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This work aims at discovering the potential of CO2 reduction by implementing techniques of process intensification in the production processes of green alternative fuel, dimethyl ether (DME), from CO2 and renewable hydrogen (H2) with both one-step and two-step configurations. A novel intensified process using the two-step configuration (named as TSHI), which converts CO2 to methanol followed by the dehydration of methanol to DME, is proposed in this study. Developed based on the validated thermodynamic representation and the reaction kinetics expression, TSHI shows the greatest potential of CO2 reduction – 1.704 ton CO2/ton DME – among the five discussed process scenarios. TSHI’s energy consumption per unit weight of DME is compared with reported case in the literature, which also uses CO2 and renewable H2 as feedstock in a two-step configuration, and the result has shown an energy saving amount of 23%. Though TSHI exhibits high capability of reducing CO2 amount in the atmosphere, the result of techno-economic analysis showed that there are still rooms for further improvements to produce green alternative fuel cost-effectively.

Timber harvesting is an activity in producing wood to supply the lumber industry. However, timber harvesting brought consequences such as decreasing carbon sequestration potential of natural forests. This study aimed to determine the reduction in the potential for carbon sequestration due to timber harvesting in natural forests. Data were collected using non-destructive methods through stand inventory before felling for all tree species, cruising results report, and tree distribution maps. Biomass was calculated using the existing allometric, and carbon stocks were calculated using the Intergovernmental Panel on Climate Change method. The results showed that there were 238 trees (65.29 m3) of stands in the study area (6 ha) based on stand inventory before felling. Potential biomass and carbon storage before trees felling were 16.12 ton ha-1 and 7.58 ton ha-1, respectively. Potential biomass and carbon storage after tree felling were 5.15 ton ha-1 and 2.42 ton ha-1, respectively. Carbon absorption before and after tree felling is 28.37 ton CO2eq ha-1 and 4.44 ton CO2eq ha-1, respectively. Carbon emissions during tree felling was 18.93 ton CO2eq ha-1 (81.00%). The application of environmentally friendly wood harvesting shall be carried out appropriately to minimize a decrease in carbon absorption from timber harvesting. Keywords: biomass, carbon emission, timber harvesting

Continuous catalytic naphtha reformers are one of the main refinery units producing hydrogen. Reliable and comprehensive modeling of such a complex and integrated refinery unit plays a pivotal role in optimization to increase the efficiency of the process. A reaction network with 26 pseudo components and 58 reactions, considering coke formation and catalyst activity, was proposed to predict the outlet compositions of reactors in more detail. The whole unit, including reaction and purification sections, was simulated to cover all products. NOMAD optimizer, with the mesh adaptive direct search algorithm, is used to minimize energy costs. Non-linear constraints were defined to guarantee the quality of the final products. The optimized decision variables reduced the energy cost by 13.5%, mainly caused by a significant decline in natural gas consumption. The simulation also indicated an increase of 4800 ton/y in reformate production, which the product is rich in aromatics. By contrast, LPG, hydrogen-rich gas, and coke production dropped by nearly 4355, 321, and 127 ton/y, respectively. The coke production decline can significantly increase the catalyst lifetime and decrease the operating cost of the catalyst regeneration unit.

Monazite is a phosphate mineral that contains thorium (Th) and rare earth elements. The Th concentration in monazite can be as high as 500 ppm, and it has the potential to be used as fuel in the nuclear power system. Therefore, this study aimed to conduct the techno-economic analysis (TEA) of Th extraction in the form of thorium oxide (ThO2) from monazite. Th can be extracted from monazite through an alkaline fusion method. The TEA of ThO2 production studied parameters, including raw materials, equipment costs, total plant direct and indirect costs, and direct fixed capital cost. These parameters were calculated for the production of 0.5, 1, and 10 ton ThO2 per batch. The TEA study revealed that the highest production cost was ascribed to installed equipment. Furthermore, the highest return on investment (ROI) of 21.92% was achieved for extraction of 1 ton/batch of ThO2, with a payback time of 4.56 years. With further increase in ThO2 production to 10 ton/batch, the ROI was decreased to 5.37%. This is mainly due to a significant increase in the total capital investment with increasing ThO2 production scale. The minimum unit production cost was achieved for 1 ton ThO2/batch equal to 335.79 $/Kg ThO2.

Ferrochromium production is a highly energy-intensive process, consuming between 3000 and 4000 kWh for producing one ton of ferrochrome alloy. The alloy produced contains chromium, iron as a princi...

One of the primary constraints in upland rice cultivation is the disease blast (Magnaporthe oryzae), which can provide reduction up to 100% of the grain yield The use of silicon with benefi cial microorganisms (bioagents) can be an alternative for the control of this disease and to provide an increase in the productivity of the rice grain. The objective of this work was to study the eff ect of rates of silicon with bioagents in blast suppression and grain yield of upland rice. The methodology used was tests carried out in field conditions, in two different areas: Capivara and Palmital farms, during the growing season 2015/2016. The experimental design was in a split-plot scheme with four replications. In the main plots were the silicon fertilization rates (0, 2, 4 and 8 ton ha-1) and in the subplots was the bioagents (1-without bioagents, 2-Pseudomonas fluorescens, 3-Burkholderia pyrrocinia, 4-Trichoderma asperellum, 5-a mixture of the three bioagents). The results showed that the use of 2 ton ha-1 of silicon with a mixture of bioagents was the best treatment to control leaf blast. Besides, from rates, 2 to 6 ton ha-1 of silicon in Capivara Farm and up to 8 ton ha-1 of silicon in Palmital Farm provided the highest grain yield. A mixture of bioagents provided the highest grain yield. In this sense, it was concluded that the best recommendation to connect blast control, grain yield and reduced amount of silicon was the use of 2 ton ha-1 of silicon with the mixture of bioagents. Made available in DSpace on 2021-12-02T14:00:55Z (GMT). No. of bitstreams: 1 jpsp-2021.pdf: 463307 bytes, checksum: a70c96be86c141bc7648f0b3558d6b5d (MD5) Previous issue date: 2021

Problems related to the effective processing of refractory gold ores containing carbon and arsenic are discussed. In the search for technologies for the extraction of gold from such ores, including those obtained from the Sayak-4 gold deposit, pyrometallurgical processing represents a possible direction. The results of an experimental study of the Reducing Pyrometallurgical Selection (RPS) process carried out in relation to this ore are presented. To this end, the ore was smelted with flux additives and a reducing agent leading to the extraction of noble metals in the metallized phase. The experiments were carried out using the following ore composition, wt. %: 3.5 g/ton Au; 1.76 g/ton Ag; 3.95 Fe; 0.01 Cu; 1.93 C; 1.0 S; 3.3 As; 0.05 Co; 38.30 SiO2; 23.6 CaO; 4.56 Al2O3; 0.73 MgO with addition of iron, copper oxides, and coke. The optimal temperature conditions of melting were determined. The possibility of obtaining a metallized phase containing 16.2–16.4 g/ton gold with gold recovery of ∼ 90% was demonstrated. Preliminary calculations show that the economic efficiency of the new process can be achieved with a gold content of more than 5 g/ton in ore. Pyrometallurgical processing is shown to be promising for treating ores obtained from refractory and double-refractory gold deposits.

Organic acids have exhibited great potential as an antibiotic replacement and as an additive work tremendously for health maintenance of broiler chicken. To explore more about organic acids, a total of 900 day-old broiler chicks (Cobb-500) were procured from a local hatchery and distributed into 9 treatment groups having 5 replicates of 20 birds each; duration of the biological trial was of 35 days. Group T1 served as control group without any dietary supplementation. Other groups T2 and T3 were boosted with different levels (125 g/ton and 250 g/ton) of enramycin (antibiotic), T4, T5, and T6 were supplemented with different levels (2 kg/ton, 3 kg/ton, and 4 kg/ton) of ammonium formate and ammonium propionate, and T7, T8, and T9 were fed with different levels (2 kg/ton, 3 kg/ton, and 4 kg/ton) of calcium formate and calcium propionate. The findings declared significant improvement (P 0.05) in body weight gain and FCR in groups T3, T5, and T9 while feed intake was not affected. Carcass evaluation depicted significantly better (P 0.05) dressed and eviscerated weight along with carcass yield (T5, T7, T8, T9). Broilers fed organic acid supplemented diet had significantly lower (P 0.05) total bacterial count (T3, T5, T8, T9) and positively improved (P 0.05) villi length (T5, T6, T9) as compared with control group. However, total protein, globulin, HDL, and LDL levels were determined to be non-significant (P 0.05) among different organic acids treatments. Hence, organic acids can be utilized as a better replacement for antibiotics. Supplementation of organic acids at a dose rate of 3 kg/ton and 4 kg/ton is recommended for efficient performance of broilers.

A pot experiment was conducted to evaluate the effects of zinc and vermicompost on the growth, yield and nutrient content of soybean (Glycine max L.) plant. The treatment variables were control (‒Zn and ‒VC), VC 5 ton/ha, Zn 1 kg/ha, Zn 2 kg/ha, Zn 3 kg/ha, Zn 1 kg/ha + VC 5 ton/ha, Zn 2 kg/ha + VC 5 ton/ha and Zn 3 kg/ha + VC 5 ton/ha. Application of zinc and vermicompost showed a significant effect on the growth parameters and macro- and micronutrients uptake by the plant. The highest average plant height (164 cm), leaf number (80 nos./plant), leaf area (3360 cm2/plant), fresh weight (49.03 gm/plant), dry weight (24.54 gm/plant), fruit length (9.4 cm), fruit number per plant (5 nos. /plant) were recorded for Zn 1 kg/ha + VC 5 ton/ha treatment while the lowest values were observed in control at harvest. Results of the growth parameters varied significantly (p ≤ 0.05) with time. It was observed that, the overall best growth performance was achieved in Zn 1 kg/ha + VC 5 ton/ha. Dhaka Univ. J. Biol. Sci. 29(2): 201-208, 2020 (July)

This study proposes a waste management system for metropolitan cities and presents a thermodynamic analysis and emission assessment of a municipal solid waste incineration plant operating with collected wastes from the 37 municipalities of Istanbul city, Turkey. A thermodynamic analysis of the proposed system shows that 53.72 MW of electricity generation and the heat of 99.4 MW for district heating are obtained with the municipal solid waste incineration. The energy and exergy efficiencies of the plant are 55.5% and 35.4%, respectively. The rate of exergy destruction for each component in the plant and their variation with ambient temperature is calculated. The maximum rate of destruction occurs for the combustion chamber as 44.02 MW. According to the emission assessment, total CO2 emission is 45 500 ton per year and this value can be reduced to 4550 ton per year with the addition of carbon capturing and storage unit. The other released emissions from the incineration plant such as CH4, N2O, CO, NH3, and non‐methane volatile organic compounds (NMVOCs) are found to be 0.15, 34.36, 201.03, 16.08, and 20.10 ton per year, respectively. © 2020 Society of Chemical Industry and John Wiley & Sons, Ltd.

Polyoxometalate-based copper clusters as promising hydrogen evolution catalysts are rarely reported. Here, [Cu5(OH)4(H2O)2(A-α-SiW9O33)2]10- (1) was tested as an effective molecular catalyst for visible-light-driven H2 evolution. A high turnover number (TON) of 718.9 was achieved in the photocatalytic reaction. Many stability experiments showed that compound 1 could maintain its structure intact during the photocatalytic process.

Here, we report that layered metallic vanadium diboride (VB2) can function as an active cocatalyst for efficiently catalyzing photocatalytic hydrogen evolution in a dye-sensitized system under visible light irradiation. In an Erythrosin B–triethanolamine (ErB–TEOA) molecular system, the highest turnover number (TON) of hydrogen evolution based on ErB reaches 40. In addition, VB2 outperforms V2O5, VS2, VN, and VC for photocatalytic hydrogen evolution.

A series of photocatalysts consisting of C- and N-doped titanium dioxide (TiO2) nanoparticles highly dispersed and firmly embedded at the surface of a silica matrix were prepared using a novel synthesis method in which activated carbon has a double role: it acts as support for depositing the TiO2 nanoparticles and as hard template for generating a silica matrix that embeds them. Additionally, the use of activated carbon in combination with ammonia during the synthesis led to carbon and nitrogen doping of the TiO2 domains, which enhanced their absorption of radiation in the visible range. The combination of these features led to higher activity (i.e. higher removal % and TON) in the photocatalytic degradation of probe pollutants (phenol and rhodamine B) compared to the benchmark P25 TiO2 under UV and, even more markedly, under visible radiation. Particularly, the photocatalyst prepared with 10 wt% of TiO2 nanoparticles (10%TiO2NP@SiO2) displayed much enhanced TON values under visible radiation compared to P25 TiO2 (a 12 times higher TON with rhodamine B, and an 8 times higher TON with phenol). The TON values are also significantly higher compared to any previously reported TiO2-SiO2 photocatalyst. The TiO2NP@SiO2 photocatalysts can be effectively reused in consecutive runs. The photocatalytic activity of the prepared materials was correlated to their physicochemical properties by means of a thorough characterisation using a combination of techniques (XRD, ICP-OES, N2 physisorption, TEM, UV–vis, FT-IR and XPS).

Recycled steel is a key material for sustainable development. However, not all steel demand can be met by recycling, and therefore, new metallic iron must be introduced in the global cycle. The transformation of iron oxides into steel requires carbon which is oxidized into CO2. This paper focuses on the basic oxygen furnace (BOF) where molten iron is converted into liquid steel. In order to assess the effect of molten iron temperature on CO2 emissions, the process has been modelled using mass and energy balances. Model results show that, for a typical converter charge, a slight increase of 10 °C can lead to a direct reduction of 0.006 t of CO2 per ton of liquid steel. A total variation of 0.17 t of CO2 per ton of liquid steel is found depending on plant strategy and process constraints. Finally, different actuation levers for carbon mitigation are assessed. It can be concluded that operation and modelling improvements should be jointly addressed to exploit their full potential for carbon footprint reduction.

The practical application of Shilov-type Pt catalysis to the selective hydroxylation of terminal aliphatic C-H bonds remains a formidable challenge, due to difficulties in replacing PtIV with a more economically viable oxidant, particularly O2 . We report the potential of employing FeCl2 as a suitable redox mediator to overcome the kinetic hurdles related to the direct use of O2 in the Pt reoxidation. For the selective conversion of butyric acid to γ-hydroxybutyric acid (GHB), a significantly enhanced catalyst activity and stability (turnover numbers (TON)>30) were achieved under 20 bar O2 in comparison to current state-of-the-art systems (TON60). Altogether, a useful catalytic system for the selective hydroxylation of primary aliphatic C-H bonds with O2 is presented. ispartof: CHEMISTRY-A EUROPEAN JOURNAL vol:25 issue:45 pages:10724-10734 ispartof: location:Germany status: published

We study the process of hydrogen release from magnesium hydride under the conditions of uniaxial pressing in a vacuum at room temperature up to pressures of about 2.4 ton/cm2. It is shown that the desorption of hydrogen occurs under loading. The amount of hydrogen almost linearly depends on the applied pressure. The measured coefficient is 5 ·10– 3 wt.%· cm2 /ton.

Several mononuclear complexes with structure of [TpyRu2+(Py)2Cl]+ and [TpyRu2+(Isoq)2Cl]+ have been designed and synthesized. The structures of these complexes were confirmed by NMR and ESI-MS, the properties of all catalysts were also characterized optically and electrochemically. Water oxidation experiments were examined by turnover numbers (TONs), which showed the catalytic properties of all catalysts. In comparison, pyridine functionalized 1a-1d have more catalytic activities than isoquinoline coordinated complexes 2a-2d. It was also observed that attached polycyclic aromatic groups on the terpyridines had limited impact on catalytic activities. Among these ruthenium complexes, Ph-TpyRu2+(Py)2Cl exhibited the highest TON of 897.

We report the synthesis of tripodal ligand-based nickel catalysts [Ni(tren)(NO3)2] (1) & [Ni(hmtren)(H2O)](NO3)2 (2) and demonstrate its catalytic hydrogenation of CO2 to formate in a basic medium. 1 exhibited the catalytic activity with a turnover number (TON) of 418 in a triethylamine medium at 120 °C. 2 was synthesized by introducing electron releasing methyl groups in 1, which was found to enhance the production of formate and presented a better TON of 638. The catalytic effects of 1 and 2 in the production of formate with NaHCO3 and KOH bases are discussed, and this study validates the use of a non-precious metal catalyst for CO2 hydrogenation in an aqueous medium.

In this paper, we adopt a non-radial directional distance function to analyze the efficiency and shadow price of CO2 emissions of coal-fired power plants. Using a sample of Shanghai's 20 coal-fired power plants, we find that the efficiency performance of power plants remained steady during the period 2007–2010. On average, the carbon abatement costs of Shanghai's power plants increased from 20.58 yuan/ton to 39.67 yuan/ton during 2007–2010. Although the average shadow price of the power plants increased during the period, the price was still well below shadow prices for the energy consumption of the industries, and a little lower than the trading price in the ETS markets. In addition, the paper discusses the implications of the findings.

High-pressure X-ray diffraction and Raman spectroscopy in a diamond anvil cell were used to study the insertion of the chemical hydrogen storage material, ammonia borane, in the one-dimensional pores of the zeolite theta-1 TON. Heating of this material up to 300 °C under pressures up to 5 GPa resulted in the release of a significant amount of hydrogen due to the conversion of ammonia borane confined in the channels of TON and outside the zeolite to polyaminoborane and then polyiminoborane chains. The filling of TON with hydrogen resulted in a much greater increase in unit cell volume than that corresponding to thermal expansion of normal compact inorganic solids. This process at high temperature is accompanied by a phase transition from the collapsed high-pressure Pbn21 form to the more symmetric Cmc21 phase with expanded pores. This material has a high capacity for hydrogen adsorption under high-temperature, high-pressure conditions.

Highlights • Brownification is an increasing threat to aquatic ecosystems. • Reasons behind changes in C and N concentrations in forested streams were studied. • TOC and TON concentrations increased significantly in 7–10 of 12 forested catchments in 30 yrs. • Air temperature and sulphate concentrations explained 83% of the TOC variation. • TON trends were connected to TOC and linked to climatic factors and drainage-%. Brownification, caused by increasing dissolved organic carbon (DOC) concentrations is a threat to aquatic ecosystems over large areas in Europe. The increasing concentrations of DOC in northern boreal streams and lakes have attracted considerable attention with proposed important drivers such as climate, deposition and land-use, and complex interactions between them. Changes in total organic N (TON) concentrations have received less attention, even though carbon and nitrogen losses are highly related to each other. We used long-term (1990–2019) monitoring records of 12 small data-rich headwater forested catchments in a large gradient of climate and deposition. We found that total organic carbon (TOC) concentrations were significantly increasing in almost all study catchments. The mean air temperature and change in sulphate concentrations had a strong, significant correlation to TOC change-%. Both explained, alone, more than 65% of the change in TOC concentrations, and, together, up to 83% of the variation. Sulphur deposition has already decreased to low levels, our results indicate that its importance as a driver of TOC leaching has decreased but is still clearly detected, while the impact of climate warming as a driver of TOC leaching will be even more pronounced in the future. A positive correlation was found between drainage-% and increases in TON, suggesting also importance of land management. TON trends were tightly connected to changes in TOC, but not directly linked to decreasing S deposition.

The insertion of oxygen and nitrogen molecules in the one-dimensional (1D) pore system of the zeolite TON was studied at high pressure by vibrational spectroscopy, X-ray diffraction, and Monte Carlo (MC) molecular modeling. Rietveld refinements and MC modeling indicate that, on average, six diatomic molecules per unit cell enter the pores of the zeolite. This induces changes in compressibility and distortion related to the Cmc21-to-Pbn21 phase transition compared to the empty-pore material. The filling behavior with N2 and O2 under pressure is similar to that of argon, suggesting that the kinetic diameter, which is very close in these three systems, plays a major role. The orientation of the diatomic molecules appears to have a rather minor effect on filling occurring at a slightly higher pressure for N2, which has a larger kinetic diameter. Both inserted molecules, initially not showing any marked orientation, begin to exhibit a degree of orientational order above 2 GPa.

A Mn-catalyzed diastereo- and enantioselective hydrogenation of α-substituted β-ketoamides has been realized for the first time under dynamic kinetic resolution conditions. anti-α-Substituted β-hydroxy amides, which are useful building blocks for the synthesis of bioactive molecules and chiral drugs, were prepared in high yields with excellent selectivity (up to >99 % dr and >99 % ee) and unprecedentedly high activity (TON up to 10000). The origin of the excellent stereoselectivity was clarified by DFT calculations.

Summary Hetero-axial cobalt complexes are known for their oxygen-tolerant photocatalytic hydrogen production activity, mostly in organic solvents. Here, variable combinations of peripheral basic groups are explicitly positioned around an existing complex framework to generate an enzyme-inspired minimal outer coordination sphere (OCS) scaffold. This catalyst design strategy yields a series of water-soluble, upgraded versions of imidazole-linked cobaloximes. The presence of fringe protic functionalities ensures the formation of a dynamic and water-mediated proton relay. This appended proton relay allows us to probe imidazole-bound cobaloxime in pure aqueous conditions. It exhibits highly efficient electrocatalytic (TOF ∼4,900 s−1) and photocatalytic (TON ∼12,000) hydrogen production in neutral water compared to its relatively moderate performance in organic media. The catalyst retains its activity (TON ∼22), even under natural sunlight (sunny day in Gandhinagar) in aerobic aqueous solution, emphasizing the importance of OCS features for producing robust, natural-condition-ready, synthetic catalysts.

Cement production consumes 9.10% of the total industrial energy, thus making it the third largest consumer of energy. Each ton of cement generates approximately 0.7–0.93 ton of CO2 dependin...

The study was carried out to examine the optimum dose of Nitrogen on Broccoli in Institute of Agriculture and Animal Science, Lamjung Campus during Sept, 2015- Jan, 2016. Six treatment Viz. 50, 100,150,200, 250, 300 kg/ha of Nitrogen with same level of P and k (160:100 kg/ha) and FYM (20 t/ha) were used in a Randomized Complete Block Design with three replications. Effect of treatments on plant height, leaf area and head weight plant-1, yield ha-1 were significant and other parameters (leaf number, SPAD reading, plant spreading) were not affected by the treatments. Treatment that received 300 kg N ha-1 gave the maximum yield ha-1 (14.77 ton) which was followed by treatment that received 250 kg N ha-1 (10.60 ton), 200 kg N ha-1 (8.11 ton), 150 kg N ha-1 (7.432 ton), 100 kg N ha-1 (5.96 ton) and 50 kg ha-1 (4.24 ton). Treatments 250 kg N ha-1, 200 kg N ha-1, 150 kg N ha-1 and 100 kg N ha-1 were statistically at par while 50 kg produced the least yield ha-1. Application of 300 kg N ha-1 gave the higher result with respect to plant height (17.75 cm), leaf area (699.32 cm2), leaf number (7.77), SPAD reading (68.71), plant spreading (70.21 cm), compared to other treatments while minimum result obtained from application of 50 kg N ha-1. Hence, we can conclude that the total head production increased with increased N Int. J. Appl. Sci. Biotechnol. Vol 6(3): 270-273

The paper by J.M. Dewey (Shock Waves 29(4):583–587, 2019) described the development of an Excel-based interface that provides the physical properties of blast waves generated by propane/oxygen explosions. The interface was developed using the data from a nominal 20 ton explosion of an assumed stoichiometric propane/oxygen mixture. Comparisons of data from the interface with measurements of small-scale stoichiometric propane/oxygen explosions show discrepancies. Further studies revealed that the 20 ton explosion was not stoichiometric and had a 43% oxygen deficiency. The interface has been redeveloped assuming that only 57% of the available propane had been detonated. The revised interface produces results which agree with measurements from both the 20 ton explosion and the small-scale (

Hydro-metathesis of propene was carried out by using well-defined W(CH3)6 supported on silica and silica-alumina. It was observed that W(CH3)6 supported silica-alumina catalyst is much better (TON 4577) than the silica supported catalyst (TON 2104). We demonstrated that the present catalysts are much better than the previously reported (tantalum hydride/KCC-1, TON 786) catalyst. For the first time, we observed the formation of n-decane from propene, which enables us to think of using cheaper raw materials and converting them to petroleum range alkanes using hydro-metathesis reaction.

A sandwich tungstobismuthate with new topology based on {B-β-BiW8O30}-cluster and unique 14-nuclear sandwich unit is reported as a high-efficiency visible light-driven water oxidation catalyst containing extended hetero-metal oxygen layer. At optimal conditions, the turn-over number (TON) of the title compound can reach 205.5 with O2 yield of 32.88%.

A thermoregulated phase-separable Rh nanocatalyst exhibited high performance in the hydroformylation of styrene, even after 20 recycles. Most strikingly, the TON reached up to 101 850, which is far higher than the highest value ever reported for this reaction. Besides, the catalytically active species of rhodium complexes were preliminary explored via a mercury experiment and FT-IR.

A photosensitizer based on a ruthenium complex of a bisamide-polypyridyl ligand gives rise to a large improvement in photocatalytic stability, rate of activity, and efficiency in photocatalytic H2 production compared to [Ru(bpy)3 ]2+ (bpy=2,2'-bpyridine). The bisamide ruthenium polypyridyl complex combined with a cobaltoxime-based photocatalyst was found to be highly efficient under blue-light (turnover number (TON)=7800) and green-light irradiation (TON=7200) whereas [Ru(bpy)3 ]2+ was significantly less effective with a TON of 2600 and 1100, respectively. The greatest improvement was under red-light-emitting diodes, with bisamide ruthenium polypyridyl complex and cobaltoxime exhibiting a TON of 4200 compared to [Ru(bpy)3 ]2+ and cobaltoxime at a TON of only 71.

Sarjono A, Lahjie AM, Simarangkir BDAS, Kristiningrum R, Ruslim Y. 2017. Carbon sequestration and growth of Anthocephalus cadamba plantation in North Kalimantan, Indonesia. Biodiversitas 18: 1385-1393. Forest plantation of Jabon (Anthocephalus cadamba) plays many important roles for the primary source of timber production and also the carbon absorption for environmental amelioration. The growth of A. cadamba trees was measured using the formulas of MAI (Mean Annual Increment) and PAI (Periodic Annual Increment) as the basis of the increment measurement, while the analysis of biomass and carbon with simple linear regression (y = a + bx) was used, with the coefficient of R2 = 0.90. The annual increment of A. cadamba trees reached its maximum point or the intersection between MAI and PAI at the age of 8 years, showing the maximum production of A. cadamba trees. Forest plantation of A. cadamba produced biomass and carbon sequestration of 81.90 ton ha-1 and 39.31 ton ha-1, respectively at the age of 8 years. However, the amount of biomass and carbon in another plot of A. cadamba trees was 96.85 ton ha-1 and 46.49 ton ha-1, respectively. While the values of the third plot were 116.84 ton ha-1 and 56.08 ton ha-1, respectively. The correlation between the diameter and biomass production and the correlation between the age of stands and carbon production were very strong with R2 value was higher than 0.90. This indicated that Jabon (Anthocephalus cadamba) plantation had important roles in carbon sequestration and biomass production.

Top gas recycling oxygen blast furnace (TGR-OBF) process is a promising ironmaking process. The biggest challenge of the TGR-OBF in operation is the dramatic decrease of top gas volume (per ton hot metal), which once led to hanging-up and shutdowns in practice of the Toulachermet. In order to avoid this weakness, the strategy of medium oxygen blast furnace was presented. The maneuverable zone of the TGR-OBF was determined by the top gas volume, which should not be far from the data of the traditional blast furnace. The deviation of ±12.5% was used, and then the maneuverable blast oxygen content is from 0.30 to 0.47 according to the calculation. The flame temperature and the top gas volume have no much difference compared to those of the traditional blast furnace. The minimum carbon consumption of 357 kg per ton hot metal in the maneuverable zone occurs at the oxygen content of 0.30 (fuel saving of 14%). In the unsteady evolution, the N2 accumulation could approach nearly zero after the recycling reached 6 times. Thus far, some TGR-OBF industrial trials have been carried out in different countries, but the method of medium oxygen enriched TGR-OBF has not been implemented, because the accumulation of N2 was worried about. The presented strategy of medium oxygen enriched TGR-OBF is applicable and the strategy with good operational performance is strongly suggested as a forerunner of the full oxygen blast furnace.

Significance The most important single economic concept in the economics of climate change is the social cost of carbon (SCC). At present, regulations with more than $1 trillion of benefits have been written for the United States that use the SCC in their economic analysis. The DICE model (Dynamic Integrated model of Climate and the Economy) is one of three integrated assessment models used to estimate the SCC in the United States. The present study presents updated estimates based on a revised DICE model (DICE-2016R). The study estimates that the SCC is $31 per ton of CO 2 in 2010 US$ for the current period (2015). This study will be an important step in developing the next generation of estimates of the SCC in the United States and other countries.

Field experiments were conducted during winter seasons of 2013 and 2014 on the alkaline and silty loam soils of NWRP, Bhairahawa to study the interaction of the most promising wheat genotypes with different nitrogen levels under different agro-ecological zones and recommend the appropriate dose of nitrogen for newly released varieties. The experiment was laid out in split plot design: four nitrogen levels (0, 50, 100 and 150 kg/ha) as a whole plot and six wheat genotypes (BL 3623, BL 3629, BL 3872, NL 1008, NL 1055 and Vijay) as a sub-plot which were replicated three times. There was significant effect of varieties and nitrogen levels on plant height, number of spikes, thousand grain weight and grain yield in both the years. In first year, the highest grain yield of 3.35 t/ha was obtained from the application of nitrogen @ 150 kg/ha with the genotype BL 3872 which is followed by the genotypes BL 3623 (3.15 ton/ha) and NL 1055 (3.05 ton/ha). Similarly in second year, the genotype NL 1055 gave the highest grain yield of 4.01 ton/ha followed by genotypes BL 3629 (3.83 ton/ha) and BL 3623 (3.81 ton/ha) from the application of nitrogen @ 150 kg/ha. Based on two years results, it can be concluded that N was a limiting factor in the productivity of wheat. Nitrogen @ 150 kg per ha produced higher yield and yield attributing characters. Similarly, the wheat genotypes NL 1055, BL 3629, BL 3623 and BL 3872 were superior among the genotypes.

The experiment was designed to study the effect of dietary Nano-selenium on productive, immunological performance, oxidation resistance and selenium deposition in tissue of laying hens- A total number of 180 laying hens of Silver Montazah strain were used. Layers were divided randomly into six treatments. Five Nano-selenium diet concentrations (200, 160, 120, 80 and 40 mg/ton for treatments (T2, T3, T4, T5 and T6), respectively. The treatment (T1) was used as control with 200 mg/ton diet sodium selenite. The results were discussed and summarized as follows: Application of Nano-selenium in layer diets was effective in increasing egg number, egg mass, total serum protein, and albumin. Also, Nano-selenium improved some immunological traits, feed conversion, some egg quality traits and some antioxidant enzymes traits. The optimum level of Nano-selenium was 200 mg/ton diet, which recorded 5.409 feed/g egg mass compared to 9.249 feed / g egg mass in control treatment (200 mg/ton diet) Application of 200 mg/ton diets Nano-selenium were significantly decreased total cholesterol, high density Lipoprotein, triglycerides, heterophils (H%) and H/L ratio. Where, Lymphocyte was significantly (p≤ 0.01) increased. The concentration of selenium in liver, breast meat and whole egg were 30.9%, 40.5% and 102.3% higher in layers fed 200 mg/ton diet Nano- selenium compared to layers fed 200mg/ton sodium selenite. layers fed 200mg/ton diet Nano- selenium had 5.6 % and 5.4 % higher in dressing and edible meat, respectively.

Two electron-reduction of the TiIV guanidinate complex (ImDipp N)(Xyket guan)TiCl2 gives (η6 -ImDipp N)(xyket guan)Ti (1intra ) and (ImDipp N)(Xyket guan)Ti(η6 -C6 H6 ) (1inter ) (Xyket guan=[(tBuC=N)C(NXylyl)2 ]- , Xylyl=2,5-dimethylphenyl) in the absence or presence of benzene, respectively. These complexes have been found to hydrogenate monocyclic and polycyclic arenes under relatively mild conditions (150 psi, 80 °C)-the first example of catalytic, homogeneous arene hydrogenation with TON >1 by a Group IV system.

Eight bidentate NHC/Ru complexes, namely [Ru]-1–[Ru]-8, were designed and prepared. In particular, [Ru]-2 displayed extraordinary performance even in open air for the dehydrogenative coupling of alcohols and hydroxides. Notably, an unprecedentedly low catalyst loading of 250 ppm and the highest TON of 32 800 and TOF of 3200 until now were obtained.

This research has been done to estimate the mercury emission in Iran following to the UNEP procedures, which to identify and to quantify of mercury releases of anthropogenic sources in Iran. According to results, the rate of mercury emission in Iran in 2015 was 136.78 ton per year in which 31.5 ton has been emitted to the air, 9.8 ton to water, 10.1 ton to land, 18.5 ton to products, 5.5 ton to general wastes, and 61.3 ton to sector specific sector-specific treatment/disposal. The results also showed that total mercury emissions in Iran were about 1.58 ram per year. These high values compared with other countries attributed to lack of control technologies and use of non-environmental friendly technology in Chlor-alkali production. Chlor-alkali plant is responsible of 50% mercury emission in all environmental compartments in Iran.

A more efficient telomerization of 1,3-butadiene with carbon dioxide leading to the valuable δ-lactone 1 (3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one) is reported. The key to success is the use of a palladium/TOMPP-catalyst system (TOMPP=tris-(o-methoxyphenyl)-phosphine), which provided under optimal conditions significantly increased yields of the desired product and improved catalyst turnover numbers (TON=1500).

WOS: 000381593700002, To be industrially feasible, and applicable in synthesis of fine chemicals, a catalyst has to possess high turnover number (TON) and turnover frequency (TOF). In this study, a new cross-linked chitosan derivative was synthesized by using 2,2'-pyridil as a cross-linking agent. 2,2'-Pyridil cross-linked chitosan was used to as a support material for palladium catalyst. Chitosan-pyridil-based Pd(II) catalyst was tested in the microwave-assisted synthesis of biaryls via Suzuki coupling reactions. The catalyst yielded remarkable TONs of up to 20,000 and TOFs of up to 240,964 by using very low catalyst loading (5 x 10(-3)% mol) in a short reaction time (5 min). The catalyst also showed a better recyclability. (C) 2016 Elsevier B.V. All rights reserved.

New bipyridinemethanamine-containing tetradentate ligands and their corresponding ruthenium complexes have been synthesized. The synthesized complexes performed well in the hydrogenation of a variety of esters with high efficiency (TON up to 9700) giving alcohols in good yields.

In the present study, the effectiveness of polymer (maleic-itaconic acid) on ammonia (NH 3 ) emissions reduction and in retaining nitrogen (N) in fresh liquid swine manure (SM) was evaluated. The relationship between pH and NH 3 emission was also determined. Different doses of polymer (namely Treatment 1 = T1 = 0.8 L polymer/ton of manure, Treatment 2 = T2 = 1.6 L polymer/ton of manure, Treatment 3 = T3 = 2.4 L polymer/ton of manure, and Treatment 4 = T4 = 3.2 L polymer/ton of manure) were added to the SM and its effects were observed for 30 d. The tests results showed significant reduction in pH for T1, T2, T3 and T4 compared to control (C). For the short term (up to 3d) T2, T3, and T4 showed significantly lower NH 3 gas concentrations than C, however, for the long term (up to 10–20 d) only T4 continued to indicate significantly lower NH 3 gas concentrations. Although numeric observations were reported for other treatments (T1, T2 and T3), no significant differences in NH 3 gas concentrations were found. The NH 3 emissions reductions were calculated in the range of 81–92%, 31–88%, −39–61%, 6–41%, −106% to −6% for the treatment period of 1, 3, 10, 20 and 30 d, respectively. The addition of polymer resulted in no significant difference in total ammonia nitrogen (TAN) and NO 3 − –N concentration. However, the addition of polymer had a significant influence on total Kjehldahl nitrogen (TKN) and soluble chemical oxygen demand (SCOD) concentration. The NH 3 gas emissions strongly correlated with the manure pH (R 2 = 0.911–0.999).

Magnesium is a promising lightweight and green metallic engineering material, but the environmental impact of primary magnesium production stage, especially greenhouse gas (GHG) emissions cannot be ignored. In this study, the life cycle energy consumption and GHG emissions caused by the production of primary magnesium in the years of 2003-2013 in China were calculated; the factor decomposition was conducted to analyze the GHG emissions of magnesium production process by using logarithmic mean Divisia index method (LMDI), including energy GHG emission factors, energy structure, energy consumption per ton of primary magnesium, production, emissions per unit of dolomite and ferrosilicon, and dolomite and ferrosilicon consumptions per ton of primary magnesium. The results showed that GHG emissions of primary magnesium production increased 260.29*104 t CO2eq in total from 2003 to 2013. The variety magnesium production contributed the biggest part of GHG emissions, accounting for 418.17%. The energy structure took second place on the contribution of GHG emissions, accounting for-161.49%. The nest part was energy consumption per ton of primary magnesium, accounting for-138.97%. While, the contribution of energy GHG emission factors, emissions per unit of dolomite and ferrosilicon, and dolomite and ferrosilicon consumptions per ton of primary magnesium was relatively small, which were 0.88%, 0.00% -2.72% -4.73% and-11.13%, respectively. Thus, it is the key methods to reduce GHG emissions by optimizing the energy structure and decreasing the energy consumption.

Methanol is an alternative fuel that offers a convenient solution for efficient energy storage. Complementary to carbon capture activities, significant effort is devoted to the development of technologies for methanol synthesis by hydrogenation of carbon dioxide. While CO2 is available from plenty of sources, cheap sources of H2 are less frequently found. An additional source of hydrogen at industrial scale is the wet hydrogen by-product of chlorine production. This study is the first to propose an efficient process for methanol synthesis by CO2 hydrogenation using wet hydrogen by-product from chlor-alkali production. A key feature of this novel process is the use of a stripping unit where the wet hydrogen flows in counter-current mode with the condensed methanol–water mixture resulting from the high-pressure low-temperature separator after the reaction. This operation has a double positive effect, as it removes the CO/CO2 from the methanol–water mixture thus allowing a complete recycle of CO2 and avoiding its presence in the product, while also removing the water from the wet hydrogen thus avoiding the negative impact of adding water on the equilibrium conversion – with consumption figures of 550 kWh electricity and 0.48–1.16 ton steam per ton methanol.

We report an all-new nickel-containing POM catalyst [{β-SiNi2W10O36(OH)2(H2O)}4]24− (1) that catalyzes water oxidation under visible light. Multiple experiments confirm that 1 acts as an active and dominant catalyst rather than Ni2+ ions (aq) or nickel oxide during the water oxidation.

Chemical looping combustion (CLC) is a promising method for power production with integrated CO2 capture with almost no direct energy penalty. When integrated into a natural gas combined cycle (NGCC) plant, however, CLC imposes a large indirect energy penalty because the maximum achievable reactor temperature is far below the firing temperature of state-of-the-art gas turbines. This study presents a techno-economic assessment of a CLC plant that circumvents this limitation via an added combustor after the CLC reactors. Without the added combustor, the energy penalty amounts to 11.4%-points, causing a high CO2 avoidance cost of $117.3/ton, which is more expensive than a conventional NGCC plant with post-combustion capture ($93.8/ton) with an energy penalty of 8.1%-points. This conventional CLC plant would also require a custom gas turbine. With an added combustor fired by natural gas, a standard gas turbine can be deployed, and CO2 avoidance costs are reduced to $60.3/ton, mainly due to a reduction in the energy penalty to only 1.4%-points. However, due to the added natural gas combustion after the CLC reactor, CO2 avoidance is only 52.4%. Achieving high CO2 avoidance requires firing with clean hydrogen instead, increasing the CO2 avoidance cost to $96.3/ton when a hydrogen cost of $15.5/GJ is assumed. Advanced heat integration could reduce the CO2 avoidance cost to $90.3/ton by lowering the energy penalty to only 0.6%-points. An attractive alternative is, therefore, to construct the plant for added firing with natural gas and retrofit the added combustor for hydrogen firing when CO2 prices reach very high levels. 2590-1745/ © 2020 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/BY/4.0/).

Global warming is one of the major environmental issues of this century. Carbon dioxide (CO2) emissions are the main cause of global warming. Green open space (RTH) such as urban parks, urban forests and green lines play an important role in mitigating global warming and climate change in urban areas because it is able to reduce CO2 from the atmosphere. This study aims to determine the potential of biomass and carbon stored in the Green Open Green Space of Polewali, West Sulawesi. Data collection for stored biomass and carbon is carried out at three green space locations including; Urban forest and city park and green lane each made three plots measuring 20 m x 20 m, and three plots on the Green Line measuring 1200 m. Retrieval of data by measuring tree height and diameter, analysis to obtain the dry volume, biomass and carbon stored for each tree species contained in the Polewali green space. Biomass is obtained by the formula M = BJ x Vk x BEF, the stored carbon value is obtained from the product of biomass by 0.47. The magnitude of the relationship of volume with biomass and carbon uses a regression equation (Ŷ=a+bX). The results show there are types of Glodokan (Polyalthia longifolia), Johar (Senna siamea), Mahogany (Swetenia sp) and Trambesi (Samanea saman) which are spread in the Polewali open green space. Trambesi is a type that has dominant biomass and stored carbon of 381.95 (tons / ha) and 179.52 (ton/ha). Green lane is the type of green space that has the most stored carbon and is currently 440.94 (ton/ha) and 207.24 (ton/ha). The overall green space biomass is 571.83 (ton/ha) and stored carbon is 268.76 (ton/ha) found in urban forests, urban gardens and green belt. The relationship of volume with biomass and stored carbon shows a very strong relationship with the coefficient of determination (R2) of 0.96.

A series of Mn-I complexes containing lutidine-based chiral pincer ligands with modular and tunable structures has been developed. The complex shows unprecedentedly high activities (up to 9800 TON; TON=turnover number), broad substrate scope (81 examples), good functional-group tolerance, and excellent enantioselectivities (85-98% ee) in the hydrogenation of various ketones. These aspects are rare in earth-abundant metal catalyzed hydrogenations. The utility of the protocol have been demonstrated in the asymmetric synthesis of a variety of key intermediates for chiral drugs. Preliminary mechanistic investigations indicate that an outer-sphere mode of substrate-catalyst interactions probably dominates the catalysis.