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Start Over Author "Jean-Pierre Lallier" Topic chemistry.chemical_classification
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1. Mono-oxygenase-like oxidation of hydrocarbons using supported manganese–porpnyrin catalysts: beneficial effects of a silica support for alkane hydroxylation

Author

Jean-Pierre Lallier, Laurent Barloy, Daniel Mansuy, and Pierrette Battioni

Subjects
Hydroxylation, chemistry.chemical_classification, Alkane, chemistry.chemical_compound, Cycloalkane, Ketone, chemistry, Molecular Medicine, Organic chemistry, Alcohol, Aliphatic compound, Porphyrin, Catalysis
Abstract

A supported Mn–porphyrin catalyst was prepared by strong adsorption of the tetracationic Mn[meso-tetra(4-N-methylpyridiniumyl) porphyrin](Cl)4+4Cl– on silica, and was found very efficient for cyclo-octene epoxidation (95% yield, 13 turnovers per min) and for alkane hydroxylation, with alcohol yields and alcohol: ketone ratios remarkably higher than those obtained with corresponding soluble Mn–porphyrins.

Published
1989
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