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The characteristics and heterogeneity of coal pores are crucial for understanding the production mechanism of coalbed methane (CBM). In this study, coal samples with varying degrees of metamorphism (0.58% ≤ RO, max ≤ 3.44%) were collected. The characteristics of pore development and the heterogeneous properties of pores were revealed through low-temperature nitrogen adsorption (LTNA) and low-field nuclear magnetic resonance (NMR) experiments. The results indicate that pores with varying diameters exhibit favorable development in low-rank coals, along with favorable pores connectivity. The micropores composition of middle-rank coals was found to be 73.56%, however, the connectivity among transitional, meso, and macropores was observed to be poor. In high-rank coals, the proportion of micropores was 92.74%, with numerous micropores being closed or semi-closed. This resulted in inferior connectivity between micropores and transitional pores. As coal metamorphism progressed, the DL1 (characterizing the roughness of adsorption pores (AP) surface, ranging from 2.13 to 2.45) and DL2 (characterizing the complexity of AP structure, ranging from 2.56 to 2.77) initially decreased and then increased, whereas the DN (characterizing the heterogeneity of seepage pores (SP), ranging from 2.92 to 2.95) consistently improved. Furthermore, the roughness of pore surface and the complexity of pore structure in AP increased as the specific surface area and volume of pores increased. On the contrary, as the SP content increased, the uniformity of the pore structure improved. When the volume of SP remained constant, the complexity of the pore structure decreased due to increased pore connectivity. [ABSTRACT FROM AUTHOR]

The development of the coal pore system is extremely significant for gas disaster prevention in coal mines and coalbed methane exploitation. To accurately, quantifiable, and non-destructively characterize the coal pore system, the relationship between total porosity, effective porosity, pore size distribution, and resistivity of coals with different degrees of metamorphic was studied by resistance test and low field NMR techniques. The dimensionless parameter ρP that characterize the coal pore system was defined by the variety of resistivity in dry and saturated conditions. The achieved results are presented as follows: (1) The greater the ρP (the influence of the coal pore system on the conductivity), the larger the total porosity; (2) The proportion of effective pores increased linearly with the addition of the ρP; (3) The proportion of micropores and small pores decreased linearly as the ρP increased, revealed that these pores had poor connectivity and complicated structure, and had a significant negative effect on the conductivity of saturated coal. (4) The proportion of mesopores and macropores gained linearly as the ρP increased, indicated these pores had well connectivity, and had a positive influence on the conductivity. The results showed that the variety of coal resistivity from dry to the saturated condition was mainly controlled by the pore system. Therefore, a new method to characterize the coal pore system was proposed, which was exceedingly effectively, conveniently, and non-destructively. [ABSTRACT FROM AUTHOR]