1. Selective removal of high concentration arsenate from aqueous solution by magnetic Fe–Y binary oxide
- Author
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Linqing Dai, Shixing Wang, Minghu Zhao, Zhen Huang, and Libo Zhang
- Subjects
Aqueous solution ,Materials science ,Ion exchange ,Precipitation (chemistry) ,Inorganic chemistry ,Oxide ,Arsenate ,Langmuir adsorption model ,chemistry.chemical_element ,02 engineering and technology ,equipment and supplies ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,chemistry.chemical_compound ,symbols.namesake ,Colloid and Surface Chemistry ,Adsorption ,chemistry ,symbols ,0210 nano-technology ,human activities ,Arsenic - Abstract
A novel magnetic Fe-Y binary oxide was prepared by precipitation method and served as an adsorbent to remove arsenic in pollutant. The FTIR, FESEM, XRD and XPS were used to characterize the adsorbent. The adsorption properties of the magnetic Fe-Y binary oxide were tested by batch experiment. The adsorption process complies with the Langmuir model. It indicates that the adsorption process is a single layer adsorption on the surface of the magnetic Fe-Y binary oxide. At the same time, the adsorption process is also very good in accordance with the pseudo second-order kinetic model, indicating that the process is chemiadsorption. When pH = 5, the maximum adsorption capacity was 303 mg/g. The increase of temperature promotes the As(V) adsorption on the magnetic Fe-Y binary oxide. The magnetic Fe-Y binary oxide has high selectivity and regenerative ability at least 5 cycles. The adsorption mechanism of As(V) on the magnetic Fe-Y binary oxide is chelation and ion exchange.
- Published
- 2020