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Optical polaritons appear when a material excitation strongly couples to the optical mode. Such strong coupling between molecular transitions and optical cavities results in far-reaching opportunities in modifying fundamental properties of chemical matter. More recently an exciting prospect of cavity-free polaritons has emerged by matter sustaining the optical mode with its geometry. Here we show how strong coupling of the interband transition and surface plasmons can be engineered in nickel at the nanoscale to realize cavity-free optical polaritons inside metals. Using electron energy-loss spectroscopy, we demonstrate that in thin films and nanoantennas the propagation and radiation losses result in a broadening of the plasmon linewidth and a transition from strong to weak coupling. Further, higher-order plasmon resonances couple to the interband transition, and the multipolar coupled states acquire the field profile of the plasmon. Our results provide a fundamental understanding of plasmon-interband coupling in metals and establish the base for the design of unforeseen photocatalytic and magneto-optical nanosystems., Comment: 15 pages, 5 figures

Molecular polaritons are hybrid light-matter states that emerge when a molecular transition strongly interacts with photons in a resonator. At optical frequencies, this interaction unlocks a way to explore and control new chemical phenomena at the nanoscale. Achieving such a control at ultrafast timescales, however, is an outstanding challenge, as it requires a deep understanding of the dynamics of the collectively coupled molecular excitation and the nanoconfined electromagnetic fields. Here, we investigate the dynamics of collective polariton states, realized by coupling molecular photoswitches to optically anisotropic plasmonic nanoantennas. Pump-probe experiments reveal an ultrafast collapse of polaritons to a single-molecule transition triggered by femtosecond-pulse excitation at room-temperature. Through a synergistic combination of experiments and quantum mechanical modelling, we show that the response of the system is governed by intramolecular dynamics, occurring one order of magnitude faster with respect to the unperturbed excited molecule relaxation to the ground state.

The optical properties of some nanomaterials can be controlled by an external magnetic field, providing active functionalities for a wide range of applications, from single-molecule sensing to nanoscale nonreciprocal optical isolation. Materials with broadband tunable magneto-optical response are therefore highly desired for various components in next-generation integrated photonic nanodevices. Concurrently, hyperbolic metamaterials received a lot of attention in the past decade since they exhibit unusual properties that are rarely observed in nature and provide an ideal platform to control the optical response at the nanoscale via careful design of the effective permittivity tensor, surpassing the possibilities of conventional systems. Here, we experimentally study magnetic circular dichroism in a metasurface made of type-II hyperbolic nanoparticles on a transparent substrate. Numerical simulations confirm the experimental findings, and an analytical model is established to explain the physical origin of the observed magneto-optical effects, which can be described in terms of the coupling of fundamental electric and magnetic dipole modes with an external magnetic field. Our system paves the way for the development of nanophotonic active devices combining the benefits of sub-wavelength light manipulation in hyperbolic metamaterials supporting a large density of optical states with the ability to freely tune the magneto-optical response via control over the anisotropic permittivity of the system.

The quest to improve density, speed and energy efficiency of magnetic memory storage has led to exploration of new ways of optically manipulating magnetism at the ultrafast time scale, in particular in ferrimagnetic alloys. While all-optical magnetization switching is well-established on the femtosecond timescale, lateral nanoscale confinement and thus potential significant reduction of the size of the magnetic element remains an outstanding challenge. Here we employ resonant electromagnetic energy-funneling plasmon nanoantennas to influence the demagnetization dynamics of a ferrimagnetic TbCo alloy thin film. We demonstrate how Ag nanoring-shaped antennas under resonant optical femtosecond pumping reduce the overall magneto-optical response due to demagnetization in the underlying films up to three times compared to non-resonant illumination. We attribute such substantial reduction to the nanoscale confinement of the demagnetization process. This is qualitatively supported by the electromagnetic simulations that strongly evidence the optical energy-funneling to the nanoscale from the nanoantennas into the ferrimagnetic film. This is the first and defining step for reaching deterministic ultrafast all-optical magnetization switching at the nanoscale in such systems, opening a route to develop nanoscale ultrafast magneto-optics.

Nanometer-thin rare-earth-transition metal (RE-TM) alloys with precisely controlled compositions and out-of-plane magnetic anisotropy are currently in the focus for ultrafast magnetophotonic applications. However, achieving lateral nanoscale dimensions, crucial for potential device downscaling, while maintaining designable optomagnetic functionality and out-of-plane magnetic anisotropy is extremely challenging. Here we integrate nanosized Tb$_{18}$Co$_{82}$ ferrimagnetic alloys, having strong out-of-plane magnetic anisotropy, within a gold plasmonic nanoantenna array to design micrometer-scale a magnetophotonic crystal that exhibit abrupt and narrow magneto-optical spectral features that are both magnetic field and light incidence direction controlled. The narrow Fano-type resonance arises through the interference of the individual nanoantenna's surface plasmons and a Rayleigh anomaly of the whole nanoantenna array, in both optical and magneto-optical spectra, which we demonstrate and explain using Maxwell-theory simulations. This robust magnetophotonic crystal opens the way for conceptually new high-resolution light incidence direction sensors, as well as for building blocks for plasmon-assisted all-optical magnetization switching in ferrimagnetic RE-TM alloys., Comment: 13 pages, 4 figures

This Perspective surveys the state-of-the-art and future prospects of science and technology employing the nanoconfined light (nanophotonics and nanoplasmonics) in combination with magnetism. We denote this field broadly as nanoscale magnetophotonics. We include a general introduction to the field and describe the emerging magneto-optical effects in magnetoplasmonic and magnetophotonic nanostructures supporting localized and propagating plasmons. Special attention is given to magnetoplasmonic crystals with transverse magnetization and the associated nanophotonic non-reciprocal effects, and to magneto-optical effects in periodic arrays of nanostructures. We give also an overview of the applications of these systems in biological and chemical sensing, as well as in light polarization and phase control. We further review the area of nonlinear magnetophotonics, the semiconductor spin-plasmonics, and the general principles and applications of opto-magnetism and nano-optical ultrafast control of magnetism and spintronics.