Giroudon, Marie, Patapy, Cédric, Peyre Lavigne, Matthieu, Andriamiandroso, Mialitiana, Cartier, Robin, Bacquié, Céline, Dubos, Simon, André, Ludovic, Pommier, Sébastien, Lefevbre, Xavier, Cyr, Martin, Bertron, Alexandra, Laboratoire Matériaux et Durabilité des constructions (LMDC), Institut National des Sciences Appliquées - Toulouse (INSA Toulouse), Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT), Toulouse Biotechnology Institute (TBI), Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), and Ecocem
International audience; Anaerobic digestion, a renewable energy source, is the degradation of organic waste into biogas, mainly composed of CH4 and CO2. The sector is expanding rapidly due to its multiple environmental and economic benefits. This process is implemented industrially in concrete structures that are in direct contact with the biowaste being digested and the gas produced. Both phases can damage concrete through (i) the presence of volatile fatty acids, dissolved CO2, ammonium, and microbial biofilm in the liquid phase, and (ii) high concentrations of CO2 and various concentrations of H2S in the gas phase. In order to develop more sustainable concrete biogas units, long-term, in-situ experiments were carried out in a semi-industrial scale digester to provide new insights into the performance levels and deterioration mechanisms of various low-CO2 binders, including alkali-activated metakaolin (geopolymer), alkali-activated slag (AAS), and supersulfated cements (SSC), in comparison to calcium aluminate cement (CAC) and Portland cement based matrices. In the running conditions explored, carbonation of the cementitious matrices was predominant over other deterioration phenomena in both the digester liquid and the gas phases. Alkali-activated metakaolin and calcium aluminate cement performed better with few degradations observed. Supersulfated cements and alkali-activated slag showed an intermediate behaviour with good performance in the acidic liquid phase but low performance in the CO2-rich gas phase.