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1. Low temperature activation of benzylic CH bonds with heterogeneous Fe/MgO catalyst under atmospheric molecular oxygen

Author

Seong-Hoon Cho, Chul Sung Kim, Min Serk Cheong, Kwang-Deog Jung, and Sung-Hwan Han

Subjects
Chemistry, Magnesium, Process Chemistry and Technology, Inorganic chemistry, Oxygene, Acetaldehyde, chemistry.chemical_element, Photochemistry, Heterogeneous catalysis, Oxygen, Catalysis, chemistry.chemical_compound, Molecular oxygen, computer, computer.programming_language
Abstract

The room temperature benzylic oxidation was performed with Fe/MgO catalyst. This Fe/MgO catalyst was prepared by the dissolution-precipitation method. This heterogeneous catalyst, Fe/MgO, activated the CH bond with atmospheric molecular oxygen even at 10 °C; its catalytic activity was greatly enhanced by the addition of N-hydroxyphthalimide (NHPI) and/or acetaldehyde.

Published
2004
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