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Large Nd1+xBa2-xCu3Oy (Nd123ss) single crystal cubes of side 3 mm were fabricated isothermally by the flux method. The crystals exhibited a Tc of 95 K with a sharp superconducting transition. One crystal was cut into small pieces, and its magnetic properties were measured to study the spatial distribution of the superconducting properties. It was found that although Tc values were almost constant, a small but significant intrinsic difference in the Jc-B properties and irreversibility field was observed depending on the sample position. This suggests that the distribution of Nd-rich Nd123ss clusters are spatially different even within the same single crystal. Such differences may be caused by the time variation of Nd concentration in the liquid during crystal growth.

The authors are investigating the possibility of using bulk magnets in the Maglev system. It is considered that bulk magnets for the Maglev system must be composed of numerous superconducting bulks arranged in rows and columns for each magnet pole because a bulk superconductor with a high critical current density doesn't have a sufficiently large size for Maglev magnet. Therefore, it is necessary to examine the flux-trapping characteristic of superconducting bulks arranged in array. Flux-trapping experiments are performed using the melt-processed YBaCuO superconducting bulks arranged in rows and columns, in which each bulk individually has a magnetizing coil, and the bulks are magnetized by field cooling. It is found that, when the superconducting bulks are arranged in rows and columns, the trapped flux density and the generated magnetic field are smaller than those when a superconducting bulk is used alone. The rate of decreases in the trapped flux density and the generated magnetic field becomes larger with increases in the number of superconducting bulks arranged in array. The trapped flux decreases conspicuously in particular at a superconducting bulk surrounded by other superconducting bulks.

Superconducting transitions are measured in field-cooled cooling (FCC) and field-cooled warming (FCW) modes in external magnetic fields ranging between 1 mT and 7 T on various high-T c superconductors (single crystal and melt-processed YBa2-Cu3O7-δ, single crystals and melt-processed NdBa2Cu3O7-δ, and on various ternary 123-superconductors). Our measurements reveal that a two step transition is observed if the sample exhibits also the secondary peak effect in the magnetization loops.

One of the applications of a bulk magnet in which flux is trapped in oxide superconducting bulks is a superconducting magnet for Maglev systems. We are investigating the possibility of using bulk magnets in Maglev systems. It is believed that bulk magnets far Maglev systems must be composed of superconducting bulks arranged in rows and columns for every pole, because a superconductor made of melt-processed Y-Ba-Cu-O with a high critical current density is smaller in size than the pole. Therefore, it is necessary to examine the flux-trapping characteristics of superconducting bulks in an array. Flux-trapping experiments are performed using melt-processed Y-Ba-Cu-O superconducting bulks arranged in rows and columns, in which each bulk has a magnetizing coil (an individual magnetization method) or all bulks have one magnetizing coil centered at outer bulks in an array (unified magnetization method), and the bulks are magnetized by field cooling. The magnetic field on the superconducting bulks arranged in an array is smaller than that of the single bulk arrangement because the magnetic field generated by the surrounding superconducting bulks acts to weaken the field of the surrounded suerconducting bulk. Furthermore, in the case of the individual magnetization method, the magnetic field applied is decreased during field cooling so that the trapped flux is smaller too. The rate of decrease in the individual magnetization method is larger than the rate of decrease in the unified magnetization method. It is clear that the unified magnetization method is more suitable than individual magnetization for magnetizing bulk magnets for aglev systems, which require a high magnetic field and large-scale system.

The angular dependence of the critical currents is investigated in a moderately twinned ${\mathrm{NdBa}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{7\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\delta}}}$ (NdBCO) single crystal in the temperature range $30l~Tl~90\mathrm{K}.$ In intermediate fields around the fishtail peak a reduction of critical current density due to twin structure is observed up to 90 K. This effect implies that vortices retain their three-dimensional character practically up to ${T}_{c}.$ The effect of twin planes disappeared at external fields declined more than $\ensuremath{\theta}\ensuremath{\approx}15\ifmmode^\circ\else\textdegree\fi{}$ from the $c$ axis (twin planes). In this case, the hysteresis loops exhibited a clear fishtail shape. The intermediate peak observed previously in NdBCO single crystal at $\ensuremath{\theta}=0\ifmmode^\circ\else\textdegree\fi{}$ is identified with the low-field limit of the twin plane activity.

Unlike Y123 which forms only a stoichiometric compound, the light rare earth elements (LREs: La, Nd, Sm, Eu, Gd) form a solid solution . The presence of such solid solution caused a depression in the superconducting transition temperatures , particularly for La123, Nd123 and Sm123 when they are melt processed in air. Recently, we have found that the of these LRE123 superconductors can greatly be enhanced when they are melt processed in a reduced oxygen atmosphere. Furthermore, values of these superconductors were larger than that of a good quality Y123 superconductor in high magnetic fields at 77 K. In this article, on the basis of our study over the last several years, the melt processes for LRE - Ba - Cu - O are described, the microstructural and superconducting properties of the superconductors are reviewed and the flux pinning mechanism is also discussed.

Induced current densities and magnetic relaxation rates were measured over a wide temperature and field range on a single crystal and a melt processed sample of using a SQUID magnetometer. The temperature dependence of the magnetic relaxation rate shows a pronounced minimum at elevated temperatures. This leads to very high values of the effective pinning energy and for the single crystal and the melt processed sample respectively, for an applied magnetic field . Furthermore, these samples show a well developed fishtail effect, leading to a current density . This demonstrates that the fishtail effect is closely related to the low relaxation rates observed here.

A reduced oxygen atmosphere during melt processing turned out to be critical for the fabrication of NdBa2Cu3Oy (Nd123) superconductors possessing high superconducting transition temperature (Tc) with a sharp transition and large critical current density (Jc) at 77 K. In a dc magnetization measurement, Nd123 superconductors melt processed in flowing a mixture gas of 1% O2 in Ar exhibited the Tc of about 95 K and the transition width of 1.5 K with the applied field of 10 Oe. A four‐probe measurement showed the zero resistive transition Tc (R=0) of about 95 K. An anomalous peak effect in the magnetization hysteresis (M‐H) loops was commonly observed and lead to large magnetic Jc of 2×104 A/cm2 at 77 K and 2 T for the applied field H parallel to the c axis of a sample (H∥c). This achievement is attributable to a preferential formation of high Tc phase (x

The effects of the second phase (Nd4Ba2Cu2Ox; Nd422) on the pinning property of Nd-Ba-Cu-O crystals have been studied. Hysteresis loops and magnetic relaxation were measured with a SQUID magnetometer. Critical current density (J s ) is obtained from the hysteresis loops using extended Bean model. The normalized relaxation rate (S) and the apparent pinning energy (U*0) are deduced from the relaxation data using Anderson-Kim model. It was found that J c -B curves and U*0-B curves are strongly dependent on the volume fraction of Nd422 phase, like Y211 phase with Y-Ba-Cu-O system.

Critical current density J c of Nd1+xJBa2-xCu3Oy (Nd123) single crystals flux-grown under the Oxygen-Controlled-Melt-Growth (OCMG) process has been investigated using DC magnetization measurements. The superconducting transition temperature T c of a Nd123 single crystal flux-grown using a 0.1% O2 — Ar gas in a zirconia crucible was 94 K. Using a magneto-optical observation method, the sample was found to be free of weakly-linked regions. DC magnetization hysteresis curves exhibited an anomalous peak effect in the high temperature range. This behavior is attributable to a field-induced pinning by finely-distributed low T c phases in the high T c matrix. J c calculation using the extended Bean model resulted in high J c of about 4 × 104 A/cm2 under 2 T and over 1 × 104 A/cm2 under 4 T at 77 K.

REBa2Cu3Oy superconductors with rare earth (RE) ions with large radii (RE: La, Nd, Sm, Eu) exhibit relatively low T c due to the presence of RE-Ba solid solution. We have found that this solid solution can be suppressed if these superconductors are melt processed in a reduced oxygen atmosphere. We have also found that critical current densities of these superconductors are higher than those of melt processed YBa2Cu3Oy with fine Y2BaCuO5 inclusions in a high field region. The irreversibility line was also shifted toward the higher H-T region. We believe that flux pinning in these superconductors is ascribable to a finely distributed RE(Ba1−x,REx)2Cu3Oy phase in a good superconductive matrix.

Since High-Tc superconductors such as Y-system and Bi-system show perfect diamagnetism at above 90 K, it is expected that a magnetic field will be shielded by superconductors cooled with liquid nitrogen. In this study, magnetic shielding effect of superconducting YBaCuO disks prepared by melt processes was measured at 77K. The results indicate that disk samples with ~16 mm in diameter and ~ 1 mm in thickness can reduce an external magnetic field in intermediate field range, but that the magnetic flux comes in through grainboundaries and cracks of the sample.

A surface acoustic wave element includes a single crystal substrate; a buffer layer formed by a crystal film that is formed on top of the single crystal substrate; and a piezoelectric thin film having a hexagonal system or a trigonal system crystal structure that is formed on top of the buffer layer. The surface acoustic wave element has an improved performance by improving the film quality of the piezoelectric thin film. In addition, because a semiconductor device can be formed on the single crystal substrate, the surface acoustic wave element can be integrated with the semiconductor device. Moreover, leakages of surface acoustic waves into the single crystal substrate are prevented. There are also provided a frequency filter, an oscillator, an electronic circuit, and an electronic instrument that are provided with this surface acoustic wave element.

Magnetization properties by a pulsed magnetic field were studied in YBaCuO superconductors prepared by the Melt-Powder-Melt-Growth (MPMG) process. The sample size was 10 mm × 10 mm × 1 mm. A pulsed magnetic field of up to 2.3 T was applied perpendicular to the sample surface at 77 K. Two-dimensional distributions of the trapped magnetic field over the YBaCuO sample surface were measured at 77 K by a scanning Hall sensor. A maximum magnetic field of 0.15 T was trapped. The maximum trapped magnetic field increased with an increasing applied magnetic field, and showed a peak. Then the trapped field decreased with a further increasing pulsed magnetic field.

The effects of various oxygen partial pressures (P O2) during melt processing on the superconducting properties of fabricated NdBa2Cu3O y (Nd123) superconductors have been systematically investigated. Unlike in air or O2, samples melt-processed in reduced oxygen atmospheres exhibited unprecedentedly high T c's of 95–96 K with a sharp superconducting transition. Especially, for a sample melt-processed in 0.1% O2 in Ar, the magnetization hysteresis ( M-H ) loop was kept open up to 7 T at 77 K and for the field parallel to the c-axis of the sample (H//c), implying that very effective flux pinning can be achieved in high magnetic fields.

REBa2Cu3O y superconductors with rare earth (RE) ions with large radii (RE: La, Nd, Sm) exhibit relatively low T c due to the presence of RE-Ba solid solution. We have found that this solid solution can be suppressed if these superconductors are melt processed in a reduced oxygen atmosphere. We have also found that critical current densities of these superconductors are higher than those of melt processed YBa2Cu3O y with fine Y2BaCuO5 inclusions in a high field region. The irreversibility line was also shifted toward the higher H-T region. We believe that flux pinning in these superconductors is ascribable to a finely distributed RE(Ba1- x , RE x )2Cu3O y phase in a good superconductive matrix.