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Selenium (Se) is an essential trace element for humans. Low concentrations of Se can promote plant growth and development. Enhancing grain yield and crop Se content is significant, as major food crops generally have low Se content. Studies have shown that Se biofortification can significantly increase Se content in plant tissues. In this study, the genetic transformation of wheat was conducted to evaluate the agronomic traits of non-transgenic control and transgenic wheat before and after Se application. Se content, speciation, and transfer coefficients in wheat grains were detected. Molecular docking simulations and transcriptome data were utilized to explore the effects of selenium-binding protein-A TaSBP-A on wheat growth and grain Se accumulation and transport. The results showed that TaSBP-A gene overexpression significantly increased plant height (by 18.50%), number of spikelets (by 11.74%), and number of grains in a spike (by 35.66%) in wheat. Under normal growth conditions, Se content in transgenic wheat grains did not change significantly, but after applying sodium selenite, Se content in transgenic wheat grains significantly increased. Analysis of Se speciation revealed that organic forms of selenomethionine (SeMet) and selenocysteine (SeCys) predominated in both W48 and transgenic wheat grains. Moreover, TaSBP-A significantly increased the transfer coefficients of Se from solution to roots and from flag leaves to grains. Additionally, it was found that with the increase in TaSBP-A gene overexpression levels in transgenic wheat, the transfer coefficient of Se from flag leaves to grains also increased.

We conducted a systematic investigation into the spectral and pulse characteristics of C and L-band Nonlinear Polarization Rotation (NPR) mode-locked fiber lasers effectively employing nonlinear polarization rotation technology. In our experimental setup, we achieved a stable mode-locked state at 1560.076 nm, exhibiting a 3 dB spectral bandwidth of 9.1 nm. As the pump power increased, we observed spectral shifts accompanied by shifts in the first Kelly sideband and the generation of new Kelly sidebands. In this paper, the phenomenon of spectral deviation is elucidated through the interplay of self-phase modulation, group velocity drift, and polarization-dependent isolator (PD-ISO) filter effect, with an analysis of the formation and deviation of Kelly sidebands. Notably, spectral shift persisted even when the pump power exceeded 200 mW. However, continuous pump power escalation led to soliton splitting, resulting in the formation of new soliton beams. Based on the simultaneous generation of spectral shift and pulse splitting, our study contributes to an enhanced understanding of soliton dynamics in ultrafast fiber lasers and lays a foundation for the application of high-repetition-frequency harmonic mode-locked lasers with tunable wavelengths.

A series of Zn-modified HBeta (Zn/HBeta) catalysts were prepared via the wetness impregnation method with different zinc precursors such as ZnSO4·7H2O, ZnCl2, C4H6O4Zn·2H2O and Zn(NO3)2·6H2O, and their catalytic performance in the conversion of ethanol to propylene reaction was evaluated. Results indicate that the amount and strength distribution of the acid sites of the Zn/HBeta catalysts were easily tuned by employing different types of zinc precursors. More importantly, when the zinc species were introduced to the HBeta, the propylene yield was significantly enhanced, whereas the yields of ethylene and C2–C4 alkanes were remarkably suppressed. For the catalyst prepared by using the ZnCl2 precursor, a higher propylene yield of up to 43.4% for Zn/HBeta-C was achieved as a result of the moderate amount and strength distribution of acid sites. The average coking rate of the used Zn/HBeta catalysts strongly depended on the amount of total acid sites, especially the strong acid sites, i.e., the higher the amount of total acid sites of the catalyst, the greater the average coking rate. For the catalyst prepared by using the ZnSO4·7H2O precursor, Zn/HBeta-S exhibited a better stability even after depositing more coke, which was due to the higher amount of strong acid sites.

This study conducted water-induced fault slip experiments on saw-cut granite, sandstone, and limestone samples. Experimental results demonstrated that injecting 15 MPa pressurized water into the vicinity of a high-permeability sandstone fault could decrease the effective normal stress and induce fault slip but not significantly affect the stress of granite and limestone faults due to low permeability. When the pressurized water was injected into the fault plane, 1 MPa pressurized water could not significantly affect fault stress; however, the 15 MPa pressurized water caused a significant reduction in frictional strength and induced fault sliding. The actual pore pressure differed from the injection pressure and showed significant differences in three faults, resulting in the apparent difference in stress drop, slip duration, displacement, and sliding rate. Three faults showed velocity-strengthening properties at room temperature. The fault slip caused by 15 MPa pressurized water injection was a direct response of fault strength to the reduction in effective normal stress. The limestone fault was characterized by velocity-weakening behavior at 100 °C, and the sliding rate of the fault induced by the 15 MPa pressurized water injection was faster than that at room temperature. The experiment results suggest that high-pressure injection can dominate over velocity-dependent effects, inducing fault-unstable slips in velocity-strengthening faults, but is more likely to induce medium-strong earthquakes on the velocity-weakening fault.

In recent years, taste and odor (T&O) compounds in drinking water are becoming a serious problem, which has brought many challenges to drinking water treatment plants. Due to global concerns about the emergence of T&O compounds, researchers have proposed various water treatment technologies to ensure the quality of drinking water. In this paper, abiotic and biotic methods for the treatment of T&O compounds are reviewed, including process parameters, advantages and disadvantages, removal efficiency and mechanism. Geosmin (GSM) and 2-methylisoborneol (2-MIB) are the most common odorous substances with earthy and musty smells. The chemical and biological methods for the possible degradation pathways of these two compounds are summarized. Furthermore, suggestions and approaches are provided for efficient and safe strategies for T&O compound treatments and their future applications.

Environmental pollution caused by rapid industrial activities are becoming increasingly drastic, particularly its impact on soil and plant health. The present study was conducted to investigate the heavy metal (loid) (As, Cd, Cu, Hg, Pb, and Zn) concentrations in soils and food biomass crops and estimate the potential health risks of metals to humans via consumption of contaminated food biomass crops from Shifang, a periurban agricultural areas in the Chengdu Plain, Sichuan, China. Results revealed that the soils have been experiencing a substantial accumulation of heavy metals, especially for Cd, with a mean of 0.84 mg kg−1, about six times higher than the background values, of which 98% exceeded the pollution warning threshold of the China Soil Environmental Quality Standards. A total of 78% of all the grain part failed the national food standard for Cd. No significantly positive relationships between metal levels in food biomass crops and in the corresponding soils, indicated metals enrichment in soils were not entirely reflected to crops contaminant burdens. Estimated daily intake (EDI) of all the metals except for Pb, exceeded the oral reference dose (RfD) or the minimal risk levels recommended by USEPA and ATSDR. Target hazard quotients (THQs) of all the metals except for Cd was less than one indicated that potential health risk to the local inhabitant originated mainly from Cd exposure via cereals consumption. Mitigation strategies to curtail Cd-contaminated soils and crops Cd burdens need careful tailoring to meet the needs of health and safety in this region.

In recent years, federated GBDTs have gradually replaced traditional GBDTs, and become the focus of academic research. They are used to solve the task of structured data mining. Aiming at the problems of information leakage, insufficient model accuracy and high communication cost in the existing schemes of horizontal federated GBDTs, this paper proposes an algorithm of gradient boosting decision trees based on horizontal federated learning, that is, secure and efficient FL for GBDTs (SeFB). The algorithm uses locality sensitive hashing (LSH) to build a tree by collecting similar information of instances without exposing the original data of participants. In the stage of updating the tree, the algorithm aggregates the local gradients of all data participants and calculates the global leaf weights, so as to improve the accuracy of the model and reduce the communication cost. Finally, the experimental analysis shows that the algorithm can protect the privacy of the original data, and the communication cost is low. At the same time, the performance of the unbalanced binary data set is evaluated. The results show that SeFB algorithm compared with the existing schemes of horizontal federated GBDTs, the accuracy is improved by 2.53% on average.

Molecular beam epitaxy technology has a significant advantage in semiconductor technology due to its strong controllability, especially for the preparation of materials such as quantum wires and quantum dots [...]

Single-bit upset (SBU) and multiple-cell upset (MCU) features of high-speed QDR-SRAM are revealed under the 14 MeV neutron irradiation. By comparing with the high-altitude real atmosphere test results directly, the equivalence of 14 MeV neutrons for atmospheric neutron-induced single event effect (SEE) evaluation is investigated. It is found that, compared with the 65 nm planar device, the SBU cross-section of 14 nm FinFET SRAM decreases to 1/58 and the proportion of MCU shows little difference, which results from the narrow channel between fin and substrate caused by shallow channel isolation in 14 nm FinFET process, and the charge sharing effect between fins is weakened. The SBU and MCU cross-sections under the 14 MeV neutron irradiation are underestimated by 22.8% and 85.7%, respectively. Besides, the probability and maximum size of MCU are both smaller than those in the real atmosphere. The MCU shape tends to be vertical, resulting from the smaller vertical spacing of sensitive volumes (about 100 nm). Further Monte-Carlo simulation shows that the total yield of secondary ions produced by atmospheric neutrons is higher than that produced by 14 MeV neutrons. Major Components of the “useful” products are p, Si, α, etc., which are the main cause of SBU events. Besides, compared with 14 MeV neutrons, atmospheric neutrons generate more kinds of secondary ions in the SV within the scope from p to W, and the diverse high-Z elements, such as W, Ta, Hf, etc., are the main cause of MCU events. Moreover, the maximum LET of secondary ions can reach 31.5 MeV·cm2/mg. The equivalence of using 14 MeV neutrons for atmospheric neutron-induced SEE evaluation is closely related to the critical charge of the device under test.

The practice and theory of grouting engineering show that both injected medium porosity and grouting fluid weight play an important influence on the diffusion law and morphology of penetration grouting. However, the effects have not been well studied in the context of existing penetration grouting mechanisms. In this paper, the actual diffusion law and morphology of cement grout into the gravel soil are studied on the basis of indoor experiments, mathematical statistics, and theoretical analyses. Then, the three-dimensional space diffusion trajectory equation was quantitatively characterized. The influence of the coupling effect between gravel soil porosity and cement grout weight on diffusion morphologies of penetration grouting was discussed by the definition of the morphological deviation rate. Results show that actual penetration diffusion dimensions of cement grout into the gravel soil differ from that of theoretical values calculated by the penetration grouting mechanism, and its spatial diffusion morphology is approximated as ellipsoid. The coupling effect between gravel soil porosity and cement grout weight have a relatively significant effect on the diffusion morphologies of penetration grouting except for gravel soil with porosity 0.5. The research results can provide theoretical support and technical references for the practical grouting engineering of gravel soil.

Double perovskites (DPs) have been attracting attention in an assortment of optoelectronic applications, for they hold advantages such as high quantum efficiency, long carrier migration distance and strong linear and nonlinear absorptions. As specific kinds of perovskites (PVKs), DPs are gifted with orthorhombic crystal structures which provide rich conversion combinations and broaden the space for research and application. However, few works have been reported about DPs in ultrafast photonics applications. In this article, a DP with chemical formula of Ba2LaTaO6 (BLT) was successfully synthesized by high-temperature solid phase method. The microstructures and morphologies were observed, and the linear and nonlinear absorption were characterized. By first using BLT as a novel saturable absorber in both normal and anomalous dispersion region fiber lasers, dual-wavelength soliton and dissipative soliton were successfully operated at C-band. This study affirms BLT’s nonlinear optical properties, lays the foundation for optical research on BLT, and meanwhile provides a meaningful reference for future development of pulsed lasers based on DPs.

Semiconductor superluminescent light-emitting diodes (SLEDs) have emerged as ideal and vital broadband light sources with extensive applications, such as optical fiber-based sensors, biomedical sensing/imaging, wavelength-division multiplexing system testing and optoelectronic systems, etc. Self-assembled quantum dots (SAQDs) are very promising candidates for the realization of broadband SLED due to their intrinsic large inhomogeneous spectral broadening. Introducing excited states (ESs) emission could further increase the spectral bandwidth. However, almost all QD-based SLEDs are limited to the ground state (GS) or GS and first excited state (ES1) emission. In this work, multiple five-QD-layer structures with large dot size inhomogeneous distribution were grown by optimizing the molecular beam epitaxy (MBE) growth conditions. Based on that, with the assistance of a carefully designed mirror-coating process to accurately control the cavity mirror loss of GS and ESs, respectively, a broadband QD-SLED with three simultaneous states of GS, ES1 and second excited-state (ES2) emission has been realized, exhibiting a large spectral width of 91 nm with a small spectral dip of 1.3 dB and a high continuous wave (CW) output power of 40 mW. These results pave the way for a new fabrication technique for high-performance QD-based low-coherent light sources.

K+/Cl− and K+/F− co-doped LiNi0.5Mn1.5O4 (LNMO) materials were successfully synthesized via a solid-state method. Structural characterization revealed that both K+/Cl− and K+/F− co-doping reduced the LixNi1−xO impurities and enlarged the lattice parameters compared to those of pure LNMO. Besides this, the K+/F− co-doping decreased the Mn3+ ion content, which could inhibit the Jahn–Teller distortion and was beneficial to the cycling performance. Furthermore, both the K+/Cl− and the K+/F− co-doping reduced the particle size and made the particles more uniform. The K+/Cl− co-doped particles possessed a similar octahedral structure to that of pure LNMO. In contrast, as the K+/F− co-doping amount increased, the crystal structure became a truncated octahedral shape. The Li+ diffusion coefficient calculated from the CV tests showed that both K+/Cl− and K+/F− co-doping facilitated Li+ diffusion in the LNMO. The impedance tests showed that the charge transfer resistances were reduced by the co-doping. These results indicated that both the K+/Cl− and the K+/F− co-doping stabilized the crystal structures, facilitated Li+ diffusion, modified the particle morphologies, and increased the electrochemical kinetics. Benefiting from the unique advantages of the co-doping, the K+/Cl− and K+/F− co-doped samples exhibited improved rate and cycling performances. The K+/Cl− co-doped Li0.97K0.03Ni0.5Mn1.5O3.97Cl0.03 (LNMO-KCl0.03) exhibited the best rate capability with discharge capacities of 116.1, 109.3, and 93.9 mAh g−1 at high C-rates of 5C, 7C, and 10C, respectively. Moreover, the K+/F− co-doped Li0.98K0.02Ni0.5Mn1.5O3.98F0.02 (LNMO-KF0.02) delivered excellent cycling stability, maintaining 85.8% of its initial discharge capacity after circulation for 500 cycles at 5C. Therefore, the K+/Cl− or K+/F− co-doping strategy proposed herein will play a significant role in the further construction of other high-voltage cathodes for high-energy LIBs.

Gold nanorods (GNRs) has been investigated in the field of chemistry, optoelectronics, and medicine for their tenability, compatibility, electromagnetics, and excellent photonics properties. Especially, GNRs, used to generate ultrashort pulse, have been studied recently. However, multiple pulses evolution based on GNRs needs to be further explored. In this article, GNRs are synthesized by seed-mediated growth method, characterized systematically and been chosen as saturable absorber (SA) to apply in ultrafast photonics. The GNRs SA presents a saturable intensity of 266 MW/cm2, modulation depth of 0.6%, and non-saturable loss of 51%. Furthermore, a passively mode-locked erbium-doped fiber laser based on GNRs SA with femtosecond pulse is demonstrated. Thanks to the excellent properties of GNRs, by adjusting the cavity polarization direction with the proposed GNRs SA, soliton molecules operation with spectrum modulation period of 3.3 nm and pulse modulation interval of 2.238 ps is directly obtained. For the most important, 9th-order harmonic soliton molecules have been generated in the laser cavity for the first time. It is demonstrated that GNRs can be a novel type of non-linear optical (NLO) device and have potential applications in the field of ultrafast photonics.

It is of utmost importance for advanced driver assistance systems to evaluate the risk of the current situation and make continuous decisions about what kind of evasive maneuver can be initiated. The purpose of this paper is to establish efficient indicators to evaluate the risk of candidate driving maneuvers for a human-in-the-loop vehicle. A novel safe driving envelope generation method is proposed, which takes various constraints into consideration, including the human operation, vehicle motion limits, and collision avoidance with road boundary and obstacles. The efficiency of the proposed method is validated by simulation experiments and real vehicle tests. The results show that the feasibility of candidate driving maneuvers can be efficiently determined by computing the driving envelope, and the proposed driving envelope method can be easily implemented for real-time applications.

(Dy0.7Y0.25La0.05)2O3 magneto-optical transparent ceramics were successfully fabricated by pressureless sintering in reductive H2 atmosphere (PLSH). The raw powder of (Dy0.7Y0.25La0.05)2O3 was synthesized by a modified self-propagating high-temperature synthesis (SHS) and sintered to transparent ceramics at 1400–1600 °C in a flowing H2 atmosphere, showing good sinterability of the as-synthesized raw powder. The magneto-optical Verdet constant of (Dy0.7Y0.25La0.05)2O3 transparent ceramics was measured to be −191.57 rad/(T·m) at a wavelength of 632.8 nm. In this magneto-optical material of (Dy0.7Y0.25La0.05)2O3, relative cheaper Dy and Y were used to replace Tb, and the low cost and good magneto-optical property showed the advantage of application on Faraday isolators (FIs) and Faraday rotators (FRs).

The authors would like to make the following corrections to their paper, published in the International Journal of Molecular Sciences [...]

The polymorphic membrane protein D (PmpD) is a highly conserved outer membrane protein which plays an important role in pathogenesis during Chlamydia psittaci infection. In this study, we evaluated the ability of the N-terminus of PmpD (PmpD-N) to modulate the functions of chicken macrophages and the signaling pathway(s) involved in PmpD-N-induced Toll-like receptors (TLRs), as well as interleukin (IL)-6 and IL-10 cytokine secretions. Thus, HD11 macrophages were treated with exogenous and intracellular PmpD-N of C. psittaci. The chlamydial growth was evaluated by enumeration of chlamydial loads in the infected macrophages. The phagocytic function of macrophages following PmpD-N treatment was detected by fluorescein-labeled Escherichia coli (E. coli). The concentration of nitric oxide (NO) secreted by HD11 macrophages was measured by the amount of NO2- in the culture supernatant using the Griess method. The cytokine secretions were assessed using multiplex cytokine ELISA kits. Expression levels of TLRs, myeloid differentiation factor 88 (MyD88), and nuclear factor kappa B (NF-κB) were analyzed by a Western blotting assay, as well as a luciferase assay, while NF-κB p65 nuclear translocation was assessed by confocal microscopy. The nuclear translocation of the transcription factor NF-κB was confirmed by evaluating its ability to combine with the corresponding promoter using the electrophoretic mobility shift assay (EMSA). After treatment with exogenous or endogenous PmpD-N, chlamydial loads and phagocytic functions were reduced significantly compared with those of the plasmid vector group, while NO secretions were reduced significantly compared with those of the lipopolysaccharide (LPS) treatment. Stimulation of HD11 cells with PmpD-N provoked the secretion of the Th2 cytokines, IL-6, and IL-10 and upregulated the expression of TLR2, TLR4, MyD88, and NF-κB. Furthermore, inhibition of TLR2, MyD88, and NF-κB in HD11 cells significantly decreased IL-6 and IL-10 cytokine levels, while NO production and phagocytosis increased significantly, strongly suggesting their involvement in PmpD-N-induced Th2 cytokine secretion and macrophage dysfunction. Our data indicate that C. psittaci PmpD-N inhibited macrophage functions by activating the Th2 immune response and the TLR2/MyD88/NF-κB signaling pathway.

Ultra-dense and highly heterogeneous network (HetNet) deployments make the allocation of limited wireless resources among ubiquitous Internet of Things (IoT) devices an unprecedented challenge in 5G and beyond (B5G) networks. The interactions among mobile users and HetNets remain to be analyzed, where mobile users choose optimal networks to access and the HetNets adopt proper methods for allocating their own network resource. Existing works always need complete information among mobile users and HetNets. However, it is not practical in a realistic situation where important individual information is protected and will not be public to others. This paper proposes a distributed pricing and resource allocation scheme based on a Stackelberg game with incomplete information. The proposed model proves to be more practical by solving the problem that important information of either mobile users or HetNets is difficult to acquire during the resource allocation process. Considering the unknowability of channel gain information, the follower game among users is modeled as an incomplete information game, and channel gain is regarded as the type of each player. Given the pricing strategies of networks, users will adjust their bandwidth requesting strategies to maximize their expected utility. While based on the sub-equilibrium obtained in the follower game, networks will correspondingly update their pricing strategies to be optimal. The existence and uniqueness of Bayesian Nash equilibrium is proved. A probabilistic prediction method realizes the feasibility of the incomplete information game, and a reverse deduction method is utilized to obtain the game equilibrium. Simulation results show the superior performance of the proposed method.

Plug-in Hybrid Electric Vehicles (PHEVs), as a new type of environmental-friendly low cost transportation, have attracted growing interests for logistics. The path-planning optimization for PHEV has become a major challenge. In fact, PHEV-based routing optimization is a type of hybrid vehicle routing problem (HVRP). Compared with the traditional Traveling Salesman Problem (TSP) and Vehicle Routing Problem (VRP), the PHEV routing problem should consider more constraints, such as time limits, capacity constraints (including fuel tank capacity and battery capacity), electric stations, fuel stations and so forth. In this paper, a Mixed Integer Linear Programming formulation is presented and a novel hybrid metaheuristic approach (HMA_SVND) is proposed. Our method is a combination of memetic algorithm (MA), sequential variable neighborhood descent (SVND) and a revised 2_opt method. Comparative studies show that our proposed method outperformed previous works.

Tropomyosin (TM) and arginine kinase (AK) are known as two major allergens in seafood. For the first time, we demonstrate a newly developed ion-exchange chromatography coupled with dynamic coating capillary electrophoresis (IEC-DCCE) method to simultaneously analyze the TM and AK in shellfish. First, we have optimized the procedure of IEC for simple enrichment of TM and AK crude extract. By using 30 mM borate-borax at pH 9.0 with 0.3% (v/v) Tween-20 as a dynamic coating modifier for capillary electrophoresis (CE) separation, the migration time, separation efficiency and electrophoretic resolution greatly improved. The limits of detection (LOD) were 1.2 μg mL−1 for AK and 1.1 μg mL−1 for TM (S/N = 3), and the limits of quantification (LOQ) were 4.0 μg mL−1 for AK and 3.7 μg mL−1 for TM (S/N = 10). The recovery of AK ranged from 91.5 to 106.1%, while that of TM ranged from 94.0 to 109.5%. We also found that only when the concentrations of AK and TM were above LOD reported here, these proteins can stimulate human mast cell (LAD2) degranulation. Finally, the use of IEC-DCCE to analyze fresh shellfish samples highlights the applicability of this method for the simultaneous detection of these allergens in complex food systems.

The epigenetic plasticity hypothesis indicates that exposure during pregnancy may cause adult-onset disorders, including hypertension, myocardial infarction and heart failure. Moreover, myocardial fibrosis coincides with hypertension, myocardial infarction and heart failure. This study was designed to investigate the effects of prenatal exposure to lipopolysaccharide (LPS) on myocardial fibrosis. The result showed that at six and 16 weeks of age, the LPS-treated offspring exhibited increased collagen synthesis, an elevated cardiac index (CI), higher mRNA levels of TIMP-2 and TGFβ and a reduced mRNA level of MMP2. The protein levels corresponded to the mRNA levels. The offspring that were prenatally treated with pyrrolidine dithiocarbamic acid (PDTC), an inhibitor of NF-κB, displayed improvements in the CI and in collagen synthesis. Moreover, PDTC ameliorated the expression of cytokines and proteins associated with myocardial fibrosis. The results showed that maternal inflammation can induce myocardial fibrosis in offspring during aging accompanied by an imbalance of TIMP-2/MMP2 and TGFβ expression.

Background: Atherosclerosis is a fundamental pathological process responded to some serious cardiovascular events. Although the cholesterol-lowering drugs are widely prescribed for atherosclerosis therapy, it is still the leading cause of death in the developed world. Here we measured the effects of compound K in atherosclerosis formation and investigated the probably mechanisms of the anti-antherosclerosis roles of compound K. Methods: We treated the atherosclerotic model animals (apoE−/− mice on western diet) with compound K and measured the size of atherosclerotic lesions, inflammatory cytokine levels and serum lipid profile. Peritoneal macrophages were collected in vitro for the foam cell and inflammasome experiments. Results: Our results show that treatment with compound K dose-dependently attenuates the formation of atherosclerotic plaques by 55% through activation of reverse cholesterol transport pathway, reduction of systemic inflammatory cytokines and inhibition of local inflammasome activity. Compound K increases the cholesterol efflux of macrophage-derived foam cells, and reduces the inflammasome activity in cholesterol crystal stimulated macrophages. The activation of LXRα may contribute to the athero-protective effects of compound K. Conclusion: These observations provide evidence for an athero-protective effect of compound K via LXRα activation, and support its further evaluation as a potential effective modulator for the prevention and treatment of atherosclerosis.