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Thermosets and composites were prepared from blends of epoxidized waste vegetable oils and diglycidyl ether of bisphenol-A to investigate this material as an alternative triglyceride source for epoxy resins. Purification of the waste oil was developed to remove impurities derived from thermal degradation in the frying process and different epoxidation methodologies were investigated. Effects of epoxidized vegetable oil content (up to 30 wt%) and origin on the tensile properties were studied and revealed that purified waste oils performed similarly to neat oil in contents up to 10 wt%, proving that this strategy does not compromise tensile properties when waste oils are used in suitable proportions. Furthermore, a more prominent plasticizing effect was observed when more than 15 wt% of bio-based resin was used as confirmed by DMA. Composites were prepared with recycled carbon fibres (up to 30 wt%) and thermosets with 10 wt% of bio-based epoxy resins, significantly improving the mechanical properties. [ABSTRACT FROM AUTHOR]

Carbon fibre epoxy composites are sought after for their excellent specific energy absorption (SEA) but are costly. A range of prepreg carbon fibre epoxy layups were subjected to a 10 m/s impact with 4 kJ of energy. Fibre volume fraction and voidage were determined for each sample and the fracture analysed in detail. SEA ranged from 35.27 J/g to 60.25 J/g with the highest performance from 8 plies of 200 gsm 2 × 2 twill all laid at 0°. Vacuum assisted oven cure resulted in higher voidage than autoclave cure (2.52% versus 0.17%) but did not affect SEA. According to a ratio of performance to cost the highest rated samples were an 8 ply oven cure and a 3 ply autoclave cure specimen and there was little difference between them. This work has highlighted that there is enormous potential for cost reduction of prepreg carbon fibre epoxy energy absorption structures through the use of heavier areal weight fabrics and fewer plies as well as through the use of oven cured prepreg. [ABSTRACT FROM AUTHOR]

Abstract: Fibre reinforced composites have excellent specific properties and are widely sought after by engineers seeking to reduce mass. However, end of life disposal is a significant problem and so research into more sustainable natural fibre composites is extremely topical. This paper examines the applicability of natural fibre composites for high performance structural applications. Woven flax and regenerated cellulose (Cordenka) textiles were pre-impregnated with commercially available epoxy resins and consolidated into test laminates in an autoclave to determine their static (compressive, tensile, flexural) and dynamic (energy absorption) properties. The range of compressive strengths was 77.5–299.6MPa. Tensile strengths ranged from 63 to 92.6MPa and interlaminar shear strength (ILSS) from 10.7 to 23.3MPa. Specific energy absorption (SEA) varied between 21.2–34.2kJ/kg. Biotex flax combined with MTM49 resin matched the SEA of T300 carbon fibre using the same resin system and layup. This work has demonstrated that natural fibre composites have significant scope for use in structural applications but additional work is required on fibre to matrix bonding in order to maximise their properties whilst remaining an environmentally credible option. [Copyright &y& Elsevier]

Abstract: This study was designed to ascertain if the addition of lignin to hemp-epoxy composites was beneficial to their mechanical properties. Composites were made using a VARTM method with a two-part epoxy resin and a non-woven hemp fibre mat. Lignin was added to the resin before infusion at concentrations varying between 0 and 10% w/w. Samples were then tested according to the relevant ISO standards. There was an increase in impact properties of the fabricated composites with the energy absorbed by the composite containing 5% w/w lignin being 145% higher than the composite with no lignin added. Both flexural and tensile modulus showed an increase when lignin was added up to 2.5% w/w, although there was a drop in both when the lignin was increased to 5% w/w, attributed to poor mixing and infusion due to the increased viscosity of the resin. In all cases, the addition of lignin increased the structural properties of the composites to some degree when compared with composites with no additional lignin. [Copyright &y& Elsevier]

Abstract: This paper examines the possibilities of using an established energy crop; Miscanthus giganteus as a filler/reinforcement in injection mouldable thermoplastic composites utilising a starch-based biopolymer; Novamont Mater-Bi as the matrix. A design of experiments methodology was used to reveal how varying the processing parameters and material formulation affected the impact performance of the biocomposite. The addition of Miscanthus fibres to the polymer results in composites with higher impact absorbance and loading than those of standard Mater-Bi. [Copyright &y& Elsevier]