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Start Over Author "German, Ian" Topic cobalt -- physiological effect
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1. Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers.

Author

Demarteau, Jérémy, Kermagoret, Anthony, German, Ian, Cordella, Daniela, Robeyns, Koen, De Winter, Julien, Gerbaux, Pascal, Jérôme, Christine, Debuigne, Antoine, and Detrembleur, Christophe

Subjects
COBALT -- Physiological effect, ACETYL compounds, POLYMERIZATION, POLYMER spectra, SPECTRUM analysis
Abstract

Novel organocobalt complexes featuring weak C–CoL2 bonds (L = acetylacetonate) are prepared and used as sources of halomethyl radicals. They permit the precision synthesis of α-halide functionalized and telechelic polymers in organic media or in water. Substitution of halide by azide allows derivatization of polymers using the CuAAC click reaction. [ABSTRACT FROM AUTHOR]

Published
2015
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