All graphs under consideration are finite, simple, connected, and undirected. Adjacency matrix of a graph G is 0,1 matrix A = a i j = 0 , i f v i = v j o r d v i , v j ≥ 2 1 , i f d v i , v j = 1. . Here in this paper, we discussed new type of adjacency matrix known by 1-2 adjacency matrix defined as A 1,2 G = a i j = 0 , i f v i = v j o r d v i , v j ≥ 3 1 , i f d v i , v j = 2 , from eigenvalues of the graph, we mean eigenvalues of the 1-2 adjacency matrix. Let T n c be the set of the complement of trees of order n . In this paper, we characterized a unique graph whose least eigenvalue is minimal among all the graphs in T n c .