Search

In order to meet the requirements of high corrosion resistance, wear resistance, and self-lubrication of composite coatings for marine applications, epoxy matrix composite coatings containing PTFE and TiO2 nanoparticles were prepared on the steel substrate. With silane coupling agent KH570 (CH2=C(CH3)COOC3H6Si(OCH3)3), titanium dioxide nanoparticles were modified, and organic functional groups were grafted on their surface to improve their dispersion and interface compatibility in the epoxy matrix. Then, the section morphology, tribological, and anticorrosion properties of prepared coatings, including pure epoxy, epoxy&ndash, PTFE, and the composite coating with unmodified and modified TiO2, respectively, were fully characterized by scanning electron microscopy, friction&ndash, abrasion testing machine, and an electrochemical workstation. The analytical results show that the modified TiO2 nanoparticles are able to improve the epoxy&ndash, PTFE composite coating&rsquo, s mechanical properties of epoxy&ndash, PTFE composite coating including section toughness, hardness, and binding force. With the synergistic action of the friction reduction of PTFE and dispersion enhancement of TiO2 nanoparticles, the dry friction coefficient decreases by more than 73%. Simultaneously, modified titanium dioxide will not have much influence on the water contact angles of the coating. A larger water contact angle and uniform and compact microstructure make the composite coating incorporated modified TiO2 nanoparticles show excellent anti-corrosion ability, which has the minimum corrosion current density of 1.688 &times, 10&minus, 7 A&middot, cm&minus, 2.

Purpose The purpose of this paper is to improve binding force between the coating and the steel substrate by using chemical modification on the steel surface; at the same time, it can also increase the corrosion resistance of the coating. Design/methodology/approach The main components of the conversion film include tannic acid, sodium molybdate and silane coupling agent KH560. After the preparation was completed, the samples were tested and analyzed, including surface morphology, conversion film components, bonding force with organic resins and corrosion resistance. Finally, it drew a conclusion that the conversion film can greatly improve the bonding strength of the steel substrate and epoxy resin. Findings When the content of tannic acid is 4 g/L meanwhile the content of KH560 is 20 g/L, the conversion film has the strongest binding force with epoxy resin, from 2.15 Mpa of untreated steel to 4.60 Mpa, growth of 140 per cent. At the same time, the resulting conversion film also improves the corrosion resistance of the steel surface by a small margin. Originality/value A method of enhancing the bond between an epoxy coating and steel is provided. Verify the mechanism of this method.

The aim of this paper is to obtain Cu&ndash, Sn composite coatings incorporated with PTFE and TiO2 particles, which have superior antiwear and friction reduction properties. Electrodeposition was carried out in a pyrophosphate electrolyte, and the electrochemical behavior of the plating solutions was estimated. PTFE emulsion and TiO2 sol were prepared and used, of which the average particle sizes were less than 283 and 158 nm, respectively. Then, four different types of coatings, Cu&ndash, Sn, Cu&ndash, Sn&ndash, TiO2, Cu&ndash, PTFE and Cu&ndash, PTFE&ndash, TiO2, were electroplated with a pulsed power supply. Their microstructure, composition, microhardness, corrosion resistance and tribological properties were then analyzed and compared in detail. The results show that both PTFE and TiO2 are able to improve coating structure and corrosion resistance, while they have different effects on hardness and tribological properties. However, the presence of both PTFE and TiO2 in the deposited coating leads to a lower friction coefficient of 0.1 and higher wear and corrosion resistance.