1. Eddy-current-resistant SmCo5/CaF2 magnets produced via high-energy milling in polar and non-polar liquids
- Author
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M. Marinescu-Jasinski, J.F. Liu, C.N. Chinnasamy, George C. Hadjipanayis, and Alexander Gabay
- Subjects
Heptane ,Materials science ,Composite number ,Dielectric ,Coercivity ,Condensed Matter Physics ,Nanocrystalline material ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,chemistry ,Chemical engineering ,Electrical resistivity and conductivity ,Magnet ,Ball mill - Abstract
Processes of high-energy ball milling of SmCo 5 alloys were compared for three single-liquid environments without using additional surfactants. Both coarsely grained as-cast and nanocrystalline pre-milled SmCo 5 precursors showed tendency toward formation of thin flakes if milled in polar liquids (acetone and ethanol) in a marked contrast to milling in non-polar heptane. CaF 2 dielectric powder added prior to milling in the polar liquids tends to become attached on the flake surfaces. Milling in heptane in the presence of CaF 2 produces flake-like SmCo 5 particles which with increasing the milling time are found to incorporate an increasing amount of CaF 2 . The SmCo 5 —5 wt% CaF 2 mixtures milled for the optimum time in both the polar and non-polar liquids were successfully hot-pressed into laminated composite magnets having intrinsic coercivity of 25–30 kOe, maximum energy product of approximately 6.5 MG Oe and electrical resistivity of 500–600 μΩ cm, which is more than 7 times the resistivity of conventional Sm–Co magnets.
- Published
- 2012
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