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Start Over Author "Huang, Hua-Qi" Topic chirality
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1. The synthesis and chiral crystal structures of two enantiomers of a Ag helical coordination polymer based on argentophilicity.

Author

Zhang, Ting, Huang, Hua-Qi, Cheng, Xiao-Yue, Guo, Dong, Mei, Hong-Xin, Huang, Rong-Bin, and Zheng, Lan-Sun

Subjects
*ENANTIOMERS analysis, *CHIRALITY, *CRYSTAL structure, *COORDINATION polymers, *HELICITY (Chemistry)
Abstract

Achiral ligand- and Ag(i)-driven spontaneous resolution occurred simultaneously in the formation of two enantiomers 1P and 1M of [Ag2(5-nip)(mpyz)] (5-nip = 5-nitroisophthalic, mpyz = 2,3,5,6-tetramethylpyrazine), whose absolute sense of a helix made of achiral components is induced by the metal Ag(i) through argentophilic interactions. [ABSTRACT FROM AUTHOR]

Published
2016
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