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Over the past few decades, the oceans have stored the majority of the excess heat in the climate system resulting from anthropogenic emissions. An accurate, long-term sea surface temperature (SST) dataset is essential for monitoring and researching the changes to the global oceans. A variety of SST datasets have been produced by various institutes over the years, and here, we present a new SST data record produced originally within the Copernicus Marine Environment Monitoring Service (which is therefore named CMEMS v2.0) and assess: (1) its accuracy compared to independent observations; (2) how it compares with the previous version (named CMEMS v1.2); and (3) its performance during two major volcanic eruptions. By comparing both versions of the CMEMS datasets using independent in situ observations, we show that both datasets are within the target accuracy of 0.1 K, but that CMEMS v2.0 is closer to the ground truth. The uncertainty fields generated by the two analyses were also compared, and CMEMS v2.0 was found to provide a more accurate estimate of its own uncertainties. Frequency and vector analysis of the SST fields determined that CMEMS v2.0 feature resolution and horizontal gradients were also superior, indicating that it resolved oceanic features with greater clarity. The behavior of the two analyses during two volcanic eruption events (Mt. Pinatubo and El Chichón) was examined. A comparison with the HadSST4 gridded in situ dataset suggested a cool bias in the CMEMS v2.0 dataset versus the v1.2 dataset following the Pinatubo eruption, although a comparison with sparser buoy-only observations yielded less clear results. No clear impact of the El Chichón eruption (which was a smaller event than Mt. Pinatubo) on CMEMS v2.0 was found. Overall, with the exception of a few specific and extreme events early in the time series, CMEMS v2.0 possesses high accuracy, resolution, and stability and is recommended to users. [ABSTRACT FROM AUTHOR]