the kinks separate. Motivated by recently reported observations of charged polymers physisorbed on nanotubes, we study kinks between helical structures of a string wrapping around a cylinder. While their motion cannot be disentangled from domain dynamics, and energy and momentum is not concentrated in the solitons, the dynamics of the domains can be folded back into a one-particle picture., Comment: 5 pages 4 figures. Supplementary materials (animation): S1.mov, S2.mov, S3.mov

The inverse square potential arises in a variety of different quantum phenomena, yet notoriously it must be handled with care: it suffers from pathologies rooted in the mathematical foundations of quantum mechanics. We show that its recently studied conformality-breaking corresponds to an infinitely smooth winding-unwinding topological transition for the {\it classical} statistical mechanics of a one-dimensional system: this describes the the tangling/untangling of floppy polymers under a biasing torque. When the ratio between torque and temperature exceeds a critical value the polymer undergoes tangled oscillations, with an extensive winding number. At lower torque or higher temperature the winding number per unit length is zero. Approaching criticality, the correlation length of the order parameter---the extensive winding number---follows a Kosterlitz-Thouless type law. The model is described by the Wilson line of a (0+1) $U(1)$ gauge theory, and applies to the tangling/untangling of floppy polymers and to the winding/diffusing kinetics in diffusion-convection-reactions., Comment: 5 pages 2 figures

A theory for thermomechanical behavior of homogeneous DNA at thermal equilibrium predicts critical temperatures for denaturation under torque and stretch, phase diagrams for stable B--DNA, supercoiling, optimally stable torque, and the overstretching transition as force-induced DNA melting. Agreement with available single molecule manipulation experiments is excellent., Comment: 4 pages, 5 figures. Letter

The appearance of mathematical regularities in the disposition of leaves on a stem, scales on a pine-cone and spines on a cactus has puzzled scholars for millennia; similar so-called phyllotactic patterns are seen in self-organized growth, polypeptides, convection, magnetic flux lattices and ion beams. Levitov showed that a cylindrical lattice of repulsive particles can reproduce phyllotaxis under the (unproved) assumption that minimum of energy would be achieved by 2-D Bravais lattices. Here we provide experimental and numerical evidence that the Phyllotactic lattice is actually a ground state. When mechanically annealed, our experimental "magnetic cactus" precisely reproduces botanical phyllotaxis, along with domain boundaries (called transitions in Botany) between different phyllotactic patterns. We employ a structural genetic algorithm to explore the more general axially unconstrained case, which reveals multijugate (multiple spirals) as well as monojugate (single spiral) phyllotaxis., Comment: 9 Pages 11 Figures

A novel, protean, topological soliton has recently been shown to emerge in systems of repulsive particles in cylindrical geometries, whose statics is described by the number-theoretical objects of phyllotaxis. Here we present a minimal and local continuum model that can explain many of the features of the phyllotactic soliton, such as locked speed, screw shift, energy transport and, for Wigner crystal on a nanotube, charge transport. The treatment is general and should apply to other spiraling systems. Unlike e.g. Sine-Gornon-like systems, our solitons can exist between non-degenerate structure, imply a power flow through the system, dynamics of the domains it separates; we also predict pulses, both static and dynamic. Applications include charge transport in Wigner Crystals on nanotubes or A- to B-DNA transitions., Comment: 8 Pages, 6 Figures, Phys Rev E in press

While the statics of many simple physical systems reproduce the striking number-theoretical patterns found in the phyllotaxis of living beings, their dynamics reveal unusual excitations: multiple classical rotons and a large family of interconverting topological solitons. As we introduce those, we also demonstrate experimentally for the first time Levitov's celebrated model for phyllotaxis. Applications at different scales and in different areas of physics are proposed and discussed., Comment: Phys. Rev. Lett. accepted for publication

We analyze the rotational demagnetization of artificial spin ice, a recently realized array of nanoscale single-domain ferromagnetic islands. Demagnetization does not anneal this model system into its anti-ferromagnetic ground state: the moments have a static disordered configuration similar to the frozen state of the spin ice materials. We demonstrate that this athermal system has an effective extensive degeneracy and we introduce a formalism that can predict the populations of local states in this ice-like system with no adjustable parameters., Comment: 4 pages, 4 figures. Accepted by Phys Rev Lett