1. Unconventional magnetism in the 4d4 -based S=1 honeycomb system Ag3LiRu2O6
- Author
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M. Prinz-Zwick, R. Kumar, Kannadka Ramesha, T. Dey, J. C. Orain, N. Büttgen, S. Kundu, A. V. Mahajan, Philipp Gegenwart, C. Baines, A. A. Gippius, P. M. Ette, Indra Dasgupta, Sándor Tóth, Atasi Chakraborty, and Aga Shahee
- Subjects
Physics ,Spins ,Condensed matter physics ,Magnetism ,02 engineering and technology ,Electronic structure ,021001 nanoscience & nanotechnology ,01 natural sciences ,Magnetic susceptibility ,Heat capacity ,Lattice (order) ,0103 physical sciences ,Antiferromagnetism ,Condensed Matter::Strongly Correlated Electrons ,010306 general physics ,0210 nano-technology ,Monoclinic crystal system - Abstract
We have investigated the thermodynamic and local magnetic properties of the Mott insulating system Ag$_{3}$LiRu$_{2}$O$_{6}$ containing Ru$^{4+}$ (4$d$$^{4}$) for novel magnetism. The material crystallizes in a monoclinic $C2/m$ structure with RuO$_{6}$ octahedra forming an edge-shared two-dimensional honeycomb lattice with limited stacking order along the $c$-direction. The large negative Curie-Weiss temperature ($\theta_{CW}$ = -57 K) suggests antiferromagnetic interactions among Ru$^{4+}$ ions though magnetic susceptibility and heat capacity show no indication of magnetic long-range order down to 1.8 K and 0.4 K, respectively. $^{7}$Li nuclear magnetic resonance (NMR) shift follows the bulk susceptibility between 120-300 K and levels off below 120 K. Together with a power-law behavior in the temperature dependent spin-lattice relaxation rate between 0.2 and 2 K, it suggest dynamic spin correlations with gapless excitations. Electronic structure calculations suggest an $S = 1$ description of the Ru-moments and the possible importance of further neighbour interactions as also bi-quadratic and ring-exchange terms in determining the magnetic properties. Analysis of our $\mu$SR data indicates spin freezing below 5 K but the spins remain on the borderline between static and dynamic magnetism even at 20 mK.
- Published
- 2019
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